Organic synthesis in water
著者
書誌事項
Organic synthesis in water
Springer science+business media, c1998
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注記
Includes index
Originally published by Blackie Academic & Professional in 1998 <BA34070554>
内容説明・目次
内容説明
The use of water as a medium for promoting organic reactions has, for the most part, been non-existent, despite the fact that water has served, and continues to serve, as the solvent in which the vast majority of biochemical processes take place. Chemists have only recently come to appreciate the enormous potential that water holds for those engaged in synthetic organic and organometallic chemistry, in part because of water's unique enthalpic and entropic properties. In this volume, an international team of authors, each taking advantage of the unique properties of water for carrying out organic transformations, is brought together in order to provide a timely and concise overview of current research. The chapters focus on the practical use of water in synthetic organic chemistry, with special emphasis on Diels-Alder reactions, Claisen rearrangements, organometallic chemistry, transition-metal catalysis, oxida- tions and reductions. I am grateful to my colleagues, J. Auge, I. Beletskaya, A. Cheprakov, F. Fringuelli, J. Gajewski, P. Gamer, S. Kobayashi, A. Lubineau, D. Parker, O. Piermatti, F. Pizzo and Y. Queneau, for participating in this venture.
Their knowledge and experience have been invaluable in putting this volume together.
目次
1. Diels-Alder reactions in aqueous media. 2. Hetero Diels-Alder reactions. 3. Claisen rearrangements in aqueous solution. 4. Carbonyl additions and organometallic chemistry in water. 5. Aqueous transition-metal catalysis. 6. Oxidations and reductions in water. 7. Base-catalyzed Aldol- and Michael-type condensations in aqueous media. 8. Water-stable rare-earth Lewis-acid catalysis in aqueous and organic solvents. 9. Organometallic chemistry in water. 10. Transition metal catalyzed carbon-carbon bond pairing reactions in water. Index.
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