Heterocyclic chemistry
著者
書誌事項
Heterocyclic chemistry
Wiley, 2010
5th ed
- : cloth
- : pbk
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注記
Includes bibliographical references and index
内容説明・目次
- 巻冊次
-
: pbk ISBN 9781405133005
内容説明
This book has so closely matched the requirements of its readership over the years that it has become the first choice for chemists worldwide. Heterocyclic chemistry comprises at least half of all organic chemistry research worldwide. In particular, the vast majority of organic work done in the pharmaceutical and agrochemical industries is heterocyclic chemistry.
The fifth edition of Heterocyclic Chemistry maintains the principal objective of earlier editions - to teach the fundamentals of heterocyclic reactivity and synthesis in a way that is understandable to second- and third-year undergraduate chemistry students. The inclusion of more advanced and current material also makes the book a valuable reference text for postgraduate taught courses, postgraduate researchers, and chemists at all levels working with heterocyclic compounds in industry.
Fully updated and expanded to reflect important 21st century advances, the fifth edition of this classic text includes the following innovations:
Extensive use of colour to highlight changes in structure and bonding during reactions
Entirely new chapters on organometallic heterocyclic chemistry, heterocyclic natural products, especially in biochemical processes, and heterocycles in medicine
New sections focusing on heterocyclic fluorine compounds, isotopically labeled heterocycles, and solid-phase chemistry, microwave heating and flow reactors in the heterocyclic context
Essential teaching material in the early chapters is followed by short chapters throughout the text which capture the essence of heterocyclic reactivity in concise resumes suitable as introductions or summaries, for example for examination preparation. Detailed, systematic discussions cover the reactivity and synthesis of all the important heterocyclic systems. Original references and references to reviews are given throughout the text, vital for postgraduate teaching and for research scientists. Problems, divided into straightforward revision exercises, and more challenging questions (with solutions available online), help the reader to understand and apply the principles of heterocyclic reactivity and synthesis.
目次
- Preface to the Fifth Edition xix P.1 Hazards xxi P.2 How to Use This Textbook xxi Acknowledgements xxii References xxii Web Site xxii Biography xxiii Definitions of Abbreviations xxv 1 Heterocyclic Nomenclature 1 2 Structures and Spectroscopic Properties of Aromatic Heterocycles 5 3 Substitutions of Aromatic Heterocycles 19 4 Organometallic Heterocyclic Chemistry 37 5 Methods in Heterocyclic Chemistry 97 6 Ring Synthesis of Aromatic Heterocycles 107 7 Typical Reactivity of Pyridines, Quinolines and Isoquinolines 115 8 Pyridines: Reactions and Synthesis 125 9 Quinolines and Isoquinolines: Reactions and Synthesis 177 10 Typical Reactivity of Pyrylium and Benzopyrylium Ions, Pyrones and Benzopyrones 205 11 Pyryliums, 2- and 4-Pyrones: Reactions and Synthesis 209 12 Benzopyryliums and Benzopyrones: Reactions and Synthesis 229 13 Typical Reactivity of the Diazine: Pyridazine, Pyrimidine and Pyrazine 249 14 The Diazines: Pyridazine, Pyrimidine, and Pyrazine: Reactions and Synthesis 253 15 Typical Reactivity of Pyrroles, Furans and Thiophenes 289 16 Pyrroles: Reactions and Synthesis 295 17 Thiophenes: Reactions and Synthesis 325 18 Furans: Reactions and Synthesis 347 19 Typical Reactivity of Indoles, Benzo[b]thiophenes, Benzo[b]furans, Isoindoles, Benzo[c]thiophenes and Isobenzofurans 369 20 Indoles: Reactions and Synthesis 373 21 Benzo[b]thiophenes and Benzo[b]furans: Reactions and Synthesis 433 22 Isoindoles, Benzo[c]thiophenes and Isobenzofurans: Reactions and Synthesis 447 23 Typical Reactivity of 1,3- and 1,2-Azoles and Benzo-1,3- and -1,2-Azoles 455 24 1,3-Azoles: Imidazoles, Thiazoles and Oxazoles: Reactions and Synthesis 461 25 1,2-Azoles: Pyrazoles, Isothiazoles, Isoxazoles: Reactions and Synthesis 485 26 Benzanellated Azoles: Reactions and Synthesis 503 27 Purines: Reactions and Synthesis 515 28 Heterocycles Containing a Ring-Junction Nitrogen (Bridgehead Compounds) 539 29 Heterocycles Containing More Than Two Heteroatoms 557 30 Saturated and Partially Unsaturated Heterocyclic Compounds: Reactions and Synthesis 587 31 Special Topics 609 32 Heterocycles in Biochemistry
- Heterocyclic Natural Products 629 33 Heterocycles in Medicine 645 Index 665
- 巻冊次
-
: cloth ISBN 9781405193658
内容説明
This book has so closely matched the requirements of itsreadership over the years that it has become the first choice forchemists worldwide. Heterocyclic chemistry comprises at least half of all organicchemistry research worldwide. In particular, the vast majority oforganic work done in the pharmaceutical and agrochemical industriesis heterocyclic chemistry. The fifth edition of Heterocyclic Chemistry maintains theprincipal objective of earlier editions to teach thefundamentals of heterocyclic reactivity and synthesis in a way thatis understandable to second- and third-year undergraduate chemistrystudents. The inclusion of more advanced and current material alsomakes the book a valuable reference text for postgraduate taughtcourses, postgraduate researchers, and chemists at all levelsworking with heterocyclic compounds in industry.
