Functional metal oxides : new science and novel applications

著者

• Ogale, Satischandra B.
• Venkatesan, T
• Blamire, Mark G

書誌事項

Functional metal oxides : new science and novel applications

edited by Satishchandra B. Ogale, Thirumalai V. Venkatesan, and Mark G. Blamire

Wiley-VCH, c2013

• hbk.
• ePDF
• ePub
• Mobi
• oBook

注記

Also issued online

Includes references and index

内容説明・目次

巻冊次

hbk. ISBN 9783527331796

内容説明

Functional oxides are used both as insulators and metallic conductors in key applications across all industrial sectors. This makes them attractive candidates in modern technology ? they make solar cells cheaper, computers more efficient and medical instrumentation more sensitive. Based on recent research, experts in the field describe novel materials, their properties and applications for energy systems, semiconductors, electronics, catalysts and thin films. This monograph is divided into 6 parts which allows the reader to find their topic of interest quickly and efficiently. * Magnetic Oxides * Dopants, Defects and Ferromagnetism in Metal Oxides * Ferroelectrics * Multiferroics * Interfaces and Magnetism * Devices and Applications This book is a valuable asset to materials scientists, solid state chemists, solid state physicists, as well as engineers in the electric and automotive industries.

目次

• PREFACE PART I: Magnetic Oxides INTRODUCTION TO MAGNETIC OXIDES Oxide Structures and Crystal Chemistry Oxide Growth Magnetic Properties of 3d and 4f Ions Magnetic Interactions in Oxides Concentrated Magnetic Oxides Dilute Magnetic Oxides Conclusions MAGNETIC/MULTIFUNCTIONAL DOUBLE PEROVSKITE OXIDE THIN FILMS Introduction Thin-Film Deposition Structure and Morphology Electronic Structure Physical Properties Applications of Multifunctional Oxides Future Directions PART II: Dopants, Defects and Ferromagnetism in Metal Oxides MAGNETIC OXIDE SEMICONDUCTORS: ON THE HIGH-TEMPERATURE FERROMAGNETISM IN TIO2- AND ZNO-BASED COMPOUNDS Introduction Properties of (Ti,Co)O2 Properties of Transition-Metal-Doped ZnO Discussion Summary and Outlooks EFFECT OF TA ALLOYING ON THE OPTICAL, ELECTRONIC, AND MAGNETIC PROPERTIES OF TIO2 THIN FILMS Introduction Ta Substitution in TiO2: Doping or Alloying? Diluted Magnetic Semiconductors (DMS) Defect-Mediated Ferromagnetism Magnetic Impurity Analysis in Ti1-xTaxO2 System Defect-Induced Ferromagnetism in Ti1-xTaxO2 Film First-Principles Spin-Polarized GGA + U Calculations Mechanism of Defect-Mediated FM Optimization of Ferromagnetism Outlook for Defect-Mediated Properties of Ti1-xTaxO2 DEFECT-INDUCED OPTICAL AND MAGNETIC PROPERTIES OF COLLOIDAL TRANSPARENT CONDUCTING OXIDE NANOCRYSTALS Introduction Colloidal Transition-Metal-Doped Transparent Conducting Oxide Nanocrystals Native Defects in Colloidal Transparent Conducting Oxide Nanocrystals Summary and Outlook PART III: Ferroelectrics STRUCTURE - PROPERTY CORRELATIONS IN RARE-EARTH-SUBSTITUTED BIFEO3 EPITAXIAL THIN FILMS AT THE MORPHOTROPIC PHASE BOUNDARY Introduction Combinatorial Discovery of a MPB in Sm-substituted BiFeO3 (Sm-BFO) Structural Evolution across the MPB in Sm-BFO Universal Behavior in RE-Substituted BFO Structural Fingerprint of MPB in RE-Substituted BFO Chemical-Substitution-Induced Polarization Rotation in BFO Concluding Remarks and Future Perspectives ANTIFERROELECTRICITY IN OXIDES: A REEXAMINATION Introduction Definition and Characteristic Properties Microscopic Origins of Macroscopic Behavior Antiferroelectric Materials: Structure and Properties Relation to Alternative Ferroelectric Phases Antiferroelectricity in Thin Films Properties for Applications Prospects PART IV: Multiferroics PROBING NANOSCALE ELECTRONIC CONDUCTION IN COMPLEX OXIDES Scanning-Probe-Based Transport Measurements Domain Wall Conductivity Photovoltaic Effects at Domain Walls Local Characterization of Doped Oxides and Defects Local Electronic Probing of Oxide Interfaces Nanoscale Electronic Properties of CMR Manganites Future Directions MULTIFERROICS WITH MAGNETOELECTRIC COUPLING Introduction: Ferroic Materials Principles of Symmetry Analysis Magnetoelectric Couplings and a Landau-Like Theory Chemical Considerations Classification of Multiferroics Multiferroic Materials and Mechanisms Microscopic Mechanisms of Magnetic Ferroelectricity: Type II Multiferroics Domains and Metal - Insulator Transition PART V: Interfaces and Magnetism DEVICE ASPECTS OF THE SRTIO3 - LAALO3 INTERFACE
• BASIC PROPERTIES, MOBILITY, NANOSTRUCTURING, AND POTENTIAL APPLICATIONS Introduction The LaAlO3/SrTiO3 Interface: Key Characteristics and Understanding Charge-Carrier Mobility Micro/Nanostructuring Electric Field Gating Applications X-RAY SPECTROSCOPIC STUDIES OF CONDUCTING INTERFACES BETWEEN TWO INSULATING OXIDES Introduction Photoemission Measurements of Interfaces Interfaces between a Mott Insulator and a Band Insulator: LaAlO3/LaVO3 and LaTiO3/SrTiO3 Interfaces between Two Band Insulators: LaAlO3/SrTiO3 Summary INTERFACIAL COUPLING BETWEEN OXIDE SUPERCONDUCTORS AND FERROMAGNETS Introduction Experimental Results Materials Considerations Conclusions PART VI: Devices and Applications METAL-OXIDE NANOPARTICLES FOR DYE-SENSITIZED SOLAR CELLS TiO2: Polymorphism, Optoelectronic Properties, and Bandgap Engineering Principle and Basis of Dye-Sensitized Solar Cell (DSC) Technology Progress in TiO2 Engineering for Improved Charge-Collection Efficiency and Light Confinement Development of Molecular Sensitizers Suited to TiO2 Optoelectronic Properties Development of Redox Mediators Conclusions HYBRID SOLAR CELLS FROM ORDERED NANOSTRUCTURES Introduction Working Mechanisms of Hybrid Solar Cells Nanostructures for Hybrid Solar Cells Metal Oxide Modifications Conclusion and Outlook ELECTRIC FIELD EFFECTS IN FUNCTIONAL METAL OXIDES Introduction Developments of Gate Dielectrics: from High-k Oxides to Ionic Electrolytes Electric-Field-Induced Modulation of Ferromagnetism Electrostatic Modulation of Superconductivity Transparent Amorphous Metal-Oxide Field-Effect Transistors Solution-Processable Transparent Amorphous Metal Oxides for Thin-Film Transistors Challenges and Opportunities RESISTIVE SWITCHINGS IN TRANSITION-METAL OXIDES Introduction Classification of Current - Voltage Hystereses Bipolar Continuous Switching Toward Device Applications and Summary INDEX

