Basic organometallic chemistry : concepts, syntheses, and applications of transition metals
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書誌事項
Basic organometallic chemistry : concepts, syntheses, and applications of transition metals
Universities Press , CRC Press, 2010
- hbk.
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内容説明・目次
内容説明
Filled with detail not often found in coverage of the chemistry involved with transition metals, this clearly written resource encourages enhanced interest in the study of organometallic chemistry. Among a wealth of topics it covers the 18 Valence Electron Rule, unique reactions in organometallic chemistry, bioorganometallic chemistry, relevant ligands, bonding, structures, and a variety of other reactions, processes, and applications essential to understanding this highly complex field. The text includes figures, equations, and a large number of problems and exercises at the end of each chapter.
目次
Introduction
The 18 valence electron rule
Metal carbonyls
Neutral spectator ligands: Phosphines and N- heterocyclic carbenes
Alkenes and alkynes as ligands
Carbenes and carbynes: complexes with metal carbon double and triple bonds
Alkyl, aryl and ligands with higher hapticity
Unique reactions in organometallic chemistry
Ligand substitution reactions, metal-metal bonding and fluxionality in organometallic compounds
Organometallic clusters
Homogeneous catalysis using organometallic compounds
Hydrogenation, hydrosilylation and hydrocyanation of alkenes and asymmetric hydrogenation
Hydroformylation
Methanol carbonylation and olefin oxidation: Monsanto, Cativa and Wacker processes
Olefin metathesis
Palladium catalysed C-C and C-N cross coupling reactions
Olefin polymerisation reactions
Ferrocene: Structure, bonding and reactions
Organometallic polymers
Bioorganometallic chemistry
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