Fully updated and expanded to reflect important 21stcentury advances, the fifth edition of this classic text includesthe following innovations: * Extensive use of colour to highlight changes in structure andbonding during reactions * Entirely new chapters on organometallic heterocyclic chemistry,heterocyclic natural products, especially in biochemical processes,and heterocycles in medicine * New sections focusing on heterocyclic fluorine compounds,isotopically labeled heterocycles, and solid-phase chemistry,microwave heating and flow reactors in the heterocycliccontext Essential teaching material in the early chapters is followed byshort chapters throughout the text which capture the essence ofheterocyclic reactivity in concise resumes suitable asintroductions or summaries, for example for examinationpreparation. Detailed, systematic discussions cover the reactivityand synthesis of all the important heterocyclic systems. Originalreferences and references to reviews are given throughout the text,vital for postgraduate teaching and for research scientists.Problems, divided into straightforward revision exercises, and morechallenging questions (with solutions available online), help thereader to understand and apply the principles of heterocyclicreactivity and synthesis.
目次
- Preface Definitions of abbreviations 1. Heterocyclic nomenclature 2. Structures and spectroscopic properties of aromaticheterocycles 3. Substitutions of aromatic heterocycles 4. Organometallic heterocyclic chemistry 5. Methods in heterocyclic chemistry 6. Ring synthesis of aromatic heterocycles 7. Typical reactivity of pyridines, quinolines andisoquinolines 8. Pyridines: reactions and synthesis 9. Quinolines and isoquinolines: reactions andsynthesis 10. Typical reactivity of pyrylium and benzopyrylium ions,pyrones and benzopyrones 11. Pyryliums, 2- and 4-pyrones: reactions andsynthesis 12. Benzopyryliums, benzopyrones: reactions andsynthesis 13. Typical reactivity of the diazines: pyridazine,pyrimidine and pyrazine 14. The diazines: pyridazine, pyrimidine, and pyrazine:reactions and synthesis 15. Typical reactivity of pyrroles, thiophenes, andfurans 16. Pyrroles: reactions and synthesis 17. Thiophenes: reactions and synthesis 18. Furans: reactions and synthesis 19. Typical reactivity of indoles, benzo[b]thiophenes,benzo[b]furans, isoindoles, benzo[c]thiophenes andisobenzofurans 20. Indoles: reactions and synthesis 21. Benzo[b]thiophenes and benzo[b]furans:reactions and synthesis 22. Isoindoles, benzo[c]thiophenes and isobenzofurans:reactions and synthesis 23. Typical reactivity of 1,3- and 1,2-azoles and benzo-1,3-and -1,2-azoles 24. 1,3-Azoles: imidazoles, thiazoles, and oxazoles:reactions and synthesis 25. 1,2-Azoles: pyrazoles, isothiazoles, isoxazoles:reactions and synthesis 26. Benzanellated azoles: reactions and synthesis 27. Purines: reactions and synthesis 28. Heterocycles containing a ring-junction nitrogen(bridgehead compounds) 29. Heterocycles containing more than two heteroatoms 30. Saturated and partially unsaturated heterocycliccompounds: reactions and synthesis 31. Special topics 32. Heterocycles in biochemistry
- heterocyclic naturalproducts 33. Heterocycles in medicine
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