Synthesis of optically active oxymethylenehelicene oligomers and self-assembly phenomena at a liquid-solid interface
著者
書誌事項
Synthesis of optically active oxymethylenehelicene oligomers and self-assembly phenomena at a liquid-solid interface
（Springer theses : recognizing outstanding Ph. D. research）
Springer, c2020
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注記
"Doctoral thesis accepted by Tohoku University, Sendai, Japan"
Includes bibliographical references
内容説明・目次
内容説明
In this book, the author demonstrates that double-helix formation and fibril film formation occur on solid surfaces as a result of the catalytic effect of the liquid-solid interface of the newly synthesized helicene oligomer. In addition, he shows that the double helix produced at the liquid-solid interface can be diffused into a solution to form a self-assembling material by means of mechanical stirring. Both types of formation are new chemical phenomena unique to liquid-solid interfaces not found in solutions.
Detailed results are provided for new chemical reactions at liquid-solid interfaces, and gleaned from experiments performed using synthetic organic molecules. The book offers a useful reference guide to elucidating reaction mechanisms for researchers whose work involves chemical phenomena at a liquid-solid interface.
目次
1. Introduction.- 2. Fibril Film Formation of Pseudoenantiomeric Oxymethylenehelicene Oligomers at the Liquid-Solid Interface.- 3. Mechanical Stirring Induces Heteroaggregate Formation and Self-assembly of Pseudoenantiomeric Oxymethylenehelicene Oligomers in Solution.- 4. Proximate Stochastic Chiral Symmetry Breaking by Racemic Oxymethylenehelicene Oligomers.- 5. Conclusions.- 6. Experimental Section.
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