Cyclic β-keto esters : synthesis and reactions
著者
書誌事項
Cyclic β-keto esters : synthesis and reactions
（Chemistry research and applications）
Nova Science Publishers, c2010
- : pbk
- タイトル別名
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Cyclic beta-keto esters : synthesis and reactions
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注記
Includes bibliographical references (p. [93]-106) and index
内容説明・目次
内容説明
The chemistry of cyclic ss-ketoesters has received considerable attention because they serve as highly important intermediates in many organic synthesis. The wide application of these compounds in organic synthesis, depends chiefly on the reactivity of the methylene group, and the ready hydrolysis of the ester group, and its substituted derivatives to carboxlic acids and ketones. The syntheses and reactions of cyclic ss-ketoesters are reviewed in a formal way.
目次
- Carboxylation of ketones
- Intramolecular condensation & cyclization of Six-membered rings
- Isomerization
- Dieckmann condensation (intramolecular Claisen condensation)
- Miller & Nord Reaction:
- Esters of *,*-diethylacetonedicarboxylic acid
- Cyclic *-keto esters from cyclic ketones & ethyl cyanoacetate
- Claisen acylation & carboethoxylation of ketones & esters
- Homologation of ketones with ethyl diazoacetate
- Synthesis of carboethoxycyclohexanone
- Synthesis of carboethoxycyclohexanone
- The enamine acylation & alkylation of carbonyl compound
- Synthesis of 2-Carboethoxycyclohexanone
- Synthesis of N-containing cyclic O-keto esters
- Synthesis of N,N-Difluoro-O-ketoesters.
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