Green polymer chemistry : biocatalysis and biomaterials
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書誌事項
Green polymer chemistry : biocatalysis and biomaterials
（ACS symposium series, 1043,
American Chemical Society, c2010-2013
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注記
Editors of v. 2: H. N. Cheng, Richard A. Gross, Patrick B. Smith
"Sponsored by the ACS Division of Polymer Chemistry"--T.p. of v. 2
"This book is based on contributions by oral and poster presenters at the international symposium , Biocatalysis in Polymer Science, held at the ACS National Meeting in Washington D.C. on August 17-20, 2009"--Pref. of [v. 1]
V. 2: According to the pref., the chapters were contributed by the presenters at the international symposium on"Green Polymer Chemistry: Biocatalysis and Biobased Materials" at the American Chemical Society (ACS) national meeting in Philadelphia, PA in August 2012
Includes bibliographical references and index
収録内容
- Green polymer chemistry: biocatalysis and biomaterials
- Novel biobased materials
- Solid or swollen polymer-protein hybrid materials
- Biofabrication based on the enzyme-catalyzed coupling and crosslinking of pre-formed biopolymers
- Development of novel soy protein-based polymer blends
- Thermodynamic and microscopy studies of urea-soy protein composites
- Extraction and characterization of sugar beet polysaccharides
- Novel biobased plastics, rubbers, composites, coatings and adhesives from agricultural oils and by-products
- Enzyme-nanotube-based composites used for chemical and biological decontamination
- New or improved biocatalysts
- Hemin-binding aptamers and aptazymes
- Synthesis of covalently linked enzyme dimers
- Biotransformations using cutinase
- Syntheses of polyesters and polycarbonates
- Biosynthesis of polyhydroxyalkanoates from 4-ketovaleric acid in bacterial cells
- Synthesis of functional polycarbonates from renewable resources
- Polymers from biocatalysis: materials with a broad spectrum of physical properties
- Lipase-catalyzed copolymerization of ?-pentadecalactone (pdl) and alkyl glycolate: synthesis of poly(pdl-co-ga)
- Chemo-enzymatic syntheses of polyester-urethanes
- Enzymatic synthesis and properties of novel biobased elastomers consisting of 12-hydroxystearate, itaconate and butane-1,4-diol
- Syntheses of polyamides and polypeptides
- Synthesis of poly(aminoamides) via enzymatic means
- Mechanistic insight in the enzymatic ring-opening polymerization of ?-propiolactam
- Syntheses and modifictions of polysaccharides
- Production of natural polysaccharides and their analogues via biopathway engineering
- Glycosaminoglycan synthases: catalysts for customizing sugar polymer size and chemistry
- Development and applications of a novel, first-in-class hyaluronic acid from bacillus
- Biocatalytic redox polymerizations
- Enzymatic synthesis of electrically conducting polymers
- Sustained development in baeyer-villiger biooxidation technology
- Enzymatic hydrolyses and degradations
- Embedding enzymes to control biomaterial lifetime
- Surprisingly rapid enzymatic hydrolysis of poly(ethylene terephthalate)
- Polylactic acid (pla)-degrading microorganisms and pla depolymerases
- Grafting and functionalization reactions
- Green polymer chemistry: enzymatic functionalization of liquid polymers in bulk
- Bio-based and biodegradable aliphatic polyesters modified by a continuous alcoholysis reaction
- Synthesis of grafted polylactic acid and polyhydroxyalkanoate by a green reactive extrusion process
内容説明・目次
- 巻冊次
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[1] ISBN 9780841225817
内容説明
Green Polymer Chemistry is a crucial area of research and product development that continues to grow in its influence over industrial practices. Developments in these areas are driven by environmental concerns, interest in sustainability, desire to decrease our dependence on petroleum, and commercial opportunities to develop "green" products. Publications and patents in these fields are increasing as more academic, industrial, and government scientists become
involved in research and commercial activities.
The purpose of this book is to publish new work from a cutting-edge group of leading international researchers from academia, government, and industrial institutions. Because of the multidisciplinary nature of Green Polymer Chemistry, corresponding publications tend to be spread out over numerous journals. This book brings these papers together so that the reader can gain a better appreciation of the breadth and depth of activities in Green Polymer Chemistry. It is based on contributions by
oral and poster presenters at the international symposium, Biocatalysis in Polymer Science, held at the ACS National Meeting in Washington D.C. on August 17-20, 2009. Whereas many aspects of Green Polymer Chemistry were covered during the symposium, a particular emphasis was placed on biocatalysis and
biobased materials. Many exciting new findings in basic research and applications were reported. In addition, several leaders in these areas who were unable to attend the symposium contributed important reviews of their ongoing work. As a result, this book provides a good representation of activities at the forefront of research in Green Polymer Chemistry emphasizing activities in biocatalysis and biobased chemistry.
