Controlled radical polymerization : Mechanisms
著者
書誌事項
Controlled radical polymerization : Mechanisms
（ACS symposium series, 1187）
American Chemical Society , Distributed in print by Oxford University Press, c2015
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注記
Other editors: Brent S. Sumerlin, Nicolay V. Tsarevsky, John Chiefari
Includes bibliographical references and index
内容説明・目次
内容説明
This book and the following volume (1188: Controlled Radical Polymerization: Materials) are addressed to chemists and polymer scientists interested in radical processes, and especially in controlled/living radical polymerization. The chapters in this first volume summarize the most recent advances in the field, including mechanistic, materials, and applications aspects. Controlled/living radical polymerization (CRP) or reversible-deactivation radical polymerization
(RDRP, as recommended by IUPAC) is among the most rapidly expanding areas of chemistry and polymer science.
This first volume provides an overview of the current status of controlled/living radical polymerization (CRP) systems, and also discusses important issues relevant to all radical polymerization methods. The mechanistic and kinetic aspects of ATRP are also covered, as well as more complex mechanisms such as "hybrid" processes.
Thirty-seven chapters published in two volumes show that there have been significant developments in CRP over the last 15 years. New systems have been discovered; substantial progress has been achieved in understanding the mechanism and kinetics of reactions involved in all CRP systems. As a result of these advances, significant progress has been made towards developing a comprehensive relationship between molecular structure and macroscopic properties. Several commercial applications of CRP
have been announced and it is anticipated that new products made by CRP will soon be on the market.
目次
1. Controlled Radical Polymerization: State-of-the-Art in 2014
2. Radical Ring-Opening Polymerization: Molecular Designs, Polymerization Mechanisms, and Living/Controlled Systems
3. Effects of Ionization on Tacticity and Propagation Kinetics in Methacrylic Acid Polymerization
4. ESR Investigations of Radicals by Various Magnetic Resonance Techniques with the Aid of ATRP
5. Catalyst Activity in ATRP, Determining Conditions for Well-Controlled Polymerizations
6. Tris(2-pyridylmethyl)amine Based Ligands in Copper Catalyzed Atom Transfer Radical Addition (ATRA) and Polymerization (ATRP)
7. Kinetic Studies of Elementary Reactions in SET-LRP / SARA ATRP
8. Visible Light-Induced Atom Transfer Radical Polymerization for Macromolecular Syntheses
9. Pushing Monomer Conversions High in Bulk ATRP: The Effects of ICAR Agent Concentrations on the System Livingness and Polymer Molecular Weight Control
10. Living Radical Polymerizations Using Sodium Iodide and Potassium Iodide as Catalysts
11. Photochemically Enabled Iodine Degenerative Transfer Controlled Radical Homo- and Block Copolymerization of Vinylidene Fluoride at Ambient Temperatures with Mn2(CO)10 and Visible Light
12. RAFT Polymerization -- Then and Now
13. Catalyst-Free Visible Light-Induced RAFT Photopolymerization
14. Simultaneous Control over Monomer Sequence and Molecular Weight Using the RAFT Process
15. Aqueous RAFT/MADIX Polymerization of Vinylphosphonic Acid under Microwave Irradiation
16. Organotellurium-Mediated Radical Polymerization under Photo Irradiation
17. The Interplay of ATRP, OMRP and CCT in Iron-Mediated Controlled Radical Polymerization
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