Copper-catalyzed electrophilic amination of sp[2] and sp[3] C-H bonds
著者
書誌事項
Copper-catalyzed electrophilic amination of sp[2] and sp[3] C-H bonds
（Springer theses : recognizing outstanding Ph. D. research）
Springer, c2016
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注記
"Doctoral thesis accepted by Duke University, Durham, NC, USA"
On t.p. "[2]", "[3]" are superscripts
Includes bibliographical references
内容説明・目次
内容説明
This thesis reports the latest developments in the direct amination of various C H bonds using an H Zn exchange/electrophilic amination strategy. McDonald and co-workers reveal this approach to be a rapid and powerful method for accessing a variety of functionalized amines.
The material outlined in this book shows how McDonald achieved C H zincation using strong, non-nucleophilic zinc bases and subsequent electrophilic amination of the corresponding zinc carbanions with copper as a catalyst and O-benzoylhydroxylamines as the electrophilic nitrogen source.
McDonald's findings are of relevance to medicinal chemistry, drug discovery and materials science. Her thesis is a source of inspiration for scientists entering the field and students beginning their PhD in a related area.
目次
Electrophilic amination for the synthesis of alkyl and aryl amines.- Selective -amination and -acylation of esters and amides via dual reactivity of O-acylhydroxylamines toward zinc enolates.- Copper-catalyzed -amination of phosphonates and phosphine oxides: a direct approach to -amino phosphonic acids and derivatives.- Copper-Catalyzed Electrophilic Amination of Heteroarenes and Arenes by C H Zincation.
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