Reagents for organocatalysis

著者

• Rovis, Tomislav

書誌事項

Reagents for organocatalysis

edited by Tomislav Rovis

（Handbook of reagents for organic synthesis）

Wiley, 2016

• : cloth

注記

Includes indexes

内容説明・目次

内容説明

Spurred by the desire to make chemistry a sustainable and "greener" technology, the field of organocatalysis has grown to become one of the most important areas in synthetic organic chemistry. Organic catalysts can often replace potentially toxic metal catalysts and allow reactions to proceed under mild reaction conditions, thereby saving energy costs and rendering chemical processes inherently safer. More importantly perhaps, organocatalysis offers a complementary reactivity in many instances leading to increased versatility. This Handbook describes 126 key reagents for organocatalytic reactions and will be especially useful for professionals in the area of sustainable chemistry, medicinal research, as well as synthetic organic chemists working in academia and the pharmaceutical industry. All the information compiled in this volume is also available in electronic format on Wiley Online Library. The 126 reagents represented here are but a small fraction of the ca. 5,000 reagents available in the electronic Encyclopedia of Reagents for Organic Synthesis (e-EROS). e-EROS offers various search interfaces to locate reagents of interest, including chemical structure, substructure and reactions search modes. e-EROS is updated regularly with new and updated entries.

