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松永浩文 MATSUNAGA Hirofumi

ID:9000254706172

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Versatile routes to chiral 4-substituted 2-oxazolidinones and .ALPHA.-amino acids. Use of chiron, (4+2) cycloadducts of dialkyl azodicarboxylates and 2-oxazolones.

MATSUNAGA Hirofumi , ISHIZUKA Tadao , MARUBAYASHI Nobuhiro , KUNIEDA Takehisa

The thermal reaction of 3-[(1S)-2-alkoxyl-1-apocamphanecarbonyl]-2-oxazolones with dialkyl azodicarboxylates results in exclusive formation of [4+2] type cycloadducts with moderate levels of diastereo …

Chemical and Pharmaceutical Bulletin 40(4), 1077-1079, 1992

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