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Zhang Zihan, Meyer Karsten Bulletin of Japan Society of Coordination Chemistry 82 (0), 2-12, 2023-11-30

<p> The use of tripodal N-Heterocyclic Carbene (NHC) ligands has enabled the synthesis of novel monomeric transition metal complexes with distinctive bonding motifs. Researchers have successfully …

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大久保 將史 Bulletin of Japan Society of Coordination Chemistry 82 (0), 29-41, 2023-11-30

<p>A net-zero society needs integration of a large amount of renewable energy to a power grid while ensuring the quality of electricity. As the intermittent power from the renewables should be …

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Fukuzumi Shunichi, Min Lee Yong, Nam Wonwoo Bulletin of Japan Society of Coordination Chemistry 82 (0), 13-28, 2023-11-30

<p>Metal-oxygen/water complexes such as metal-oxo, metal-hydroxo, metal-aqua, metal-peroxo, metal-hydroperoxo and metal-superoxo complexes play pivotal roles as reactive intermediates in various …

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堂免 一成 Bulletin of Japan Society of Coordination Chemistry 81 (0), 66-73, 2023-05-31

<p>In recent years, hydrogen energy has attracted increasing attention in relation to climate change and energy issues. However, the hydrogen used must be produced without carbon dioxide emissions. …

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堀毛 悟史 Bulletin of Japan Society of Coordination Chemistry 81 (0), 74-84, 2023-05-31

<p>The chemistry of coordination polymers and metal-organic frameworks, MOFs, has dominantly progressed with the development of crystallography. The study of "disordered systems" such as liquid and …

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伊東 忍 Bulletin of Japan Society of Coordination Chemistry 81 (0), 3-19, 2023-05-31

<p>Oxidation reactions utilizing reactive species generated on metal ions are important processes in biological reactions and various catalytic reactions. A typical example is dioxygen …

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谷藤 一樹 Bulletin of Japan Society of Coordination Chemistry 81 (0), 58-65, 2023-05-31

<p>Transition metal-sulfur clusters are ubiquitous as enzymatic cofactors and play critical roles in various molecular transformations. Their synthetic counterparts have been studied with a …

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Shang-Da Jiang, Ye-Xin Wang, Zheng Liu, hen Zhou, Song Gao Bulletin of Japan Society of Coordination Chemistry 81 (0), 39-49, 2023-05-31

<p>In the development of quantum information technology, a major challenge is to find suitable materials to process the information with quantum coherence while integrating interactions that enable …

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大谷 亮 Bulletin of Japan Society of Coordination Chemistry 81 (0), 50-57, 2023-05-31

<p>We have investigated cyanide-based metal complexes, which were synthesized by combining [M(CN)₄]^2- (M = Pt, Pd, Ni) or [MN(CN)₄]^2- (M = Mn, Re) with …

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A. Fischer Roland Bulletin of Japan Society of Coordination Chemistry 81 (0), 20-38, 2023-05-31

<p>Intermetallics (M¹/M²) of abundant metals of very different properties can substitute rare and precious metals for industrial catalysis. A challenge in this context is the …

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寺西 利治 Bulletin of Japan Society of Coordination Chemistry 80 (0), 14-27, 2022-12-25

<p>Elaborate chemical synthesis methods allow the production of various types of inorganic nanocrystals (NCs) with uniform shape and size distributions. The transformation of already-synthesized NCs …

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Fasan Rudi, Siriboe Mary G. Bulletin of Japan Society of Coordination Chemistry 80 (0), 4-13, 2022-12-25

<p>Biocatalysis has covered an increasingly important role in the synthesis and manufacturing of pharmaceuticals and other high value compounds. In the interest of expanding the range of …

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高田 昌樹 Bulletin of Japan Society of Coordination Chemistry 79 (0), 100-105, 2022-06-06

<p>Since 2002, the structural science via Maximum Entropy Method based on synchrotron radiation(SR) diffraction data has driven an innovation of structural chemistry in Coordination Chemistry at …

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Miller Joel S. Bulletin of Japan Society of Coordination Chemistry 79 (0), 38-49, 2022-06-06

<p>Numerous coordination compounds have recently been identified exhibit the technologically important property of bulk magnetic ordering as ferro-, ferri- and antiferromagnets. These compounds …

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棚瀬 知明 Bulletin of Japan Society of Coordination Chemistry 79 (0), 25-37, 2022-06-06

<p>Structurally constrained multinuclear transition metal assemblies are fascinating building blocks for atomically precise nanostructured molecular devices due to a variety of functions with …

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大洞 光司 Bulletin of Japan Society of Coordination Chemistry 79 (0), 78-87, 2022-06-06