目次

• Preface xi Introduction xiii Catalyst Finder xv Recent Review Articles and Monographs xix Short Note on InChIs and InChIKeys xxi 4-Acetamido-2,2,6,6-tetramethyl-1-piperidinyloxyl 1 4-Acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium Tetrafluoroborate 2 2[1]-Amino-[1,1[1]-binaphthalen]-2-ol 13 (9R)-9-Amino-9-deoxyquinidine 16 9(S)-Amino-9-deoxyquinine 24 (1R,2S)-1-Amino-2,3-dihydro-1H-inden-2-ol 35 (2S,4S)-2-(Anilinomethyl)-1-ethyl-4-hydroxypyrrolidine 50 (S)-2-(Anilinomethyl)pyrrolidine 51 9-Azabicyclo[3.3.1]nonane-N-oxyl 59 Benzoyl trimethylsilane 61 Benzyl 1,3-Butadiene-1-carbamate 66 3-Benzyl-5-(2-hydroxyethyl)-4-methyl-1,3-thiazolium Chloride 69 (S)-5-Benzyl-2-mesityl-6,6-dimethyl-6,8-dihydro-5H-[1,2,4]triazolo[3,4-C][1,4]-oxazin-2-ium Tetrafluoroborate 72 3-Benzyl-4-methyl-1,3-thiazolium Chloride 75 cis-4-Benzyloxy- , -bis-(3,5-dimethylphenyl)-L-prolinol (2S,4R)- 76 N-Benzylquininium Chloride 78 3-Benzylthiazolium Bromide 85 Benzyltriethylammonium Chloride 86 Bicyclo[2.2.1]heptan-2-one,7,7- Dimethyl-1-(1S,3S,4R)-2-thiabicyclo-[2.2.1]hept-3-yl-, (1S,4R) 88 [1,1[1]-Binaphthalene]-2,2[1]-diol, 3,3[1]-Bis[3,5-bis(trifluoromethyl)phenyl]-, (1R)- 95 N,N[1]-(1S)-[1,1[1]-Binaphthalene]-2,2[1]-diy lbis-(2S,2[1]S)-pyrrolidine-2-carboxamide 98 (R)-1,1[1]-Bi-2,2[1]-naphthol 101 1,1[1]-Binaphthyl-2,2[1]-disulfonic Acid 124 1,1[1]-Binaphthyl-2,2[1]-diyl Hydrogen Phosphate 129 N,N[1]-Bis[3,5-bis(trifluoromethyl)-phenyl]thiourea 133 1-[3,5-Bis(tert-butyl)phenyl]octahydro-3,6,6-trimethylcyclopenta[b]phosphole 137 1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene 139 1,3-Bis(2,6-diisopropylphenyl)imidazolidinium Chloride 146 1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene 149 (-)-(4R,5R)-4,5-Bis[hydroxy(diphenyl)-methyl]-2, 2-dimethyl-1,3-dioxolane(TADDOL) 152 (2S,5S)-2-(Bis(4-methoxyphenyl)((trimethylsilyl)oxy) methyl)-5-(4-methoxy-3,5-dimethylphenyl)pyrrolidine 161 (3R,5R,8R)- 3,8-Bis(1-methylethyl)-2,2,7,7-tetrakis(4-methylphenyl)-1,4,6,9-tetraaza-5 5-phosphaspiro[4,4] non-5-ene, Hydrochloride salt (1:1) 162 1,2-Bis(phenylsulfonyl)ethylene 163 3,3[1]-Bis(trifluoromethanesulfonyl)-2,2[1]-dihydroxy-1,1[1]-binaphthalene 172 1-[Bis(trifluoromethanesulfonyl)methyl]-2,3,4,5,6-pentafluorobenzene 174 3-[[3,5-Bis(trifluoromethyl)phenyl]-amino]-4-[[(1R,2R)-2-(dimethylamino)-cyclohexyl]amino]-3-cyclobutene-1,2-dione 180 N-[3,5-Bis(trifluoromethyl)phenyl]-N[1]-(9R)-cinchonan-9-yl-thiourea 183 N-[3,5-Bis(trifluoromethyl)phenyl]-N[1]-[(1R,2R)-2-(dimethylamino)cyclohexyl]-thiourea 186 1-[3,5-Bis(trifluoromethyl)phenyl]-3-{(2S)-3,3-dimethyl-1-[(triphenylphosphoranylidene)amino] butan-2-yl}thiourea 189 2-[Bis[3,5-bis(trifluoromethyl)phenyl][(trimethylsilyl) oxy]methyl]pyrrolidine 192 (1R)-3,3[1]-Bis(2,4,6-trimethylphenyl)-[1,1[1]-binaphthalene]-2,2[1]-dicarboxylic acid 199 Bromamine-T 202 Bromonitromethane 205 tert-Butyl 2-(tert-butyldimethylsilyl)-2-oxoacetate 210 (S)-5-((tert-Butyldimethylsilyloxy)-diphenylmethyl)-2-phenyl-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-2-ium Tetrafluoroborate 1a (and Related Reagents) 214 Chloramine-T 219 Cinchonanium, 1-(9-Anthracenylmethyl)-9-(propen-1-yloxy)-, Bromide(1:1), (8 ,9R) 227 1,2-Cyclohexanediamine, N1,N2-Bis[4-(1-pyrrolidinyl)-2-quinolinyl]-, (1R,2R)- 