Crystalline state photoreactions : direct observation of reaction processes and metastable intermediates

Bibliographic Information

Crystalline state photoreactions : direct observation of reaction processes and metastable intermediates

Yuji Ohashi

Springer, c2014

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includes bibliographical references

Description and Table of Contents

Description

This book focuses on a variety of photochemical reaction processes in the crystalline state. The crystalline state reaction is a new category of solid state reaction, in which a reaction occurs with retention of the single crystal form. The whole reaction processes were observed directly by X-ray and neutron diffractions. In this book, not only the structures of metastable intermediates, such as radicals, carbenes, and nitrenes, but also the unstable species of photochromic compounds and photo-excited structures are shown with colored figures of the molecular structures, with more than 200 figures. The book is an indispensable resource not only for organic, inorganic and physical chemists but also for graduate students, as it furnishes more than 300 references.

Table of Contents

Introduction.- Crystalline State Reaction and Reaction Cavity.- Racemizations of Alkyl Groups in Cobaloxime Complex.- Characteristic Processes of Various Racemizations.- Photoisomerization of Alkyl Groups in Cobaloxime Complexes.- Control of Reactivity.- Metastable or Unstable Intermediates in Reversible Processes.- Metastable or Unstable Intermediates in Reversible Processes.- Conclusion.

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Details

  • NCID
    BB15956226
  • ISBN
    • 9784431543725
  • Country Code
    ja
  • Title Language Code
    eng
  • Text Language Code
    eng
  • Place of Publication
    Tokyo
  • Pages/Volumes
    xi, 208 p.
  • Size
    25cm
  • Classification
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