Nanomaterials in catalysis

Author(s)

    • Serp, Philippe
    • Philippot, Karine

Bibliographic Information

Nanomaterials in catalysis

edited by Philippe Serp and Karine Philippot ; with a foreword by Gabor A. Somorjai and Bruno Chaudret

Wiley-VCH, c2013

Available at  / 7 libraries

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Includes bibliographical references and index

Description and Table of Contents

Description

Nanocatalysis has emerged as a field at the interface between homogeneous and heterogeneous catalysis and offers unique solutions to the demanding requirements for catalyst improvement. Heterogeneous catalysis represents one of the oldest commercial applications of nanoscience and nanoparticles of metals, semiconductors, oxides, and other compounds have been widely used for important chemical reactions. The main focus of this fi eld is the development of well-defined catalysts, which may include both metal nanoparticles and a nanomaterial as the support. These nanocatalysts should display the benefits of both homogenous and heterogeneous catalysts, such as high efficiency and selectivity, stability and easy recovery/recycling. The concept of nanocatalysis is outlined in this book and, in particular, it provides a comprehensive overview of the science of colloidal nanoparticles. A broad range of topics, from the fundamentals to applications in catalysis, are covered, without excluding micelles, nanoparticles in ionic liquids, dendrimers, nanotubes, and nanooxides, as well as modeling, and the characterization of nanocatalysts, making it an indispensable reference for both researchers at universities and professionals in industry.

Table of Contents

FOREWORD PREFACE CONCEPTS IN NANOCATALYSIS Introduction The Impact of the Intrinsic Properties of Nanomaterials on Catalysis How can Nanocatalyst Properties be Tailored? Nanocatalysis: Applications in Chemical Industry Conclusions and Perspectives METALLIC NANOPARTICLES IN NEAT WATER FOR CATALYTIC APPLICATIONS Introduction Synthesis of Nanoparticles in Water: The State of The Art Water-Soluble Protective Agents and their use in Nanocatalysis Conclusion and Perspectives CATALYSIS BY DENDRIMER-STABILIZED AND DENDRIMER-ENCAPSULATED LATE-TRANSITION-METAL NANOPARTICLES Introduction Synthesis Homogeneous Catalysis with DENs Generated from PAMAM and PPI Dendrimers Highly Efficient 'click'-Dendrimer-Encapsulated and Stabilized Pd Nanoparticle Pre-Catalysts Heterogeneous Catalysis Electrocatalysis Conclusion and Outlook NANOSTRUCTURED METAL PARTICLES FOR CATALYSTS AND ENERGY-RELATED MATERIALS General Survey Nanostructured Clusters and Colloids as Catalyst Precursors Nanostructured Materials in Energy-Related Processes Characterization of Nanostructured Metallic Catalyst Precursors and their Interaction with Coatings and Supports Using X-ray Absorption Spectroscopy METALLIC NANOPARTICLES IN IONIC LIQUIDS - APPLICATIONS IN CATALYSIS Introduction Interactions between Ionic Liquids and Metallic Nanoparticles Catalytic Applications Conclusions SUPPORTED IONIC LIQUID THIN FILM TECHNOLOGY Introduction Nanoparticle Catalysis with Supported Ionic Liquids Benefits for Synthesis and Processes Conclusion NANOSTRUCTURED MATERIALS SYNTHESIS IN SUPERCRITICAL FLUIDS FOR CATALYSIS APPLICATIONS Introduction: Properties of Supercritical Fluids Synthesis of Nanopowders as Nanocatalysts in SCFs Synthesis of Supported Nanoparticles as Nanocatalysts in SCFs Supercritical Microfluidic Synthesis of Nanocrystals Conclusion RECOVERY OF METALLIC NANOPARTICLES Introduction Immobilization on a Solid Support Multiple Phases Precipitation and Redispersion Magnetic Separation Filtration Conclusions CARBON NANOTUBES AND RELATED CARBONACEOUS STRUCTURES Introduction Carbon Nanotubes as Nanosupport Purification and Functionalization Preparation of CNT-Supported Catalysts Applications of CNT-Supported Catalysts Other Related Carbonaceous Materials Summary NANO-OXIDES Introduction Synthesis and Characterization of Nano-oxides Catalytic Applications of Nano-oxides Conclusions and Perspectives CONFINEMENT EFFECTS IN NANOSUPPORTS Introduction Confinement Effects in Carbon Nanotubes Metal Catalyst-Free Chemical Reactions inside Carbon Nanotubes Catalytic Reactions over Metal Particles Confined Inside Carbon Nanotubes Summary IN SILICO NANOCATALYSIS WITH TRANSITION METAL PARTICLES: WHERE ARE WE NOW? Introduction Surface Chemistry and Chemistry on Facets of Nanoparticles: Is it the Same? Electronic and Geometric Factors that Determine the Reactivity of Metal Surfaces Theoretical Studies of Multistep Pathways CONCLUSION INDEX

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