235 1,4-Diazabicyclo[2.2.2]octane 241 1,3-Di-tert-butylimidazol-2-ylidene 247 Diethyl 1,4-Dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate 254 Diethyl Oxomalonate 261 1,3-Dihydro-1,3-bis(tricyclo[3.3.1.13,7]dec-1-yl)-2H-imidazol-2-ylidene 270 1,3-Dihydro-4,5-dimethyl-1,3-bis(1-methylethyl)-2H-imidazol-2-ylidene 273 4,5-Dihydro-4-phenyl-3H-dinaphtho[2,1-c:1[1],2[1]-e]phosphepin 277 2,3-Dihydro-2-phenylimidazo[2,1-b]benzothiazole 280 6,7-Dihydro-2-phenyl-5-(phenylmethyl)-5Hpyrrolo[2,1-c]-1,2,4-triazolium Chloride 286 (R)-2,2[1]-Dihydroxy-3,3[1]diphenyl-1,1[1]-binaphthyl 301 1,3-Dimesityl-4,5-dihydroimidazol-2-ylidene 304 1,3-Dimesityl-1H-imidazolium Salts and 1,3-Dimesitylimidazolylidene 306 4-Dimethylaminopyridine 309 2,2-Dimethyl-1,3-dioxan-5-one 315 Dimethyldioxirane 320 (11bR)-4-(1,1-Dimethylethyl)-4,5-dihydro-3Hdinaphtho[2,1-c:1[1],2[1]- e]phosphepin 327 [4S-(4 ,5 )]-1-(1,3-Dimethyl-2-oxido-4,5-diphenyl-1,3,2-diazaphospholidine-2-yl)piperidine 330 (1R,2S,4R,5S)-2,5-Dimethyl-7-phenyl-7-phosphabicyclo[2.2.1]heptane 334 1,4-Dimethyl-1H-1,2,4-triazol-4-ium Iodide 335 (11bR)-Dinaphtho[2,1-d:1[1],2[1]-f][1,3,2]dioxaphosphepin,2,6-Bis[3,5-bis (trifluoromethyl)phenyl]-4-hydroxy-, 4-Oxide 339 (11bR)-Dinaphtho[2,1-d:1[1],2[1]-f][1,3,2]dioxaphosphepin,4-Hydroxy-2,6-di-2-naphthalenyl-, 4-Oxide 343 Dinaphtho[2,1-d:1[1],2[1]-f][1,3,2]dioxaphosphepin,4-Hydroxy-2,6-diphenyl-,4-Oxide, (11bR)-(Family of Reagents) 345 5,6-Dioxaspiro[2.4]heptane-4,7-dione 351 2,2[1]-Diphenyl-[3,3[1]-biphenanthrene]-4,4[1]- diol (VAPOL) and 3,3[1]-Diphenyl-[2,2[1]- binaphthrene]-1,1[1]-diol(VANOL) 353 , -Diphenyl-2-pyrrolidinemethanol 365 Dispiro[2H-pyran-2,4[1]-[4H-5,6,8b]-triazaacenaphthylene-7[1](5[1]H),2[1][1]-[2H]- pyran], 1[1],2[1],2[1]a,3,3[1],3[1][1], 4,4[1][1],5,5[1][1],6,6[1][1],8[1],8[1]a-tetradecahydro-1[1],2[1]-dimethoxy-6, 6[1][1]-dimethyl-, monohydrochloride,(1[1]S,2R,2[1]S,2[1][1]R,2[1]aS,6S,6[1][1]S,8[1]aS)- 372 N-[(4-Dodecylphenyl)sulfonyl]-2-pyrrolidinecarboxamide(Hua Cat) 373 Dodecyl 4-[[[(2S)-2-pyrrolidinylcarbonyl]-amino]sulfonyl]benzoate(Hua Cat II) 376 (11bR)-4-Hydroxy-2,6-bis[2,4,6-tris-(1-methylethyl)phenyl]-dinaphtho[2,1-d:1[1],2[1]-F][1,3,2]dioxaphosphepin-4-oxide,[(R)-TRIP] & (11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]- dinaphtho[2,1-d: 1[1],2[1]-f][1,3,2]dioxaphosphepin-4-oxide, [(S)-TRIP] 379 N-[(1S)-1-(Hydroxydiphenylmethyl)-3-methylbutyl]-2-pyrrolidinecarboxamide 393 trans-4-Hydroxy-l-proline 395 (4aR,9aS)-4-Hydroxy-4,4a,9,9a-tetrahydroindeno[2,1-b][1,4]oxazin-3(2H)-one 399 1H-Imidazolium, 1,3-Bis[2,6-bis-(1-methylethyl)phenyl],tetrafluoroborate(1-) 400 Iron(2+), tris(2,2[1]-bipyridine-N,N[1])-,Dibromide,(OC-6-11) 403 -Isocupreidine ( -ICD) 406 1-Mesityl-3,4-dimethyl-4H-1,2,4-triazol-1-ium Tetrafluoroborate 411 9-Mesityl-10-methylacridinium Perchlorate 413 6[1]-Methoxy-(8S,9R)-cinchonan-9-yl N-tertbutoxycarbonyl-2-pyrrolidinecarboxylate 417 1-Methyl-2-azaadamantane N-Oxyl 420 (S)-1-Methyl-2-[(dihydroisoindol-2-yl)methyl]pyrrolidine 421 2-Methyltetrahydrofuran 422 Methyl(trifluoromethyl)dioxirane 428 Methyl Vinyl Ketone 438 d-2-Naphthylalanine, N,N[1]- [[(2S, 5S)-1-(4-pyridinyl)-2,5-pyrrolidinediyl]dicarbonyl]bis-, 3,3[1] - Dioctyl Ester1 and l-2-Naphthylalanine, N,N[1]-[[(2S,5S)-1-(4-pyridinyl)-2,5-pyrrolidinediyl]dicarbonyl]bis-, 3,3[1]-Dioctyl Ester 449 Nitroethane 451 4-Nitropyridine N-oxide 460 (2S)-N-(2,3,4,5,6-Pentafluorophenyl)-2-pyrrolidinecarboxamide 465 1,5-Pentanediamine, N,N[1]-Bis[(11bR)-3,5-dihydro-3,5-dimethyl-4-oxido-4H-dinaphtho[2,1-d:1[1],2[1]-f ]-[1,3,2]diazaphosphepin-4-yl]-N,N[1]-dimethyl 466 2-Phenyl-6,10b-dihydro-4H,5aH-5-oxa-3,10c-diaza-2-azonia-cyclopenta[c] fluorene tetrafluoroborate
