The chemistry of nitrogen-rich functional groups

著者

    • Liebman, Joel F.
    • Greer, Alexander

書誌事項

The chemistry of nitrogen-rich functional groups

edited by Joel F. Liebman, Alexander Greer

(The Chemistry of functional groups)

Wiley, [2020]

大学図書館所蔵 件 / 5

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注記

Includes bibliographical references and index

内容説明・目次

内容説明

Nitrogen is unique among the non-carbon atoms in its ability to form single, double, and triple bonds with itself, giving rise to a wide range of organic-chemical groups containing several nitrogen atoms in different states and geometries. The present volume surveys the properties and chemical behaviour of all important nitrogen-rich organic-chemical groups, including azides, azimines, aziridines, diazo compounds, nitramines, nitrenes, nitrosamines, polyazine N-oxides, tetrazoles, triazanes, triazenes, and triazoles. A special focus lies on commercially important species which are used, e. g., as powerful explosives. PATAI's Chemistry of Functional Groups publishes comprehensive reviews on all aspects of specific functional groups. Each volume contains outstanding surveys on theoretical and computational aspects, NMR, MS, other spectroscopic methods and analytical chemistry, structural aspects, thermochemistry, photochemistry, synthetic approaches and strategies, synthetic uses and applications in chemical and pharmaceutical industries, biological, biochemical and environmental aspects. To date, almost 150 volumes have been published in the series.

目次

1. Introduction to the energetics and thermochemical aspects of polynitrogen species 1 Suzanne W. Slayden, Alexander Greer, and Joel F. Liebman 2. Stable hydrazyls and push-pull (capto-dative) aminyl free radicals 17 Alexandru T. Balaban 3. New combinations of organic azides and adjacent functional groups 27 Klaus Banert 4. Bridged azobenzenes and their chemical applications 65 David J. Warner, Katie S. Keane, and Silas C. Blackstock 5. Click chemistry and nitrogen-containing heterocycles formed in surface functionalization reactions 115 Yuan Chen, Hao Fan, and Elena Galoppini 6. Triplet vinylnitrenes 161 Upasana Banerjee, Kosala Thenna-Hewa, and Anna D. Gudmundsdottir 7. Nitrogen catenation: polyazoles and polyazines 199 Peter Politzer and Jane S. Murray 8. N-Oxides of polyazoles and polyazines 231 Peter Politzer and Jane S. Murray 9. Bridged azobenzenes and their biological applications 251 David J. Warner, Katie S. Keane, Carl Jacky Saint-Louis, and Silas C. Blackstock 10. Thermochemical insights on small nitrogen heterocyclic compounds 287 Vera L. S. Freitas and Maria D. M. C. Ribeiro da Silva 11. Some thermochemical aspects of acyclic polynitrogen species 329 Suzanne W. Slayden, Alexander Greer, and Joel F. Liebman 12. The Bronsted acid/base character of the N N and N=N bonds 357 John E. Bartmess Subject index 385

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