Iron oxides : from nature to applications

著者

• Faivre, Damien
• Frankel, Richard B.

書誌事項

Iron oxides : from nature to applications

edited by Damien Faivre ; [with a foreword by Richard B. Frankel]

Wiley-VCH, c2016

注記

Includes bibliographical references and index

内容説明・目次

内容説明

Compiling all the information available on the topic, this ready reference covers all important aspects of iron oxides. Following a preliminary overview chapter discussing iron oxide minerals along with their unique structures and properties, the text goes on to deal with the formation and transformation of iron oxides, covering geological, synthetic, and biological formation, as well as various physicochemical aspects. Subsequent chapters are devoted to characterization techniques, with a special focus on X-ray-based methods, magnetic measurements, and electron microscopy alongside such traditional methods as IR/Raman and Mossbauer spectroscopy. The final section mainly concerns exciting new applications of magnetic iron oxides, for example in medicine as microswimmers or as water filtration systems, while more conventional uses as pigments or in biology for magnetoreception illustrate the full potential. A must-read for anyone working in the field.

目次

List of Contributors XVII Foreword XXV Preface XXVII 1 Introduction 1 Damien Faivre 1.1 Iron Oxides: From Nature to Applications 1 1.2 A Very Brief Overview of the Iron Oxides and How They Found Names 3 References 5 Part I Formation, Transformation 7 2 Geological Occurrences and Relevance of Iron Oxides 9 France Lagroix, Subir K. Banerjee, and Mike J. Jackson 2.1 Introduction 9 2.2 Elemental Iron: From the Universe to the Earth 9 2.3 Residency of Elemental Iron on Earth 10 2.4 Mineral Forms of Iron Oxides 11 2.5 Occurrence and Geological Relevance of Iron Oxides 13 2.6 Iron Oxides in Continental Dust Deposits 19 2.7 Concluding Remarks 23 Acknowledgments 23 References 23 3 Reductive Dissolution and Reactivity of Ferric (Hydr)oxides: New Insights and Implications for Environmental Redox Processes 31 Stefan Peiffer and Moli Wan 3.1 Introduction 31 3.2 The Classical Perspective on Reductive Dissolution 32 3.3 Electron Transfer at Ferric (Hydr)oxides Surfaces: The Role of Fe(II) 33 3.4 Energetics at the Ferric (Hydr)oxide Interface 35 3.5 Rate Control: Surface versus Structural Properties 39 3.6 Interaction between Dissolved Sulfide and Ferric Hydroxides 42 3.7 Implications 47 References 48 4 Formation and Transformation of Iron-Bearing Minerals by Iron(II)-Oxidizing and Iron(III)-Reducing Bacteria 53 Jennyfer Miot and Marjorie Etique 4.1 Introduction 53 4.2 Biomineralization of Iron through Microbial Fe(II) Oxidation 54 4.3 Iron(III) Minerals: Electron Acceptors for Iron-Reducing Bacteria 60 4.4 Specific Properties of Iron Biominerals 64 4.5 Microbial Fe Redox Cycling: Past, Present, and Future 72 4.6 Conclusion 77 References 78 5 Controlled Biomineralization of Magnetite in Bacteria 99 Elodie C.T. Descamps, Jean-Baptiste Abbe, David Pignol, and Christopher T. Lefevre 5.1 Introduction 99 5.2 Magnetotactic Bacteria 100 5.3 Organization and Role of Magnetosomes 102 5.4 Biomineralization of Magnetosomes 104 5.5 Mineral Phase of Magnetosomes 108 Acknowledgments 111 References 111 6 Ferritin Iron Mineralization and Storage: From Structure to Function 117 Noam Aronovitz, Michal Neeman, and Raz Zarivach 6.1 Introduction 117 6.2 Basic Structure of Ferritins 118 6.3 Iron Storage and Mineralization 123 6.4 NMR and MRI Studies of the Ferritin Iron Core 126 6.5 Magnetoferritin 127 6.6 Ferritin as a Biotechnological Tool 131 6.7 Protocol Annexes 133 References 137 7 Iron Oxides in the Human Brain 143 Joanna F. Collingwood and Neil D. Telling 7.1 Introduction 143 7.2 Iron Oxides Observed in the Human Brain 146 7.3 Properties of Iron Oxides in the Brain 150 7.4 Stored and Sequestered Iron Oxide in the Human Brain 155 7.5 Methods to Detect Iron Oxides in the Brain 160 7.6 Tools and Treatments: Manipulating Iron Oxides in the Brain 163 7.7 Concluding Remarks 166 Acknowledgments 166 References 166 8 The Chiton Radula: A Model System for Versatile Use of Iron Oxides 177 Derk Joester and Lesley R. Brooker 8.1 Functional Anatomy of the Mollusk Radula 177 8.2 Development of the Radula: Organic Matrix 180 8.3 The Discovery of Biominerals in the Radula 180 8.4 The Microarchitecture of Chiton Radula Teeth 181 8.5 Development of the Chiton Radula: Stages of Biomineralization 183 8.6 Development of the Radula: Biological Control 185 8.7 Role of Acidic Macromolecules in the Insoluble Organic Matrix 186 8.8 Soluble Organic Matrix Composition 186 8.9 Selective Deposition of Ferrihydrite in Stage II 187 8.10 Conversion of Ferrihydrite to Magnetite in Stage III 190 8.11 Phase Transformations in