Zeolites and catalysis : synthesis, reactions and applications

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Zeolites and catalysis : synthesis, reactions and applications

edited by Jiří Čejka, Avelino Corma, and Stacey Zones

Wiley-VCH, c2010

  • : set
  • v. 1
  • v. 2

Available at  / 5 libraries

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Includes bibliographical references and index

Description and Table of Contents

Description

Zeolites and Catalysis Microporous, aluminosilicate minerals with regularly structured pores offer access to a wide range of applications in both academia and industry. This indispensable two-volume handbook covery everything on the hot research field of zeolites. With information spread over two volumes: Volume 1 deals with the synthesis, modification, characterization and application of catalytic active zeolites, while Volume 2 focuses on such reaction types as cracking, hydrocracking, isomerization, reforming and other industrially important topics. Edited by a highly experienced and internationally renowned team with chapters written by the ?Who?s Who? of zeolite research, this set is valuable to catalytic, solid state, physical, and industrial chemists, chemical engineers, surface chemists and materials scientists

Table of Contents

Volume 1 Preface SYNTHESIS MECHANISM: CRYSTAL GROWTH AND NUCLEATION Introduction Theory of Nucleation and Growth Nucleation and Growth in Zeolites Techniques Case Studies Conclusions and Outlook SYNTHESIS APPROACHES Introduction Aluminophosphates Mineralizers Dry Gel Conversion Syntheses Low Water Syntheses Germanium Zeolites Isomorphous Substitution Structure-Directing Agents SDA Modeling Co-Templating Layered Precursors Nonaqueous Solvents Summary and Outlook IONOTHERMAL SYNTHESIS OF ZEOLITES AND OTHER POROUS MATERIALS Introduction Hydrothermal, Solvothermal, and Ionothermal Synthesis Ionothermal Aluminophosphate Synthesis Ionothermal Synthesis of Silica-Based Zeolites Ionothermal Synthesis of Metal Organic Frameworks and Coordination Polymers Ambient Pressure Ionothermal Synthesis The Role of Cation-Templating, Co-Templating, or No Templating The Role of Anion - Structure Induction The Role of Water and Other Mineralizers Unstable Ionic Liquids Summary and Outlook CO-TEMPLATES IN SYNTHESIS OF ZEOLITES Introduction Templating of Dual-Void Structures Crystallization of Aluminophosphate-Type Materials Combined Use of Templating and Pore-Filling Agents Cooperative Structure-Directing Effects of Organic Molecules and Mineralizing Anions Cooperative Structure-Directing Effect of Organic Molecules and Water Control of Crystal Size and Morphology Membrane Systems Use of Co-Templates for Tailoring the Catalytic Activity of Microporous Materials Summary and Outlook MORPHOLOGICAL SYNTHESIS OF ZEOLITES Introduction Morphology of Large Zeolite Crystals Morphology Control of MFI Zeolite Particles Morphological Synthesis by MW Summary and Outlook POST-SYNTHETIC TREATMENT AND MODIFICATION OF ZEOLITES Introduction Direct Synthesis of Zeolites Post-Synthetic Treatment and Modification of Zeolites Summary and Outlook STRUCTURAL CHEMISTRY OF ZEOLITES Introduction Zeolite Structure Types Exemplified by Those Based on the Sodalite Cage The Expanding Library of Zeolite Structures: Novel Structures, Novel Features Summary and Outlook VIBRATIONAL SPECTROSCOPY AND RELATED IN SITU STUDIES OF CATALYTIC REACTIONS WITHIN MOLECULAR SIEVES Introduction Acidity Determination with IR Spectroscopy of Probe Molecules Zeolite Synthesis Processes Selection of Zeolite-Based Catalytic Reactions IR Microspectroscopy Concluding Remarks and Look into the Future TEXTURAL CHARACTERIZATION OF MESOPOROUS ZEOLITES Introduction Methods for Generating Meso- and Macropores in Zeolites Characterization of Textural Properties of Mesoporous Zeolites Summary and Outlook ALUMINUM IN ZEOLITES: WHERE IS IT AND WHAT IS ITS STRUCTURE? Introduction Structure of Aluminum