巻冊次

oBook ISBN 9783527654864

内容説明

This forward-looking title focuses on the key innovations for industrial growth areas for functional metal oxides: energy technology, semiconductors, electronics, and automotive.Bridging the gap between basic science and technological applications, the book covers the full range of topics in the field of advanced metal oxide science and technology such as metallic, semiconducting, insulating, ferromagnetic, superconducting, ferroelectric, and multiferroic metal oxide systems and their engineered interface systems. It emphasizes many of the modern applications of metal oxides in solar cells, batteries, catalysis and for resistive switches. Chapters about the growth and processing of oxidic thin films and nanomaterials round the topic out.

巻冊次

Mobi ISBN 9783527654871

内容説明

Functional oxides are used both as insulators and metallic conductors in key applications across all industrial sectors. This makes them attractive candidates in modern technology ? they make solar cells cheaper, computers more efficient and medical instrumentation more sensitive. Based on recent research, experts in the field describe novel materials, their properties and applications for energy systems, semiconductors, electronics, catalysts and thin films. This monograph is divided into 6 parts which allows the reader to find their topic of interest quickly and efficiently. * Magnetic Oxides * Dopants, Defects and Ferromagnetism in Metal Oxides * Ferroelectrics * Multiferroics * Interfaces and Magnetism * Devices and Applications This book is a valuable asset to materials scientists, solid state chemists, solid state physicists, as well as engineers in the electric and automotive industries.