目次
- Preface
- 1. Green Polymer Chemistry: Biocatalysis and Biomaterials
- H. N. Cheng and Richard A. Gross
- Novel Biobased Materials
- 2. Solid or Swollen Polymer-Protein Hybrid Materials
- Kasper Renggli and Nico Bruns
- 3. Biofabrication Based on the Enzyme-Catalyzed Coupling and Crosslinking of Pre-Formed Biopolymers
- Yi Liu, Xiaohua Yang, Xiao-Wen Shi, William E. Bentley, and Gregory F. Payne
- 4. Development of Novel Soy Protein-Based Polymer Blends
- Jinwen Zhang and Feng Chen
- 5. Thermodynamic and Microscopy Studies of Urea-Soy Protein Composites
- K. Venkateshan and X. S. Sun
- 6. Extraction and Characterization of Sugar Beet Polysaccharides
- Marshall L. Fishman, Peter H. Cooke, and Arland T. Hotchkiss Jr.
- 7. Novel Biobased Plastics, Rubbers, Composites, Coatings and Adhesives from Agricultural Oils and By-Products
- Yongshang Lu and Richard C. Larock
- 8. Enzyme-Nanotube-Based Composites Used for Chemical and Biological Decontamination
- Cerasela Zoica Dinu, Indrakant V. Borkar, Shyam Sundhar Bale, Guangyu Zhu, Karl Sanford, Gregg Whited, Ravi S. Kane, and Jonathan S. Dordick
- New or Improved Biocatalysts
- 9. Hemin-Binding Aptamers and Aptazymes
- Mingzhe Liu, Hiroshi Abe, and Yoshihiro Ito
- 10. Synthesis of Covalently Linked Enzyme Dimers
- Sanne Schoffelen, Loes Schobers, Hanka Venselaar, Gert Vriend, and Jan C. M. van Hest
- 11. Biotransformations Using Cutinase
- Peter James Baker and Jin Kim Montclare
- Syntheses of Polyesters and Polycarbonates
- 12. Biosynthesis of Polyhydroxyalkanoates from 4-Ketovaleric Acid in Bacterial Cells
- Jian Yu
- 13. Synthesis of Functional Polycarbonates from Renewable Resources
- Kirpal S. Bisht and Talal F. Al-Azemi
- 14. Polymers from Biocatalysis: Materials with a Broad Spectrum of Physical Properties
- Mariastella Scandola, Maria Letizia Focarete, and Richard A. Gross
- 15. Lipase-Catalyzed Copolymerization of ?-Pentadecalactone (PDL) and Alkyl Glycolate: Synthesis of Poly(PDL-co-GA)
- Zhaozhong Jiang and Jie Liu
- 16. Chemo-Enzymatic Syntheses of Polyester-Urethanes
- Karla A. Barrera-Rivera, Angel Marcos-Fernandez, and Antonio Martinez-Richa
- 17. Enzymatic Synthesis and Properties of Novel Biobased Elastomers Consisting of 12-Hydroxystearate, Itaconate and Butane-1,4-diol
- Mayumi Yasuda, Hiroki Ebata, and Shuichi Matsumura
- Syntheses of Polyamides and Polypeptides
- 18. Synthesis of Poly(aminoamides) via Enzymatic Means
- H. N. Cheng and Qu-Ming Gu
- 19. Mechanistic Insight in the Enzymatic Ring-Opening Polymerization of ?-Propiolactam
- Leendert W. Schwab, Iris Baum, Gregor Fels, and Katja Loos
- Syntheses and Modifications of Polysaccharides
- 20. Production of Natural Polysaccharides and Their Analogues via Biopathway Engineering
- Lei Li, Wen Yi, Wenlan Chen, Robert Woodward, Xianwei Liu, and Peng George Wang
- 21. Glycosaminoglycan Synthases: Catalysts for Customizing Sugar Polymer Size and Chemistry
- Paul L. DeAngelis
- 22. Development and Applications of a Novel, First-in-Class Hyaluronic Acid from Bacillus
- Khadija Schwach-Abdellaoui, Birgit Lundskov Fuhlendorff, Fanny Longin, and Jens Lichtenberg
- Biocatalytic Redox Polymerizations
- 23. Enzymatic Synthesis of Electrically Conducting Polymers
- Ryan Bouldin, Akshay Kokil, Sethumadhavan Ravichandran, Subhalakshmi Nagarajan, Jayant Kumar, Lynne A. Samuelson, Ferdinando F. Bruno, and Ramaswamy Nagarajan
- 24. Sustained Development in Baeyer-Villiger Biooxidation Technology
- Peter C. K. Lau, Hannes Leisch, Brahm J. Yachnin, I. Ahmad Mirza, Albert M. Berghuis, Hiroaki Iwaki, and Yoshie Hasegawa
- Enzymatic Hydrolyses and Degradations
- 25. Embedding Enzymes To Control Biomaterial Lifetime
