Introduction to geochemistry : principles and applications
著者
書誌事項
Introduction to geochemistry : principles and applications
Wiley-Blackwell, 2012
- : cloth
- : pbk
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注記
Includes bibliographical references (p. [406]-429) and index
内容説明・目次
- 巻冊次
-
: pbk ISBN 9781405121422
内容説明
This book is intended to serve as a text for an introductory course in geochemistry for undergraduate/graduate students with at least an elementary-level background in earth sciences, chemistry, and mathematics. The text, containing 83 tables and 181 figures, covers a wide variety of topics - ranging from atomic structure to chemical and isotopic equilibria to modern biogeochemical cycles - which are divided into four interrelated parts: Crystal Chemistry; Chemical Reactions (and biochemical reactions involving bacteria); Isotope Geochemistry (radiogenic and stable isotopes); and The Earth Supersystem, which includes discussions pertinent to the evolution of the solid Earth, the atmosphere, and the hydrosphere. In keeping with the modern trend in the field of geochemistry, the book emphasizes computational techniques by developing appropriate mathematical relations, solving a variety of problems to illustrate application of the mathematical relations, and leaving a set of questions at the end of each chapter to be solved by students. However, so as not to interrupt the flow of the text, involved chemical concepts and mathematical derivations are separated in the form of boxes. Supplementary materials are packaged into ten appendixes that include a standard-state (298.15 K, 1 bar) thermodynamic data table and a listing of answers to selected chapter-end questions.
Additional resources for this book can be found at: www.wiley.com/go/misra/geochemistry.
目次
Preface xiii
1 Introduction 1
Part I Crystal Chemistry 7
2 Atomic Structure 9
3 Chemical Bonding 23
Part II Chemical Reactions 49
4 Basic Thermodynamic Concepts 51
5 Thermodynamics of Solutions 79
6 Geothermometry and Geobarometry 107
7 Reactions Involving Aqueous Solutions 134
8 Oxidation-Reduction Reactions 167
9 Kinetics of Chemical Reactions 197
Part III Isotope Geochemistry 223
10 Radiogenic Isotopes 225
11 Stable Isotopes 253
Part IV The Earth Supersystem 281
12 The Core-Mantle-Crust System 283
13 The Crust-Hydrosphere-Atmosphere System 326
Appendix 1 Units of measurement and physical constants 372
Appendix 2 Electronic configurations of elements in ground state 374
Appendix 3 First ionization potential, electron affinity, electronegativity (Pauling scale), and coordination numbers of selected elements 377
Appendix 4 Thermodynamic symbols 379
Appendix 5 Standard state (298.15 K, 105 Pa) thermodynamic data for selected elements, ionic species, and compounds 382
Appendix 6 Fugacities of H2O and CO2 in the range 0.5-10.0 kbar and 200-1000 DegreesC 396
Appendix 7 Equations for activity coefficients in multicomponent regular solid solutions 398
Appendix 8 Some commonly used computer codes for modeling of geochemical processes in aqueous solutions 400
Appendix 9 Solar system abundances of the elements in units of number of atoms per 106 silicon atoms 402
Appendix 10 Answers to selected chapter-end questions 403
References 406
Index 431
- 巻冊次
-
: cloth ISBN 9781444350951
内容説明
This book is intended to serve as a text for an introductory course in geochemistry for undergraduate/graduate students with at least an elementary level background in earth sciences, chemistry, and mathematics. The text, containing 83 tables and 181 figures, covers a wide variety of topics ranging from atomic structure to chemical and isotopic equilibria to modern biogeochemical cycles which are divided into four interrelated parts: Crystal Chemistry; Chemical Reactions (and biochemical reactions involving bacteria); Isotope Geochemistry (radiogenic and stable isotopes); and The Earth Supersystem, which includes discussions pertinent to the evolution of the solid Earth, the atmosphere, and the hydrosphere. In keeping with the modern trend in the field of geochemistry, the book emphasizes computational techniques by developing appropriate mathematical relations, solving a variety of problems to illustrate application of the mathematical relations, and leaving a set of questions at the end of each chapter to be solved by students. However, so as not to interrupt the flow of the text, involved chemical concepts and mathematical derivations are separated in the form of boxes.
Supplementary materials are packaged into ten appendixes that include a standard state (298.15 K, 1 bar) thermodynamic data table and a listing of answers to selected chapter end questions. Additional resources for this book can be found at: www.wiley.com/go/misra/geochemistry.
目次
Preface, xiii 1 Introduction, 1 PART I CRYSTAL CHEMISTRY, 7 2 Atomic Structure, 9 3 Chemical Bonding, 23 PART II CHEMICAL REACTIONS, 49 4 Basic Thermodynamic Concepts, 51 5 Thermodynamics of Solutions, 79 6 Geothermometry and Geobarometry, 107 7 Reactions Involving Aqueous Solutions, 134 8 Oxidation Reduction Reactions, 167 9 Kinetics of Chemical Reactions, 197 PART III ISOTOPE GEOCHEMISTRY, 223 10 Radiogenic Isotopes, 225 11 Stable Isotopes, 253 PART IV THE EARTH SUPERSYSTEM, 281 12 The Core Mantle Crust System, 283 13 The Crust Hydrosphere Atmosphere System, 326 APPENDIX 1 Units of measurement and physical constants, 372 APPENDIX 2 Electronic configurations of elements in ground state, 374 APPENDIX 3 First ionization potential, electron affinity, electronegativity (Pauling scale), and coordination numbers of selected elements, 377 APPENDIX 4 Thermodynamic symbols, 379 APPENDIX 5 Standard state (298.15 K, 105 Pa) thermodynamic data for selected elements, ionic species, and compounds, 382 APPENDIX 6 Fugacities of H2O and CO2 in the range 0.5 10.0 kbar and 200 1000 C, 396 APPENDIX 7 Equations for activity coefficients in multicomponent regular solid solutions, 398 APPENDIX 8 Some commonly used computer codes for modeling of geochemical processes in aqueous solutions, 400 APPENDIX 9 Solar system abundances of the elements in units of number of atoms per 106 silicon atoms, 402 APPENDIX 10 Answers to selected chapter end questions, 403 References, 406 Index, 431
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