Carbon nanowalls : synthesis and emerging applications
著者
書誌事項
Carbon nanowalls : synthesis and emerging applications
Springer, c2010
大学図書館所蔵 全12件
  青森
  岩手
  宮城
  秋田
  山形
  福島
  茨城
  栃木
  群馬
  埼玉
  千葉
  東京
  神奈川
  新潟
  富山
  石川
  福井
  山梨
  長野
  岐阜
  静岡
  愛知
  三重
  滋賀
  京都
  大阪
  兵庫
  奈良
  和歌山
  鳥取
  島根
  岡山
  広島
  山口
  徳島
  香川
  愛媛
  高知
  福岡
  佐賀
  長崎
  熊本
  大分
  宮崎
  鹿児島
  沖縄
  韓国
  中国
  タイ
  イギリス
  ドイツ
  スイス
  フランス
  ベルギー
  オランダ
  スウェーデン
  ノルウェー
  アメリカ
注記
Includes bibliographical references
内容説明・目次
内容説明
Representing the first text to cover this exciting new area of research, this book will describe synthesis techniques of CNWs, their characterization and various expected applications using CNWs. Carbon-nanowalls (CNWs) can be described as two-dimensional graphite nanostructures with edges comprised of stacks of plane graphene sheets standing almost vertically on the substrate. These sheets form a wall structure with a high aspect ratio. The thickness of CNWs ranges from a few nm to a few tens of nm. The large surface area and sharp edges of CNWs may prove useful for a number of applications such as electrochemical devices, field electron emitters, storage materials for hydrogen gas, catalyst support. In particular, vertically standing CNWs with a high surface-to-volume ratio, serve as an ideal material for catalyst support for fuel cells and in gas storage materials.
目次
1. Introduction
1.1 Discovery of two-dimensional carbon nanostructures
1.2 Brief description of carbon nanowalls
1.3 Research on carbon nanowalls
2. Synthesis methods
2.1 Microwave plasma enhanced chemical vapor deposition
2.2 Inductively coupled plasma enhanced chemical vapor deposition
2.3 Capacitively coupled plasma enhanced chemical vapor deposition with radical injection
2.3.1 RF plasma-enhanced CVD with H radical injection
2.3.2 VHF plasma-enhanced CVD with H radical injection
2.4 Electron-beam-excited plasma enhanced chemical vapor deposition
2.5 Hot filament chemical vapor deposition
2.6 Atmospheric plasma CVD
2.7 Sputtering
3. Physics of carbon nanowalls
3.1 Characterization of carbon nanowalls
3.1.1 SEM and TEM observation
3.1.2 Raman spectra of carbon nanowalls
3.1.3 Grazing incidence in-plane X-ray diffraction
3.2 Electrical properties of carbon nanowalls
3.2.1 Field emission properties of carbon nanowalls
3.2.2 Electrical conduction of carbon nanowalls
3.3.3 Electrode for electrochemistry
4. Fabrication of carbon nanowalls using radical injection plasma enhanced CVD
4.1 Concept of radical-controlled processing
4.2 RF plasma-enhanced CVD with H radical injection
4.2.1 Experimental setup for RF plasma-enhanced CVD with H radical injection
4.2.2 Measurement of radical densities in the capacitively coupled plasma region
4.2.3 Effect of carbon source gases and H radicals on carbon nanowall growth
4.2.4 Fabrication of straight and aligned carbon nanowalls with regular spacing
4.3 VHF plasma-enhanced CVD with H radical injection
4.3.1 Experimental setup of VHF plasma-enhanced CVD with H radical injection
4.3.2 Chamber cleaning for carbon nanowall growth with high reproducibility
4.3.3 Electrical conduction control of carbon nanowalls
4.3.4 Fabrication of monolithic self-sustaining graphene sheets
5. Growth mechanism of carbon nanowalls
5.1 Measurement of radical densities in the plasma used for the fabrication of carbon nanowalls
5.1.1 Radicals in microwave plasma-enhanced CVD with CH4/H2 mixture
5.1.2 Radicals in fluorocarbon plasma with H radical injection
5.1.3 Discussion
5.2 Steady state growth of carbon nanowalls
5.2.1 RF plasma-enhanced CVD with H radical injection employing C2F6/H2 system
5.2.2 Inductively coupled plasma (ICP) enhanced CVD employing CH4/Ar system
5.2.3 Electron-beam-excited plasma (EBEP) enhanced CVD employing CH4/H2 system
5.2.4 VHF plasma-enhanced CVD with H radical injection employing C2F6/H2 system
5.2.5 Discussion
5.3 Nucleation of carbon nanowalls
5.3.1 Investigation of nucleation stage of carbon nanowall growth employing C2F6/H2
5.3.2 Comparison of carbon nanowall growth employing C2F6/H2 with and without O2 gas addition
5.3.3 Nucleation model of carbon nanowalls
5.4 Nucleation mechanism of carbon nanowall growth under ion irradiation
5.4.1 Carbon nanowall growth using multi-beam CVD technique
5.4.2 Effect of ions on the growth of carbon nanowalls
5.5 Area-selective growth of carbon nanowalls
6. Field emission
6.1 Field emission properties of as-grown carbon nanowalls
6.2 Surface treatment for improvement of field emission properties
6.2.1 Surface coating
6.2.2 Metal/carbon nanowall composites
6.2.3 Plasma surface treatment
7. Using carbon nanowalls as templates
7.1 Fabrication of nanostructured materials using carbon nanowalls as templates
7.1.1 Decoration of carbon nanowalls
7.1.2 Fabrication of nanostructured materials on carbon nanowall templates
7.2 Synthesis of Pt nanoparticles on carbon nanowall surface using supercritical fluid chemical deposition
7.2.1 Introduction
7.2.2 Synthesis of Pt nanoparticles by plating
7.2.3 Synthesis of Pt nanoparticles by sputtering
7.2.4 Supercritical fluids
7.2.5 Experimental procedure of metal-organic chemical fluid deposition using supercritical carbon dioxide
7.2.6 Characterization of platinum nanoparticles formed by metal-organic chemical fluid deposition using supercritical carbon dioxide
7.2.7 Mechanism of platinum nanoparticle formation by metal-organic chemical fluid deposition using supercritical carbon dioxide
7.3 Pattern transfer from carbon nanowall into SiO2 film
8. Future perspective for emerging applications using carbon nanowalls
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