- Manoj Ganesh and Richard Gross
- 26. Surprisingly Rapid Enzymatic Hydrolysis of Poly(ethylene terephthalate)
- Asa M. Ronkvist, Wenchun Xie, Wenhua Lu, and Richard A. Gross
- 27. Polylactic Acid (PLA)-Degrading Microorganisms and PLA Depolymerases
- Fusako Kawai
- Grafting and Functionalization Reactions
- 28. Green Polymer Chemistry: Enzymatic Functionalization of Liquid Polymers in Bulk
- Judit E. Puskas and Mustafa Y. Sen
- 29. Bio-Based and Biodegradable Aliphatic Polyesters Modified by a Continuous Alcoholysis Reaction
- James H. Wang and Aimin He
- 30. Synthesis of Grafted Polylactic Acid and Polyhydroxyalkanoate by a Green Reactive Extrusion Process
- James H. Wang and David M. Schertz
- Epilogue
- Indexes
- Author Index
- Subject Index
- 巻冊次
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2 ISBN 9780841228955
内容説明
Green polymer chemistry is a very active area of research that has attracted the attention of the scientific community and the public at large. Developments in this area are stimulated by health and environmental concerns, interest in sustainability, desire to decrease the dependence on petroleum, and opportunity to design and produce "green" products and processes. A large number of publications have appeared, and many new methodologies have been reported. In
consideration of the rapid advances in this area, the editors organized an international symposium on "Green Polymer Chemistry: Biocatalysis and Biobased Materials" at the American Chemical Society (ACS) national meeting in Philadelphia, PA in August 2012. The symposium was very successful, with a total of
63 papers and active participation and discussions among the leading researchers. Whereas all aspects of Green Polymer Chemistry were covered, a particular emphasis was placed on biocatalysis and biobased materials. Biocatalysis involves the use of enzymes, microbes, and higher organisms to carry out chemical reactions. It provides exciting opportunities to manipulate polymer structures, to discover new reaction pathways, and to devise environmentally friendly processes. It also benefits from
innovations in biotechnology which enables cheaper and improved enzymes to be made and customized polymeric materials to be produced in vivo using metabolic engineering. Biobased materials also represent an equally exciting opportunity that has found many industrial and medical applications. There is
commonality with biocatalysis because many biobased products are biodegradable, where enzymes and/or microbes are involved.
This book was compiled and edited in view of the success of the Philadelphia symposium, and the fact that this field is multidisciplinary where publications tend to be spread out over journals in different disciplines.
目次
- Preface
- 1. Green Polymer Chemistry: A Brief Review
- H. N. Cheng, Patrick B. Smith, and Richard A. Gross
- Enzymatic Biocatalysis: Lipases
- 2. Enzyme-Based Technologies: Perspectives and Opportunities
- Alan S. Campbell, Chenbo Dong, Nianqiang Wu, Jonathan S. Dordick, and
- Cerasela Zoica Dinu
- 3. Lipase-Catalyzed Synthesis of Poly(amine-co-esters) and
- Poly(lactone-co-?-amino esters)
- Zhaozhong Jiang
- 4. Metrology as a Tool To Understand Immobilized Enzyme Catalyzed
- Ring-Opening Polymerization
- Matthew T. Hunley, Sara V. Orski, and Kathryn L. Beers
- 5. Syntheses and Characterization of Aliphatic Polyesters via Yarrowia
- lipolytica Lipase Biocatalysis
- Karla A. Barrera-Rivera and Antonio Martinez-Richa
- 6. Microwave-Assisted Biocatalytic Polymerizations
- Anil Mahapatro and Taina D. Matos Negron
- 7. Green Polymer Chemistry: Enzymatic Functionalization of Poly(ethylene
