Functionalised N-heterocyclic carbene complexes
著者
書誌事項
Functionalised N-heterocyclic carbene complexes
Wiley, 2010
大学図書館所蔵 全3件
  青森
  岩手
  宮城
  秋田
  山形
  福島
  茨城
  栃木
  群馬
  埼玉
  千葉
  東京
  神奈川
  新潟
  富山
  石川
  福井
  山梨
  長野
  岐阜
  静岡
  愛知
  三重
  滋賀
  京都
  大阪
  兵庫
  奈良
  和歌山
  鳥取
  島根
  岡山
  広島
  山口
  徳島
  香川
  愛媛
  高知
  福岡
  佐賀
  長崎
  熊本
  大分
  宮崎
  鹿児島
  沖縄
  韓国
  中国
  タイ
  イギリス
  ドイツ
  スイス
  フランス
  ベルギー
  オランダ
  スウェーデン
  ノルウェー
  アメリカ
注記
Includes bibliographical references and index
収録内容
- The nature of N-heterocyclic carbenes
- Why functionalisation?
- N-heterocyclic carbenes with neutral tethers
- N-heterocyclic carbenes with anionic functional groups
- Chiral N-heterocyclic carbenes
- Natural products
内容説明・目次
内容説明
N-heterocyclic carbenes (NHCs) have found increasing use as reagents for a range of organic transformations and in asymmetric organocatalysis. The performance of these molecules can be improved and tuned by functionalisation. Functionalised carbenes can anchor free carbenes to the metal site, introduce hemilability, provide a means to immobilise transition metal carbene catalysts, introduce chirality, provide a chelate ligand or bridge two metal centres. NHC can be attached to carbohydrates and campher, derived from amino acids and purines, they can be used as organocatalysts mimicking vitamin B1 or as weak "solvent" donors in lanthanide chemistry. Functionalised N-Heterocyclic Carbene Complexes describes major trends in functionalised NHC ligands, aiming to assist readers in their attempts to develop and apply their own functionalised carbenes. After an introduction to the chemistry and behaviour of NHC, the book gives a detailed description of functionalised carbenes and their complexes according to a range of functional groups, each with a discussion of the synthetic route, structure, stability and performance.
Functionalised N-Heterocyclic Carbene Complexes is an essential guide to fine-tuning this important class of compounds for practitioners, researchers and advanced students working in synthetic organometallic and organic chemistry and catalysis.
目次
Abbreviations. Introduction.
Chapter 1 The Nature of N-Heterocyclic Carbenes.
1.1 Synthesis.
1.2 Properties of NHC.
References.
Chapter 2 Why Functionalisation?
2.1 Phosphane Mimick.
2.2 Hemilability.
2.3 Chirality.
2.4 Ligand Geometry.
2.5 Catalysis.
References.
Chapter 3 N-Heterocyclic with Neutral Tethers.
3.1 Amine Functionalities.
3.2 Oxygen-Containing Groups.
3.3 Phosphane Functionalities.
3.4 Bis-Carbene Ligands.
3.5 Tris-N-Heterocyclic Carbene Ligands.
3.6 Pincer Carbenes.
References.
Chapter 4 N-Heterocyclic with Anionic Functional Groups.
4.1 Oxygen-Containing Groups.
4.2 Nitrogen-Containing Groups.
4.3 NHC Ligands Incorporating Cp Moieties.
4.4 Transition Metal NHC Complexes Involved in the Activation of C-H Bonds.
4.5 Immobilisation of the Catalyst.
4.6 Sulfur-Containing Functional Groups.
References.
Chapter 5 Chiral N-Heterocyclic Carbenes.
References.
Chapter 6 Natural Products.
6.1 Thiazole.
6.2 Amino Acids.
6.3 Purines and Xanthines.
6.4 Carbohydrates.
6.5 Miscellaneous.
References.
Index.
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