Cobalt oxides : from crystal chemistry to physics

著者

書誌事項

Cobalt oxides : from crystal chemistry to physics

Bernard Raveau and Md. Motin Seikh

Wiley-VCH, c2012

  • : hbk.

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注記

Includes bibliographical references and index

内容説明・目次

内容説明

Unparalleled in the breadth and depth of its coverage of all important aspects, this book systematically treats the electronic and magnetic properties of stoichiometric and non-stoichiometric cobaltites in both ordered and disordered phases. Authored by a pioneer and a rising star in the field, the monograph summarizes, organizes and streamlines the otherwise difficult-to-obtain information on this topic. An introductory chapter sets forth the crystal chemistry of cobalt oxides to lay the groundwork for an understanding of the complex phenomena observed in this materials class. Special emphasis is placed on a comprehensive discussion of cobaltite physical properties in different structural families. Providing a thorough introduction to cobalt oxides from a chemical and physical viewpoint as a basis for understanding their intricacies, this is a must-have for both experienced researchers as well as entrants to the field.

目次

PREFACE CRYSTAL CHEMISTRY OF COBALT OXIDES Introduction Stoichiometric Perovskites LnCoO3 Stoichiometric Ln1_x AxCoO3 Perovskites (A1/4Ca, Sr,Ba) Oxygen-Deficient Perovskites: Order-Disorder Phenomena in the Distribution of Anionic Vacancies The Ordered Double Stoichiometric Perovskite LaBaCo2O6 Hexagonal Perovskite and Derivatives The RP-Type Cobaltites: Intergrowths of Perovskite and Rock Salt Layers and Derivatives Cobaltites with a Triangular Lattice Some Other Original Cobaltites ELECTRONIC AND MAGNETIC PROPERTIES OF STOICHIOMETRIC PEROVSKITE COBALTITES Stoichiometric LnCoO3 Perovskites Stoichiometric SrCoO3: Ferromagnetism and Metallic Conductivity Stoichiometric Ln1_xAxCoO3 Perovskites (A 1/4 Ca, Sr, and Ba) The " Ordered " Double Stoichiometric Perovskite LaBaCo2O6 ELECTRONIC AND MAGNETIC PROPERTIES OF OXYGEN-DEFICIENT PEROVSKITE COBALTITES SR1_XLNXCOO3_D AND SRCO1_XMXO3_D Disordered Perovskites Ordered 112 LnBaCo2O5+d Perovskites ELECTRONIC AND MAGNETIC PROPERTIES OF RUDDLESDEN-POEPPER-TYPE COBALTITES Cobalt Valence and Spin State Transitions Magnetic Properties of RP Phases Electrical Properties of RP Phases Phase Separation in RP Phases Magnetoresistance of RP Phases Thermoelectric Properties of RP Phases ELECTRONIC AND MAGNETIC PROPERTIES OF COBALTITES WITH A 3D "TRIANGULAR LATTICE" The Co3O4 Spinel and Derivatives The "114" LnBaCo4O7 and CaBaCo4O7 Cobaltites ELECTRONIC AND MAGNETIC PROPERTIES OF "TRIANGULAR" LAYERED COBALTITES The Layer Sodium Cobaltites NaxCoO2 Misfit Cobaltites ELECTRONIC AND MAGNETIC PROPERTIES OF THE "UNIDIMENSIONAL" COBALTITE CA3CO2O6 Valence and Spin State of Cobalt Magnetic Properties of 1D-Ca3Co2O6 and Related Derivatives Electrical Resistivity of Ca3Co2O6 and Derivatives Magnetoresistance of Ca3Co2O6 Thermoelectric Power of Ca3Co2O6 and Derivatives

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