- glycol)s Under Solventless Conditions
- Judit E. Puskas, Kwang Su Seo, Marcela Castano, Madalis Casiano, and
- Chrys Wesdemiotis
- 8. Biocatalysis for Silicone-Based Copolymers
- Stephen J. Clarson, Yadagiri Poojari, and Michael D. Williard
- Enzymatic Biocatalysis:
- Other Enzymes
- 9. Comparison of Polyester-Degrading Cutinases from Genus Thermobifida
- Fusako Kawai, Uschara Thumarat, Kengo Kitadokoro, Tomonori Waku,
- Tomoko Tada, Naoki Tanaka, and Takeshi Kawabata
- 10. <"Green>" Synthesis of Bisphenol Polymers and Copolymers, Mediated
- by Supramolecular Complexes of Laccase and Linear-Dendritic Block
- Copolymers
- Ivan Gitsov and Arsen Simonyan
- 11. Synthesis of New Polysaccharide Materials by Phosphorylase-Catalyzed
- Enzymatic ?-Glycosylations Using Polymeric Glycosyl Acceptors
- Jun-ichi Kadokawa
- 12. Biocatalytic ATRP: Controlled Radical Polymerizations Mediated by
- Enzymes
- Kasper Renggli, Mariana Spulber, Jonas Pollard, Martin Rother, and Nico Bruns
- Whole-Cell Biocatalysis
- 13. Microbial Plastic Factory: Synthesis and Properties of the New
- Lactate-Based Biopolymers
- John Masani Nduko, Ken'ichiro Matsumoto, and Seiichi Taguchi
- 14. Synthesis of Poly-(R)-3 Hydroxyoctanoate (PHO) and Its Graphene
- Nanocomposites
- Ahmed Abdala, John Barrett, and Friedrich Srienc
- 15. Biosynthesis of Polyhydroxyalkanoate by a Marine Bacterium Vibrio
- sp. Strain Using Sugars, Plant Oil, and Unsaturated Fatty Acids as Sole
- Carbon Sources
- Satoshi Tomizawa, Jo-Ann Chuah, Misato Ohtani, Taku Demura, and Keiji Numata
- 16. PEGylated Antibodies and DNA in Organic Media and Genetic
- PEGylation
- Seiichi Tada, Hiroshi Abe, and Yoshihiro Ito
- Biobased Materials: Polyesters
- 17. Effect of Polycondensation Conditions on Structure and Thermal
- Properties of Poly(caffeic acid)
- Daisuke Ishii, Hiroki Maeda, Hisao Hayashi, Tomohiko Mitani, Naoki Shinohara,
- Koichi Yoshioka, and Takashi Watanabe
- 18. Biodegradable Films and Foam of Poly(3-Hydroxybutyrate-co-3-
- hydroxyvalerate) Blended with Silk Fibroin
- Amy Tsui, Xiao Hu, David L. Kaplan, and Curtis W. Frank
- 19. Synthesis and NMR Characterization of Hyperbranched Polyesters from
- Trimethylolpropane and Adipic Acid
- Tracy Zhang, Bobby A. Howell, Paul K. Martin, Steven J. Martin, and
- Patrick B. Smith
- 20. Direct Fluorination of Poly(3-hydroxybutyrate-co)-hydroxyhexanoate
- Samsuddin F. Mahmood, Benjamin R. Lund, Sriram Yagneswaran, Shant Aghyarian,
- and Dennis W. Smith, Jr.
- Biobased Materials:
- Other Materials
- 21. Biobased Industrial Products from Soybean Biorefinery
- E. Hablot, D. Graiver, and R. Narayan
- 22. Applications of Common Beans in Food and Biobased Materials
- Atanu Biswas, William C. Lesch, and H. N. Cheng
- 23. Preparation and Characterization of Protein Isolate from Glandless and
- Glanded Cottonseed
- Michael K. Dowd and Milagros P. Hojilla-Evangelista
- 24. Hydrogenated Cottonseed Oil as Raw Material for Biobased Materials
- H. N. Cheng, Mason Rau, Michael K. Dowd, Michael W. Easson, and
- Brian D. Condon
- 25. Lignin-Based Graft Copolymers via ATRP and Click Chemistry
- Hoyong Chung, Amer Al-Khouja, and Newell R. Washburn
- 26. Esterification of Xylan and Its Application
- Noreen G. V. Fundador, Yukiko Enomoto-Rogers, and Tadahisa Iwata
- 27. Converting Polysaccharides into High-Value Thermoplastic Materials
- James H. Wang and Bo Shi
- 28. Use of Cotton Gin Trash and Compatibilizers in Polyethylene Composites
- H. N. Cheng, M. K. Dowd, V. L. Finkenstadt, G. W. Selling, R. L. Evangelista,
- and Atanu Biswas
- Epilogue
- Editors' Biographies
- Indexes
- Author Index
- Subject Index
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