<p>Hemoprotein containing heme, an iron porphyrin complex, as a cofactor is a promising scaffold toward artificial metalloenzymes and functional materials due to the unique characteristics derived …

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石谷 治 Bulletin of Japan Society of Coordination Chemistry 79 (0), 3-24, 2022-06-06

<p>We found the following new photochemical reactions and photophysical properties of transition metal complexes: (1) photochemical formation of Ru(II) hydride complexes, (2) photochemical ligand …

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貞清 正彰 Bulletin of Japan Society of Coordination Chemistry 79 (0), 88-99, 2022-06-06

<p>Recently, metal–organic frameworks (MOFs) or coordination polymers (CPs) have attracted much attention because of their potential applications such as gas storage, separation, and delivery, …

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馬越 啓介 Bulletin of Japan Society of Coordination Chemistry 79 (0), 58-67, 2022-06-06

<p>Homo- and heteropolynuclear transition-metal complexes are expected to show specific interactions and cooperative effects between metal atoms, providing novel functions that are unobtainable from …

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Higuchi Masayoshi Bulletin of Japan Society of Coordination Chemistry 79 (0), 68-77, 2022-06-06

<p>This award account focuses on metallo-supramolecular polymers (MSPs), which are composed of metal ions and multitopic ligands, as a new branch of coordination polymers. Their high solubility in …

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内田 さやか Bulletin of Japan Society of Coordination Chemistry 79 (0), 106-111, 2022-06-06

<p>Polyoxometalates (POMs) are discrete metal–oxo cluster anions comprising high-valence transition metals (Mo, W, V, Nb, etc.) and have been researched in broad areas of sciences. POMs have …

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Ri Moon Hoi, Kyu Lee Hong, Ha Junsu, Park Jihyun Bulletin of Japan Society of Coordination Chemistry 79 (0), 50-57, 2022-06-06

<p>The studies on dynamic changes in metal-organic frameworks (MOFs) induced by various external stimuli have attracted great attention in various fields and have been continuously investigated …

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加藤 昌子 Bulletin of Japan Society of Coordination Chemistry 78 (0), 3-10, 2021-11-30

<p>Photofunctional chromic metal complexes that exhibit remarkable luminescence and color changes in response to gentle stimuli such as chemical vapor and mechanical stimulus have been extensively …

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岡﨑 雅明 Bulletin of Japan Society of Coordination Chemistry 78 (0), 18-35, 2021-11-30

<p>η²-Disilene transition-metal complexes have been synthesized by a wide variety of synthetic methods and characterized by X-ray diffraction studies. Their reactivity has been …

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Cronin Leroy Bulletin of Japan Society of Coordination Chemistry 78 (0), 11-17, 2021-11-30

<p>The mechanism that controls the self-assembly of complex polyoxometalate inorganic clusters in solution is a challenge because the clusters can contain anywhere from 6 to 368 metal ions in a …

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Ghana Priyabrata, Okuda Jun Bulletin of Japan Society of Coordination Chemistry 77 (0), 37-45, 2021-05-31

<p>In organometallic chemistry and homogeneous catalysis, the design and development of ancillary ligands are pivotal in order to control the central metalʼs reactivity. Whilst for classical late …

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Pei-Qin Liao, Xiao-Ming Chen Bulletin of Japan Society of Coordination Chemistry 77 (0), 3-10, 2021-05-31

<p>Post-synthetic coordination modification has proven to be a general and powerful approach for the functionalization of porous coordination polymers or metal-organic frameworks (MOFs). …

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岩﨑 孝紀 Bulletin of Japan Society of Coordination Chemistry 77 (0), 11-25, 2021-05-31

<p>Transition-metal-catalyzed C–C bond(s) formations are one of the most fundamental organic transformations, where the design of transition metal catalysts is the key of success. To activate two …

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酒田 陽子 Bulletin of Japan Society of Coordination Chemistry 77 (0), 26-36, 2021-05-31

<p>Supramolecular chemistry is the study of the entities based on the noncovalent interactions that play an essential role in controlling of biomolecular functions. In biological system, natural …

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中江 豊崇, 西尾 正樹, 山野井 慶徳 Bulletin of Japan Society of Coordination Chemistry 76 (0), 31-39, 2020-11-30

<p>Extensive investigation of functional organosilicon compounds has identified various valuable applications in materials chemistry. This review summarizes the major developments of metal-mediated …

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桑田 繁樹 Bulletin of Japan Society of Coordination Chemistry 76 (0), 21-30, 2020-11-30

<p>Proton-responsive pincer-type ligands have been used as scaffolds to realize metal–ligand cooperative transformations. Unlike most of the ligands therein, 2,6-bis(pyrazol-3-yl)pyridines (3-bpp) …