Species in Zeolites Where is the Aluminum in Zeolite Crystals? Summary and Outlook THEORETICAL CHEMISTRY OF ZEOLITE REACTIVITY Introduction Methodology Activation of Hydrocarbons in Zeolites: The Role of Dispersion Interactions Molecular-Level Understanding of Complex Catalytic Reactions: MTO Process Molecular Recognition and Confinement-Driven Reactivity Structural Properties of Zeolites: Framework Al Distribution and Structure and Charge Compensation of Extra-Framework Cations Summary and Outlook MODELING OF TRANSPORT AND ACCESSIBILITY IN ZEOLITES Introduction Molecular Models Simulation Methods Molecular Modeling Applied to Processes Involving Zeolites Summary and Outlook DIFFUSION IN ZEOLITES - IMPACT ON CATALYSIS Introduction Diffusion and Reaction in Zeolites: Basic Concepts Diffusion in Zeolites: Potential Issues Pore Structure, Diffusion, and Activity at the Subcrystal Level Improving Transport through Zeolite Crystals Concluding Remarks and Future Outlook Volume 2 Preface SPECIAL APPLICATIONS OF ZEOLITES Introduction Zeolite Membranes Host-Guest Interactions Medical and Veterinary Applications Other Applications Summary and Outlook ORGANIZATION OF ZEOLITE MICROCRYSTALS Introduction Organization of Zeolite Microcrystals into Functional Materials by Self-Assembly Monolayer Assembly of Zeolite Microcrystals by Dry Manual Assembly Current and Future Applications Summary and Outlook INDUSTRIAL POTENTIAL OF ZEOLITES Introduction Application of Zeolites in Slurry Processes Rebalancing the Refinery Products Slate Advanced Separation Technologies Zeolites and Environmental Protection: Groundwater Remediation New Materials for Emerging Applications Summary and Outlook CATALYTICALLY ACTIVES SITES: GENERATION AND CHARACTERIZATION Introduction Acid Sites in Zeolites Characterization of Acid Sites Base Catalysis Characterization of Base Sites in Zeolites Metal Clusters in Zeolites Characterization of Metal Clusters in Zeolites Summary and Outlook CRACKING AND HYDROCRACKING Introduction FCC Hydrocracking Summary and Outlook NAPHTHA REFORMING AND UPGRADING OF DIESEL FRACTIONS Introduction Catalytic Reforming Upgrading Diesel Fractions: Catalytic Dewaxing Summary and Outlook RECENT DEVELOPMENT IN TRANSFORMATIONS OF AROMATIC HYDROCARBONS OVER ZEOLITES Introduction Zeolites under Study Toluene Disproportionation Ethylbenzene Disproportionation Disproportionation and Transalkylation of Trimethylbenezene Alkylation of Aromatics Miscellaneous Summary and Outlook ADVANCED CATALYSTS BASED ON MICRO- AND MESOPOROUS MOLECULAR SIEVES FOR THE CONVERSION OF NATURAL GAS TO FUELS AND CHEMICALS Introduction Direct Conversion of Methane Syngas Conversion Processes Summary and Outlook METHANOL TO OLEFINS (MTO) AND METHANOL TO GASOLINE (MTG) Introduction Mechanism and Kinetics of the MTO and MTG Reactions Methanol to Olefins (MTO) Methanol to Gasoline (MTG) Methanol to Propene (MTP) TIGAS Process Mobil?s Olefin-to-Gasoline and Distillate Process (MOGD) Summary and Outlook METALS IN ZEOLITES FOR OXIDATION CATALYSIS Introduction Titanium-Containing Zeolites Other-Metal-Containing Zeolites Conclusion ENVIRONMENTAL CATALYSIS OVER ZEOLITES Introduction A Glimpse into Opportunities and Issues Fields of Applications Summary and Outlook ZEOLITES AS CATALYSTS FOR THE SYNTHESIS OF FINE CHEMICALS Introduction Acid-Catalyzed Reactions Base-Catalyzed Reactions Summary and Outlook ZEOLITES AND MOLECULAR SIEVES IN FUEL CELL APPLICATIONS Introduction Zeolites in Electrolyte Membrane Zeolite Electrocatalysts Zeolites and Molecular Sieves in Fuel Processing Summary and Outlook

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Details

  • NCID
    BB08131998
  • ISBN
    • 9783527325146
  • Country Code
    gw
  • Title Language Code
    eng
  • Text Language Code
    eng
  • Place of Publication
    Weinheim
  • Pages/Volumes
    2 v.
  • Size
    25 cm
  • Classification
  • Subject Headings
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