Surface science of intercalation materials and solid electrolytes : a view on electron and ion transfer at Li-ion electrodes based on energy level concepts

著者

    • Hausbrand, René

書誌事項

Surface science of intercalation materials and solid electrolytes : a view on electron and ion transfer at Li-ion electrodes based on energy level concepts

René Hausbrand

(SpringerBriefs in Physics)

Springer, 2020

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収録内容

  • Intro
  • Preface
  • Acknowledgements
  • Contents
  • 1 Introduction
  • References
  • 2 Fundamental Aspects of Interface Formation and Charge Transfer
  • 2.1 Electronic Properties and Interface Formation
  • 2.1.1 Electronic Structure of Solids
  • 2.1.2 Solid-Solid Contacts
  • 2.1.3 Solid-Liquid Interfaces
  • 2.2 Ionic Structure and Ion Transfer
  • 2.2.1 Ionic Structure
  • 2.2.2 Ion Transfer
  • 2.3 Coupling of Electronic and Ionic Structure
  • 2.4 Interface and Interlayer Formation
  • References
  • 3 Experimental Techniques
  • 3.1 Photoelectron Spectroscopy
  • 3.2 Spectroscopy of Ionic Surfaces and Interfaces
  • 3.3 Integration of Surfaces Analysis and Thin Film Preparation
  • References
  • 4 Electronic Structure and Structure of LiCoO2 Surfaces
  • References
  • 5 Electronic Structure and Reactivity of Cathode-Liquid Electrolyte Interfaces
  • 5.1 Adsorption of Molecules on Electrode Surfaces
  • 5.2 Layer Formation at Solvent-Covered LiCoO2 Surfaces
  • 5.3 Electronic Structure and Surface Chemistry
  • 5.4 Double Layer Formation
  • 5.5 Band Diagrams and Charge Transfer
  • 5.6 Energy Levels in the Electrolyte
  • 5.7 Summary and Conclusion
  • References
  • 7.1 Structure and Formation of the CEI Layer
  • 7.2 Properties of LiCoO2-CEI Compound Interfaces
  • 7.3 Summary and Conclusion
  • References
  • 8 Li-Ion Energy Levels, Li-Ion Transfer and Electrode Potential
  • 8.1 Evaluation of Li-Ion Energy Levels
  • 8.1.1 Li1s Binding Energy Differences
  • 8.1.2 Defect Formation Energies
  • 8.2 Reference to the Vacuum Level and Combined Diagram
  • 8.3 Role of Energy Level Offsets for Ion Transfer
  • 8.4 Electronic Levels and Electrode Potential
  • 8.5 Summary and Conclusion
  • References
  • 9 Conclusion and Outlook

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