• 2-Pentafluorophenyl-6,10b-dihydro-4H, 5aH-5-oxa-3,10c-diaza-2-azoniacyclopenta[c]fluorine tetrafluoroborate
• 6,7-Dihydro-2-phenyl-5-(phenylmethyl)-5H-pyrrolo[2,1-c]-1,2,4-triazolium chloride 474 (8 ,9R)-(8[1][1] ,9[1][1]R)-1,1[1][1]-[1,3-Phenylenebis(methylene)]bis[9-hydroxy-cinchonanium]Dibromide and (9S)-(9[1][1]S)-1,1[1][1]-[1,3-Phenylenebis(methylene)]bis[9-hydroxy-cinchonanium]Dibromide 486 2-(Phenylmethoxy)acetaldehyde 489 (S)-Proline 494 (2S)-2-Pyrrolidinemethanol- , -bis(3,5-dimethylphenyl)and (2R)-2-Pyrrolidinemethanol- , -bis(3,5-dimethylphenyl) 517 1-(2-Pyrrolidinylmethyl)pyrrolidine 520 4-(1-Pyrrolidinyl)pyridine 525 5H-Pyrrolo[2,1-c]-1,2,4-triazolium, 7-Fluoro-6,7-dihydro-5-(1-methylethyl)-2-(2,3,4,5,6-pentafluorophenyl)-, (5R,7R)-, Tetrafluoroborate(1-) 528 Quinine 531 3-Quinuclidinol 547 Ruthenium (II), Tris(2,2[1]-bipyrazine- N1, N1[1]),1(OC-6-11)- 551 Ruthenium(II), Tris(2,2[1]-bipyridine- N1, N1[1])-,(OC-6-11)- 554 Ruthenium(II), Tris(1,10-phenanthroline- N1, N10)-,(OC-6-11)- 559 4,4[1]-Spirobi[4H-dinaphth[2,1-c:1[1],2[1]-e]-azepinium],3,3[1],5,5[1]-tetrahydro- 2,6-bis(3,4,5-trifluorophenyl), bromide 561 Spiro[6H-1,3-dioxolo[4,5-c]pyran-6,5[1]-oxazolidine]-3[1]-carboxylic acid, tetrahydro-2,2-dimethyl-2[1],7-dioxo-, 2-methyl-2-propyl ester, (3aR, 5[1]S, 7aR)- 567 Squaramide 571 Tetrachlorosilane 575 2,3,5,6-Tetrahydro-2,6-bis(phenylmethyl)-1H-imidazo[1,2-a] imidazole 582 2,2,6,6-Tetramethylpiperidin-1-oxyl 583 (S)-2-(5-1H-Tetrazolyl)pyrrolidine and (R)-2-(5-1H-Tetrazolyl)pyrrolidine 595 1,2,4-Triazolo[4,3- ]pyridinium, 5,6,7,8-tetrahydro-2-(2,3,4,5,6-pentafluorophenyl)-, Tetrafluoroborate 603 Triflimide 604 N-[4-(Trifluoromethyl)benzyl]-cinchoninium Bromide 612 3-(2,4,6-Trimethylphenyl)-1-methyl-1Hbenzo[d]imidazol-3-ium Iodide 614 (5S)-2,2,3-Trimethyl-5-(phenylmethyl)-4-imidazolidinone 616 1,5,7-Trimethyl-7-(5,6,7,8-tetrahydronaphth[2,3-d ]oxazol-2-yl)-3-azabicyclo-[3.3.1]nonan-2-one 621 2-Triphenylmethylpyrrolidine 624 Tris[(trifluoromethyl)sulfonyl]methane and Related Salts 625 l-Tryptophan, N,N[1]-[[(2S,5S)-1-(4-pyridinyl)-2,5-pyrrolidinediyl]-dicarbonyl]bis-, 3,3[1]-dioctyl Ester 628 Urea, N-[3,5-Bis(trifluoromethyl)phenyl]-N[1]-[(8a,9S)-6[1]-methoxycinchonan-9-yl]-
• Urea, N-[3,5-Bis(trifluoromethyl)phenyl]-N[1]-(9R)-cinchonan-9-yl- 633 List of Contributors 639 Reagent Formula Index 655

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詳細情報

• NII書誌ID(NCID): BB22653155
• ISBN:
  • 9781119061007
• LCCN: 2016023290
• 出版国コード: uk
• タイトル言語コード: eng
• 本文言語コード: eng
• 出版地: Chichester
• ページ数/冊数: xx, 699 p.
• 大きさ: 29 cm
• 分類:
  • LCC : QD262
  • DC23 : 547/.215
• 件名:
  • LCSH : Organic compounds -- Synthesis -- Handbooks, manuals, etc
  • LCSH : Catalysis
  • LCSH : Chemical tests and reagents
• 親書誌ID:
  • BA4223360X