Controlled radical polymerization : Mechanisms

著者

書誌事項

Controlled radical polymerization : Mechanisms

Krzysztof Matyjaszewski, editor ... [et al.] ; sponsored by the ACS Division of Polymer Chemistry

(ACS symposium series, 1187)

American Chemical Society , Distributed in print by Oxford University Press, c2015

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注記

Other editors: Brent S. Sumerlin, Nicolay V. Tsarevsky, John Chiefari

Includes bibliographical references and index

内容説明・目次

内容説明

This book and the following volume (1188: Controlled Radical Polymerization: Materials) are addressed to chemists and polymer scientists interested in radical processes, and especially in controlled/living radical polymerization. The chapters in this first volume summarize the most recent advances in the field, including mechanistic, materials, and applications aspects. Controlled/living radical polymerization (CRP) or reversible-deactivation radical polymerization (RDRP, as recommended by IUPAC) is among the most rapidly expanding areas of chemistry and polymer science. This first volume provides an overview of the current status of controlled/living radical polymerization (CRP) systems, and also discusses important issues relevant to all radical polymerization methods. The mechanistic and kinetic aspects of ATRP are also covered, as well as more complex mechanisms such as "hybrid" processes. Thirty-seven chapters published in two volumes show that there have been significant developments in CRP over the last 15 years. New systems have been discovered; substantial progress has been achieved in understanding the mechanism and kinetics of reactions involved in all CRP systems. As a result of these advances, significant progress has been made towards developing a comprehensive relationship between molecular structure and macroscopic properties. Several commercial applications of CRP have been announced and it is anticipated that new products made by CRP will soon be on the market.

目次

1. Controlled Radical Polymerization: State-of-the-Art in 2014 2. Radical Ring-Opening Polymerization: Molecular Designs, Polymerization Mechanisms, and Living/Controlled Systems 3. Effects of Ionization on Tacticity and Propagation Kinetics in Methacrylic Acid Polymerization 4. ESR Investigations of Radicals by Various Magnetic Resonance Techniques with the Aid of ATRP 5. Catalyst Activity in ATRP, Determining Conditions for Well-Controlled Polymerizations 6. Tris(2-pyridylmethyl)amine Based Ligands in Copper Catalyzed Atom Transfer Radical Addition (ATRA) and Polymerization (ATRP) 7. Kinetic Studies of Elementary Reactions in SET-LRP / SARA ATRP 8. Visible Light-Induced Atom Transfer Radical Polymerization for Macromolecular Syntheses 9. Pushing Monomer Conversions High in Bulk ATRP: The Effects of ICAR Agent Concentrations on the System Livingness and Polymer Molecular Weight Control 10. Living Radical Polymerizations Using Sodium Iodide and Potassium Iodide as Catalysts 11. Photochemically Enabled Iodine Degenerative Transfer Controlled Radical Homo- and Block Copolymerization of Vinylidene Fluoride at Ambient Temperatures with Mn2(CO)10 and Visible Light 12. RAFT Polymerization -- Then and Now 13. Catalyst-Free Visible Light-Induced RAFT Photopolymerization 14. Simultaneous Control over Monomer Sequence and Molecular Weight Using the RAFT Process 15. Aqueous RAFT/MADIX Polymerization of Vinylphosphonic Acid under Microwave Irradiation 16. Organotellurium-Mediated Radical Polymerization under Photo Irradiation 17. The Interplay of ATRP, OMRP and CCT in Iron-Mediated Controlled Radical Polymerization

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詳細情報

  • NII書誌ID(NCID)
    BB21005025
  • ISBN
    • 9780841230484
  • LCCN
    2015015377
  • 出版国コード
    us
  • タイトル言語コード
    eng
  • 本文言語コード
    eng
  • 出版地
    Washington, DC,[New York]
  • ページ数/冊数
    x, 339 p., 4 p. of colored plates
  • 大きさ
    24 cm
  • 分類
  • 件名
  • 親書誌ID
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