Ionic transport processes : in electrochemistry and membrane science

著者

    • Kontturi, Kyösti
    • Murtomäki, Lasse
    • Manzanares, José A.

書誌事項

Ionic transport processes : in electrochemistry and membrane science

Kyösti Kontturi and Lasse Murtomäki , José A. Manzanares

Oxford University Press, 2015

  • : pbk

大学図書館所蔵 件 / 全3件

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注記

Includes bibliographical references and index

"First published 2008"--T.p. verso

内容説明・目次

巻冊次

: pbk ISBN 9780198719991

内容説明

Modelling of heterogeneous processes, such as electrochemical reactions, extraction, or ion-exchange, usually requires solving the transport problem associated to the process. Since the processes at the phase boundary are described by scalar quantities and transport quantities are vectors or tensors, coupling them can take place only via conservation of mass, charge, or momentum. In this book, the transport of ionic species is addressed in a versatile manner, emphasizing the mutual coupling of fluxes in particular. Treatment is based on the formalism of irreversible thermodynamics, i.e. on linear (ionic) phenomenological equations, from which the most frequently used Nernst-Planck equation is derived. Limitations and assumptions made are thoroughly discussed. The Nernst-Planck equation is applied to selected problems at the electrodes and in membranes. Mathematical derivations are presented in detail so that the reader can learn the methodology of solving transport problems. Each chapter contains a large number of exercises, some of them more demanding than others.

目次

  • 1. Thermodynamics of irreversible processes
  • 2. Transport equations
  • 3. Transport at electrodes
  • 4. Transport in membranes
  • 5. Transport through liquid membranes
巻冊次

ISBN 9780199533817

内容説明

Modelling of heterogeneous processes, such as electrochemical reactions, extraction or ion-exchange, usually requires solving the transport problem associated to the process. Since the processes at the phase boundary are described by scalar quantities and transport quantities are vectors or tensors, coupling of them can take place only via conservation of mass, charge or momentum. In this book, transport of ionic species is addressed in a versatile manner, emphasizing the mutual coupling of fluxes in particular. Treatment is based on the formalism of irreversible thermodynamics, i.e. on linear (ionic) phenomenological equations, from which the most frequently used Nernst-Planck equation is derived. Limitations and assumptions made are thoroughly discussed. The Nernst-Planck equation is applied to selected problems at the electrodes and in membranes. Mathematical derivations are presented in detail so that the reader can learn the methodology of solving transport problems. Each chapter contains a large number of exercises, some of them more demanding than others.

目次

  • 1. Thermodynamics of Irreversible Processes
  • 2. Transport Equations
  • 3. Transport at Electrodes
  • 4. Transport in Membranes
  • 5. Transport Through Liquid Membranes

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