The chemistry of organoboron compounds

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The chemistry of organoboron compounds

edited by Mark Gandelman and Ilan Marek

(The Chemistry of functional groups)

J. Wiley, 2021

  • pt. 1

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R-B

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Includes bibliographical references

Description and Table of Contents

Description

The ultimate resource in organoboron chemistry Professor Mark Gandelman and his colleagues delve deeply into the theory, structure, analysis, synthesis, and reactions of organoboron chemistry in The Chemistry of Organoboron Compounds. Organoborons are used heavily as highly efficient reagents in many reactions, including cross-coupling and radical reactions. The highly regarded authors have tied together organic-chemical and physico-chemical knowledge usually unavailable from a single source. The book focuses on the use of completely biodegradable "green" reagents, as opposed to environmentally hazardous heavy metal catalysts. The Chemistry of Organoboron Compounds delivers comprehensive and complete information on: The behavior of organoboron compounds The use of organoboron compounds in organic synthesis The commercial applications of organoboron compounds As a volume in the celebrated Patai book series, The Chemistry of Organoboron Compounds includes all the features that readers of that series are used to enjoying, including a comprehensive index at the back of the book.

Table of Contents

1. Catalytic asymmetric Swuzuki-Miyaura couplings 1 F. Wieland Goetzke, Lucy van Dijk, and Stephen P. Fletcher 2. Metal-catalyzed hydroboration reactions of alkyne and subsequent asymmetric transformation 55 Jun Guo and Zhan Lu 3. Aspects of the chemical energetics of species with carbon-boron bonds and related compounds 91 Suzanne W. Slayden and Joel F. Liebman 4. Electrochemistry of organoboron compounds 115 Toshio Fuchigami and Shinsuke Inagi 5. The chemistry of organotrifluoroborates 141 Livia N. Cavalcanti, Julia C. C. V. Bento, and Gary A. Molander 6. The chemistry of organoboron species: classification and basic properties 221 Cory Williams, Mario Luis, Ivan Lopez, and Adiel Coca 7. Recent advances in the stereoselective additions of allylic boronates to carbonyl compounds 243 Helen A. Clement and Dennis G. Hall 8. Synthesis and reactivity of bora- and borata-benzenes 329 Ivo Krummenacher, Julia K. Schuster, and Holger Braunschweig 9. Boron-doped polycyclic aromatic hydrocarbons (B-PAHs): synthesis, properties, and applications 367 Maria M. Lorenzo-Garcia, Francesco Fasano, and Davide Bonifazi 10. The chemistry of multibonded organoboron compounds 461 Marc Devillard and Gilles Alcaraz 11. 1,2-Metallate rearrangement of boron derivatives 561 Joseph M. Bateman and Varinder K. Aggarwal 12. Photochemical transformations involving organoboron 657 Soren K. Mellerup and SuningWang 13. Synthesis and reactivity of 1,1- and 1,2-bisboronate species 701 Rajender Nallagonda, Nivesh Kumar, Rajasekhar Reddy Reddy, Israa Shioukhi, Hila Sagi, and Ahmad Masarwa 14. Copper-catalyzed addition of diboron species 773 Alejandro Parra, Laura Trulli, and Mariola Tortosa 15. The chemistry of boron enolate: synthesis and reactivity 855 Atsushi Abiko 16. Boron-mediated radical reactions 931 Emy Andre-Joyaux, Lars Gnagi, Manuel Gnagi-Lux, Camilo Andres Melendez Becerra, Valentin Soulard, Nicholas D. C. Tappin, and Philippe Renaud 17. Boron-based frustrated Lewis pairs in hydrogenation catalysis 1033 Douglas W. Stephan 18. Boron-based frustrated Lewis pairs in organic transformations 1061 Roman Dobrovetsky Subject index 1109

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