Quinoxalines : synthesis, reactions, mechanisms and structure

Author(s)

    • Mamedov, Vakid A.

Bibliographic Information

Quinoxalines : synthesis, reactions, mechanisms and structure

Vakid A. Mamedov

Springer, 2016

  • : hbk

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Note

Includes bibliographical references and index

Description and Table of Contents

Description

This book reviews the fundamental aspects of quinoxaline chemistry: synthesis, reactions, mechanisms, structure, properties, and uses. The first four chapters present a survey of the developments in quinoxaline chemistry since the publication of the monograph on "Condensed Pyrazines" by Cheeseman and Cookson in 1979. These chapters give comprehensive coverage of all the methods of the synthesis of quinoxalines and the important quinoxaline-containing ring systems such as thiazolo[3,4-a]-, pyrrolo[1,2-a]-, and imidazo[1,5-a]quinoxalines. Chapter five describes many new methods for the construction of quinoxaline macrocycles, which are important in applications such as optical devices and materials. The final chapter reviews all previously known rearrangements of heterocyclic systems that lead to benzimidazole derivatives. Mamedov critically analyses these transformations to reveal a novel acid-catalyzed rearrangement of quinoxalinones giving 2-heteroarylbenzimidazoles and 1-heteroarylbenzimidazolones in the presence of nucleophilic reactants (MAMEDOV Heterocycle Rearrangement). This book is of interest to researchers in the fields of heterocyclic and synthetic organic chemistry.

Table of Contents

Introduction: Quinoxaline as a Parent Heterocycle.- Synthesis of Quinoxalines.- Synthesis of Pyrrolo[l,2-a]quinoxalines.- Synthesis of Imidazo[1,5-a]- and Imidazo[1,2-a]quinoxalines.- Synthesis of Quinoxaline Macrocycles.- Rearrangements of Quinoxalin(on)es in the Synthesis of Benzimidazol(on)es.- Appendix.

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Details

  • NCID
    BB25665128
  • ISBN
    • 9783319297712
  • LCCN
    2016931837
  • Country Code
    sz
  • Title Language Code
    eng
  • Text Language Code
    eng
  • Place of Publication
    Cham
  • Pages/Volumes
    xv, 437 p.
  • Size
    25 cm
  • Classification
  • Subject Headings
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