目次

• PREFACE PART I: Magnetic Oxides INTRODUCTION TO MAGNETIC OXIDES Oxide Structures and Crystal Chemistry Oxide Growth Magnetic Properties of 3d and 4f Ions Magnetic Interactions in Oxides Concentrated Magnetic Oxides Dilute Magnetic Oxides Conclusions MAGNETIC/MULTIFUNCTIONAL DOUBLE PEROVSKITE OXIDE THIN FILMS Introduction Thin-Film Deposition Structure and Morphology Electronic Structure Physical Properties Applications of Multifunctional Oxides Future Directions PART II: Dopants, Defects and Ferromagnetism in Metal Oxides MAGNETIC OXIDE SEMICONDUCTORS: ON THE HIGH-TEMPERATURE FERROMAGNETISM IN TIO2- AND ZNO-BASED COMPOUNDS Introduction Properties of (Ti,Co)O2 Properties of Transition-Metal-Doped ZnO Discussion Summary and Outlooks EFFECT OF TA ALLOYING ON THE OPTICAL, ELECTRONIC, AND MAGNETIC PROPERTIES OF TIO2 THIN FILMS Introduction Ta Substitution in TiO2: Doping or Alloying? Diluted Magnetic Semiconductors (DMS) Defect-Mediated Ferromagnetism Magnetic Impurity Analysis in Ti1-xTaxO2 System Defect-Induced Ferromagnetism in Ti1-xTaxO2 Film First-Principles Spin-Polarized GGA + U Calculations Mechanism of Defect-Mediated FM Optimization of Ferromagnetism Outlook for Defect-Mediated Properties of Ti1-xTaxO2 DEFECT-INDUCED OPTICAL AND MAGNETIC PROPERTIES OF COLLOIDAL TRANSPARENT CONDUCTING OXIDE NANOCRYSTALS Introduction Colloidal Transition-Metal-Doped Transparent Conducting Oxide Nanocrystals Native Defects in Colloidal Transparent Conducting Oxide Nanocrystals Summary and Outlook PART III: Ferroelectrics STRUCTURE - PROPERTY CORRELATIONS IN RARE-EARTH-SUBSTITUTED BIFEO3 EPITAXIAL THIN FILMS AT THE MORPHOTROPIC PHASE BOUNDARY Introduction Combinatorial Discovery of a MPB in Sm-substituted BiFeO3 (Sm-BFO) Structural Evolution across the MPB in Sm-BFO Universal Behavior in RE-Substituted BFO Structural Fingerprint of MPB in RE-Substituted BFO Chemical-Substitution-Induced Polarization Rotation in BFO Concluding Remarks and Future Perspectives ANTIFERROELECTRICITY IN OXIDES: A REEXAMINATION Introduction Definition and Characteristic Properties Microscopic Origins of Macroscopic Behavior Antiferroelectric Materials: Structure and Properties Relation to Alternative Ferroelectric Phases Antiferroelectricity in Thin Films Properties for Applications Prospects PART IV: Multiferroics PROBING NANOSCALE ELECTRONIC CONDUCTION IN COMPLEX OXIDES Scanning-Probe-Based Transport Measurements Domain Wall Conductivity Photovoltaic Effects at Domain Walls Local Characterization of Doped Oxides and Defects Local Electronic Probing of Oxide Interfaces Nanoscale Electronic Properties of CMR Manganites Future Directions MULTIFERROICS WITH MAGNETOELECTRIC COUPLING Introduction: Ferroic Materials Principles of Symmetry Analysis Magnetoelectric Couplings and a Landau-Like Theory Chemical Considerations Classification of Multiferroics Multiferroic Materials and Mechanisms Microscopic Mechanisms of Magnetic Ferroelectricity: Type II Multiferroics Domains and Metal - Insulator Transition PART V: Interfaces and Magnetism DEVICE ASPECTS OF THE SRTIO3 - LAALO3 INTERFACE
• BASIC PROPERTIES, MOBILITY, NANOSTRUCTURING, AND POTENTIAL APPLICATIONS Introduction The LaAlO3/SrTiO3 Interface: Key Characteristics and Understanding Charge-Carrier Mobility Micro/Nanostructuring Electric Field Gating Applications X-RAY SPECTROSCOPIC STUDIES OF CONDUCTING INTERFACES BETWEEN TWO INSULATING OXIDES Introduction Photoemission Measurements of Interfaces Interfaces between a Mott Insulator and a Band Insulator: LaAlO3/LaVO3 and LaTiO3/SrTiO3 Interfaces between Two Band Insulators: LaAlO3/SrTiO3 Summary INTERFACIAL COUPLING BETWEEN OXIDE SUPERCONDUCTORS AND FERROMAGNETS Introduction Experimental Results Materials Considerations Conclusions PART VI: Devices and Applications METAL-OXIDE NANOPARTICLES FOR DYE-SENSITIZED SOLAR CELLS TiO2: Polymorphism, Optoelectronic Properties, and Bandgap Engineering Principle and Basis of Dye-Sensitized Solar Cell (DSC) Technology Progress in TiO2 Engineering for Improved Charge-Collection Efficiency and Light Confinement Development of Molecular Sensitizers Suited to TiO2 Optoelectronic Properties Development of Redox Mediators Conclusions HYBRID SOLAR CELLS FROM ORDERED NANOSTRUCTURES Introduction Working Mechanisms of Hybrid Solar Cells Nanostructures for Hybrid Solar Cells Metal Oxide Modifications Conclusion and Outlook ELECTRIC FIELD EFFECTS IN FUNCTIONAL METAL OXIDES Introduction Developments of Gate Dielectrics: from High-k Oxides to Ionic Electrolytes Electric-Field-Induced Modulation of Ferromagnetism Electrostatic Modulation of Superconductivity Transparent Amorphous Metal-Oxide Field-Effect Transistors Solution-Processable Transparent Amorphous Metal Oxides for Thin-Film Transistors Challenges and Opportunities RESISTIVE SWITCHINGS IN TRANSITION-METAL OXIDES Introduction Classification of Current - Voltage Hystereses Bipolar Continuous Switching Toward Device Applications and Summary INDEX