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芳賀 正明 Bulletin of Japan Society of Coordination Chemistry 76 (0), 5-20, 2020-11-30

<p>Metal complexes exhibit distinctive optic, magnetic, and redox properties that often depend on the specific combination of metal ion and ligand(s), and both components are attractive building …

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城 宜嗣 Bulletin of Japan Society of Coordination Chemistry 75 (0), 51-56, 2020-05-31

Heme (iron-porphyrin complex) is present in biological system as an active site of several proteins and enzymes, and is involved in many biological conversion processes of bio-energy, bio-compounds, …

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秋根 茂久 Bulletin of Japan Society of Coordination Chemistry 75 (0), 13-27, 2020-05-31

<p>　Metal complexes are generally dynamic due to the reversibility of formation/cleavage of the coordination bonds. Therefore, metal complexes could be used as platforms for switchable functional …

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細野 暢彦 Bulletin of Japan Society of Coordination Chemistry 75 (0), 42-50, 2020-05-31

Porous materials, including porous carbons, zeolites, and porous coordination polymers (PCPs), are generally recognized as rigid, hard, and fragile substances. However, focusing on their structure …

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速水 真也 Bulletin of Japan Society of Coordination Chemistry 75 (0), 28-34, 2020-05-31

<p>　Flexible and soft molecules are at the focus of materials research for the construction of functional devices for polymer, LB film, gel, liquid crystal and a number of biological materials. …

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松原 公紀 Bulletin of Japan Society of Coordination Chemistry 75 (0), 66-75, 2020-05-31

Nickel is one of the first-row transition metals used as alternatives in homogeneous catalysts using precious metals for organic transformations. Nickel(0) and (II) complexes are generally involved …

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Farha Omar K., Zhang Xuan, Knapp Julia G., Hanna Sylvia L., Chen Zhijie, Li Peng Bulletin of Japan Society of Coordination Chemistry 75 (0), 3-12, 2020-05-31

<p>　The coordination chemistry between inorganic and organic species can be optimally exemplified by metal–organic frameworks (MOFs), whose structures and functionalities can be rationally designed …

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吉澤 一成 Bulletin of Japan Society of Coordination Chemistry 75 (0), 57-65, 2020-05-31

Quantum chemical studies on methane C–H bond activation and hydroxylation by methane monooxygenase (iron and copper enzyme species), related metal-oxo species such as FeO+, metal-exchanged zeolites, …

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草本 哲郎 Bulletin of Japan Society of Coordination Chemistry 75 (0), 35-41, 2020-05-31

Stable radicals possessing open-shell electronic states exhibit vivid physical properties such as electric conductivity and magnetism attributed to unpaired electrons. Their luminescent properties, …

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塩谷 光彦 Bulletin of Japan Society of Coordination Chemistry 74 (0), 3-8, 2019-11-30

<p>Supramolecular self-assembly of a certain number of designer organic/inorganic building blocks by directional interactions such as metal coordination is the basis of elaborate molecular systems. …

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大坪 主弥 Bulletin of Japan Society of Coordination Chemistry 74 (0), 19-28, 2019-11-30

<p>Coordination nanomaterials, which are made from a bottom-up assembly of metal ions and organic ligands, have been of particular interest to researchers because of their high degrees of structural …

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森迫 祥吾, 山下 誠 Bulletin of Japan Society of Coordination Chemistry 74 (0), 29-45, 2019-11-30

<p>In this article, recent developments regarding the organometallic chemistry of boron-containing pincer ligands, especially in which a boron coordinated to transition metal center as an anionic …

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小島 隆彦 Bulletin of Japan Society of Coordination Chemistry 74 (0), 9-18, 2019-11-30

<p>Proton-coupled electron transfer (PCET), in which a proton and an electron are directed to respective accepting sites separately, is a fundamental process as observed in many kinds of redox …

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楊井 伸浩 Bulletin of Japan Society of Coordination Chemistry 73 (0), 24-31, 2019-05-31

<p>Photon upconversion (UC) is the process that converts longer wavelength (lower energy) light to shorter wavelength (higher energy) light. Among different UC mechanisms, the UC based on …

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Coudert François-Xavier Bulletin of Japan Society of Coordination Chemistry 73 (0), 15-23, 2019-05-31

<p>Recent years have seen a large increase in the number of reported framework materials, including the nowadays-ubiquitous metal–organic frameworks (MOFs). Many of these materials show flexibility …

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Solomon Edward I., Iyer Shyam R. Bulletin of Japan Society of Coordination Chemistry 73 (0), 3-14, 2019-05-31

<p>While two classes of non-heme iron enzymes use ferric centers to activate singlet organic substrates for the spin forbidden reaction with ³O₂, most classes use high spin …