Stage IV 192 8.12 Final Functional Architecture 194 8.13 Concluding Remarks 197 References 198 9 Mineralization of Goethite in Limpet Radular Teeth 207 Tina Ukmar-Godec 9.1 Introduction 207 9.2 Structure, Properties, and Function of the Limpet Radula 207 9.3 Goethite Produced in the Laboratory 210 9.4 Goethite Produced in Limpets 213 9.5 Conclusion 221 References 222 10 Synthetic Formation of Iron Oxides 225 Corinne Chaneac, Anne Duchateau, and Ali Abou-Hassan 10.1 Introduction 225 10.2 Iron Oxide and Oxyhydroxide from Aqueous Ferric Solution 226 10.3 Iron Oxide and Oxyhydroxide from Aqueous Ferrous Solution 231 10.4 Iron Oxide Synthesis Using Microfluidic Process 233 References 240 11 Oriented Attachment and Nonclassical Formation in Iron Oxides 243 Jennifer A. Soltis and R. Lee Penn 11.1 Introduction 243 11.2 OA in Iron Oxides in the Literature 245 11.3 OA and Phase Transformation 249 11.4 Detection and Characterization of Growth by OA 249 11.5 Kinetics of Growth by OA 253 11.6 Thermodynamics 257 11.7 Morphology and Surface Chemistry 258 11.8 Forces Governing Assembly 259 11.9 Future Work 260 References 261 12 Thermodynamics of Iron Oxides and Oxyhydroxides in Different Environments 269 Haibo Guo and Amanda S. Barnard 12.1 Introduction 269 12.2 Magnetic Transformations 270 12.3 Polymorphic Transformations 274 12.4 Summary 288 References 289 Part II Characterization Techniques 293 13 Introduction to Standard Spectroscopic Methods: XRD, IR/Raman, and Moessbauer 295 Fernando Vereda 13.1 Introduction 295 13.2 X-Ray Diffraction (XRD) 297 13.3 Vibrational Spectroscopy 302 13.4 Moessbauer Spectroscopy 311 Acknowledgments 319 References 319 14 TEM and Associated Techniques 325 Tanya Prozorov Common Abbreviations 325 14.1 Introduction 326 14.2 Nanoscale Analysis of Iron Oxides 327 14.3 Electron Holography 331 14.4 The Near In Situ Approach 335 14.5 In Situ Analysis with a Liquid Cell 336 Acknowledgment 338 References 339 15 Magnetic Measurements and Characterization 347 Ann M. Hirt 15.1 Introduction 347 15.2 Summary of Magnetic Properties of Iron Oxides and Iron Hydroxides 348 15.3 Induced Magnetization 349 15.4 Remanent Magnetization 355 15.5 Usage of Magnetic Properties 357 15.6 Summary 366 References 367 16 Total X-Ray Scattering and Small-Angle X-ray Scattering for Determining the Structures, Sizes, Shapes, and Aggregation Extents of Iron (Hydr)oxide Nanoparticles 371 Young-Shin Jun and Byeongdu Lee 16.1 Introduction 371 16.2 Determination of Particle Structures: Total X-Ray Scattering with PDF Analysis 373 16.3 Determination of Particle Sizes, Shapes, and Aggregation Extents: SAXS and GISAXS 378 16.4 Outlook 391 Acknowledgments 392 References 392 17 X-Ray Absorption Fine Structure Spectroscopy in Fe Oxides and Oxyhydroxides 397 M. Luisa Fdez-Gubieda, Ana Garcia-Prieto, Javier Alonso, and Carlo Meneghini 17.1 Brief Introduction to XAFS 398 17.2 XANES spectroscopy 401 17.3 EXAFS Spectroscopy 406 17.4 Conclusion and Perspectives 415 References 416 Part III Applications 423 18 Medical Applications of Iron Oxide Nanoparticles 425 Amanda K. Andriola Silva, Ana Espinosa, Jelena Kolosnjaj-Tabi, Claire Wilhelm, and Florence Gazeau 18.1 Introduction 425 18.2 IONPs for Imaging 426 18.3 Magnetic Drug Targeting 433 18.4 IONPs and Tissue Engineering 442 18.5 Activation of IONPs with Time-Dependent Magnetic Fields 446 18.6 Life Cycle of IONPs 456 18.7 Conclusion 460 References 460 19 Iron Nanoparticles for Water Treatment: Is the Future Free or Fixed? 473 Sarah J. Tesh and Thomas B. Scott 19.1 Introduction 473 19.2 Why Iron? 475 19.3 INPs: A Versatile Material for Water Treatment 477 19.4 Operational Drivers for Water Treatment 483 19.5 Static Nanocomposites 495 19.6 What Is Holding Back Static Nanocomposites? 507 19.7 Conclusion 509 References 510 20 Actuation of Iron Oxide-Based Nanostructures by External Magnetic Fields 523 Peter Vach 20.1 Introduction 523 20.2 Nanomachines 525 20.3 Guided Self-Assembly 530 20.4 Conclusion 536 References 536 21 Iron Oxide-Based Pigments and Their Use in History 545 Marco Nicola, Chiara Mastrippolito, and Admir Masic 21.1 Introduction 545 21.2 Chemical Composition and Properties of Iron Oxide-Based Pigments 545 21.3 Use of Iron Oxide-Based Pigments in History 550 21.4 Case Studies 559 References 563 22 Magnetoreception and Magnetotaxis 567 Mathieu A. Bennet and Stephan H. K. Eder 22.1 Magnetoreception 567 22.2 Magnetotaxis 576 Conclusions 586 References 586 Index 591

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詳細情報

• NII書誌ID(NCID): BB21807468
• ISBN:
  • 9783527338825
• 出版国コード: gw
• タイトル言語コード: eng
• 本文言語コード: eng
• 出版地: Weinheim
• ページ数/冊数: xxviii, 598 p.
• 大きさ: 25 cm
• 分類:
  • DC23 : 546.6212
• 件名:
  • LCSH : Iron oxides
  • LCSH : Iron oxides -- Industrial applications