巻冊次

ePub ISBN 9783527654888

内容説明

This forward-looking title focuses on the key innovations for industrial growth areas for functional metal oxides: energy technology, semiconductors, electronics, and automotive. Bridging the gap between basic science and technological applications, the book covers the full range of topics in the field of advanced metal oxide science and technology such as metallic, semiconducting, insulating, ferromagnetic, superconducting, ferroelectric, and multiferroic metal oxide systems and their engineered interface systems. It emphasizes many of the modern applications of metal oxides in solar cells, batteries, catalysis and for resistive switches. Chapters about the growth and processing of oxidic thin films and nanomaterials round the topic out.

目次

MAGNETIC OXIDES Magnetic Oxides (Broad Perspective) Magnetic Oxides for Spintronics DILUTED MAGNETIC SEMICONDUCTOR OXIDES DEFECT FERROMAGNETSM IN OXIDE FILMS FERROELECTIRCS Ferroelectrics (Experiments) Multiferroics (Theory) SUPERCONDUCTING OXIDES Road to Higher Tc Superconductors Superconductor/Ferromagnet Interfaces OXIDE-OXIDE INTERFACES Oxide-Oxide Interfaces (Experiments) Oxide-Oxide Interfaces (Theory) OXIDE INTERFACES FOR TOPOLOGICAL INSULATORS ELECTRIC FIELD EFFECTS IN OXIDES APPLICATIONS Oxide Nanomaterial Based Solar Cells Oxide Nanomaterials for Catalysis/Photocatalysis Resistive Switching in Oxides Metal Oxides for Battery Applications MATERIALS GROWTH AND PROCESSING Advances in the Growth of Oxide Thin Films Nanomaterials Growth Issues

巻冊次

ePDF ISBN 9783527654895

内容説明

This forward-looking title focuses on the key innovations for industrial growth areas for functional metal oxides: energy technology, semiconductors, electronics, and automotive. Bridging the gap between basic science and technological applications, the book covers the full range of topics in the field of advanced metal oxide science and technology such as metallic, semiconducting, insulating, ferromagnetic, superconducting, ferroelectric, and multiferroic metal oxide systems and their engineered interface systems. It emphasizes many of the modern applications of metal oxides in solar cells, batteries, catalysis and for resistive switches. Chapters about the growth and processing of oxidic thin films and nanomaterials round the topic out.

目次

MAGNETIC OXIDES Magnetic Oxides (Broad Perspective) Magnetic Oxides for Spintronics DILUTED MAGNETIC SEMICONDUCTOR OXIDES DEFECT FERROMAGNETSM IN OXIDE FILMS FERROELECTIRCS Ferroelectrics (Experiments) Multiferroics (Theory) SUPERCONDUCTING OXIDES Road to Higher Tc Superconductors Superconductor/Ferromagnet Interfaces OXIDE-OXIDE INTERFACES Oxide-Oxide Interfaces (Experiments) Oxide-Oxide Interfaces (Theory) OXIDE INTERFACES FOR TOPOLOGICAL INSULATORS ELECTRIC FIELD EFFECTS IN OXIDES APPLICATIONS Oxide Nanomaterial Based Solar Cells Oxide Nanomaterials for Catalysis/Photocatalysis Resistive Switching in Oxides Metal Oxides for Battery Applications MATERIALS GROWTH AND PROCESSING Advances in the Growth of Oxide Thin Films Nanomaterials Growth Issues

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詳細情報

• NII書誌ID(NCID): BB1431593X
• ISBN:
  • 9783527331796
  • 9783527654895
  • 9783527654888
  • 9783527654871
  • 9783527654864
• 出版国コード: gw
• タイトル言語コード: eng
• 本文言語コード: eng
• 出版地: Weinheim
• ページ数/冊数: xxiii, 474 p.
• 大きさ: 25 cm
• 分類:
  • DC23 : 546.3
• 件名:
  • LCSH : Metallic oxides
  • LCSH : Metallic oxides -- Properties
  • LCSH : Metallic oxides -- Industrial applications