Basic organometallic chemistry : concepts, syntheses, and applications of transition metals
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Bibliographic Information
Basic organometallic chemistry : concepts, syntheses, and applications of transition metals
Universities Press , CRC Press, 2010
- hbk.
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Description and Table of Contents
Description
Filled with detail not often found in coverage of the chemistry involved with transition metals, this clearly written resource encourages enhanced interest in the study of organometallic chemistry. Among a wealth of topics it covers the 18 Valence Electron Rule, unique reactions in organometallic chemistry, bioorganometallic chemistry, relevant ligands, bonding, structures, and a variety of other reactions, processes, and applications essential to understanding this highly complex field. The text includes figures, equations, and a large number of problems and exercises at the end of each chapter.
Table of Contents
Introduction
The 18 valence electron rule
Metal carbonyls
Neutral spectator ligands: Phosphines and N- heterocyclic carbenes
Alkenes and alkynes as ligands
Carbenes and carbynes: complexes with metal carbon double and triple bonds
Alkyl, aryl and ligands with higher hapticity
Unique reactions in organometallic chemistry
Ligand substitution reactions, metal-metal bonding and fluxionality in organometallic compounds
Organometallic clusters
Homogeneous catalysis using organometallic compounds
Hydrogenation, hydrosilylation and hydrocyanation of alkenes and asymmetric hydrogenation
Hydroformylation
Methanol carbonylation and olefin oxidation: Monsanto, Cativa and Wacker processes
Olefin metathesis
Palladium catalysed C-C and C-N cross coupling reactions
Olefin polymerisation reactions
Ferrocene: Structure, bonding and reactions
Organometallic polymers
Bioorganometallic chemistry
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