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錦織 広昌, 新里 光矢 Bulletin of Japan Society of Coordination Chemistry 72 (0), 30-37, 2018-11-30

<p>The dye–titania interaction is very important for the electron injection process in dye-sensitized solar cells (DSSCs). For example, the steam treatment of a fluorescein-dispersing amorphous …

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三宅 弘之 Bulletin of Japan Society of Coordination Chemistry 72 (0), 38-47, 2018-11-30

<p>Labile metal complexes have a dynamic coordination bond which is generally weaker than a common covalent bond found in organic molecules but more useful for incorporation of external donor …

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森 聖治 Bulletin of Japan Society of Coordination Chemistry 72 (0), 15-29, 2018-11-30

Homogeneous metal-catalyzed molecular bond activation reactions have been developed in the respect of effective atom economy and efficiency. Despite of rapid development of these reactions, …

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沈 建仁 Bulletin of Japan Society of Coordination Chemistry 72 (0), 3-14, 2018-11-30

<p>Photosystem II (PSII) is a huge membrane-protein complex catalyzing light-induced electron transfer and water oxidation reactions, leading to the conversion of light energy into chemical energy …

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西林 仁昭 Bulletin of Japan Society of Coordination Chemistry 71 (0), 49-55, 2018-05-31

<p>This paper describes our recent progress in catalytic nitrogen fixation by using transition metal-dinitrogen complexes as catalysts. Novel reaction systems for the catalytic transformation of …

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Willkomm Janina, Reisner Erwin Bulletin of Japan Society of Coordination Chemistry 71 (0), 18-29, 2018-05-31

<p>Converting sunlight into storable chemical energy carriers, such as dihydrogen (H₂), through light-driven splitting of water is a widely studied approach to secure future energy …

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北河 康隆, 齋藤 徹, 山口 兆 Bulletin of Japan Society of Coordination Chemistry 71 (0), 57-68, 2018-05-31

<p>A broken-symmetry (BS) method is now widely used for systems that involve (quasi) degenerate frontier orbitals because of their lower cost of computations. The BS method splits up-spin and …

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田代 省平 Bulletin of Japan Society of Coordination Chemistry 71 (0), 39-48, 2018-05-31

<p>In this account, a new method for the creation of porous functional materials based on the self-organization of metallomacrocycles is described. For instance, the authors have developed a new …

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佐藤 弘志 Bulletin of Japan Society of Coordination Chemistry 71 (0), 30-38, 2018-05-31

<p>Porous materials with infinite number of nanometer-sized pores are ubiquitous materials in our daily life as functional substances that efficiently separate or remove small molecules such as gas …

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Liu Yuzhong, Yaghi Omar M. Bulletin of Japan Society of Coordination Chemistry 71 (0), 12-17, 2018-05-31

<p>Transition metal ions as a template method has been widely used in the field of supramolecular chemistry. The metal complexation is advantageous in making complex supramocluar architectures …

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小坂田 耕太郎 Bulletin of Japan Society of Coordination Chemistry 71 (0), 3-11, 2018-05-31

<p>Transition metal complexes, having the coordination bonds with strong covalent-bond characters, undergo various bondforming reactions, similar to the organo-transition metal complexes with a …

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中沢 浩 Bulletin of Japan Society of Coordination Chemistry 69 (0), 12-20, 2017

<p>Transition metal complexes have attracted considerable attentions because they show a variety of structures, reactivities, and properties. We have focused on the reactivity, especially the …

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大塩 寛紀 Bulletin of Japan Society of Coordination Chemistry 69 (0), 2-11, 2017

<p>A metal complex may have flexible structure and electronic state which can be artificially modified and easily controlled. Such flexibilities can be useful tools for constructing functional …

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山下 弘巳 Bulletin of Japan Society of Coordination Chemistry 69 (0), 35-44, 2017

<p>Design of single-site photocatalysts (tetrahedral-coordinated metal oxide moiety, metal complexes) in nanoporous materials (zeolites, mesoporous silica, metal-organic frameworks) not only can …

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大久保 將史 Bulletin of Japan Society of Coordination Chemistry 69 (0), 45-49, 2017

<p>Battery technology is a key to realize a sustainable society. The currently-used lithium-ion batteries, which were commercialized in 1991 by SONY, have high gravimetric/volumetric energy …

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森内 敏之 Bulletin of Japan Society of Coordination Chemistry 70 (0), 22-31, 2017

<p>In this account, recent advances in the design of bioorganometallic complexes by the conjugation of organometallic complexes with nucleobases are focused on to exhibit specific properties based …

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磯部 寛 Bulletin of Japan Society of Coordination Chemistry 70 (0), 2-13, 2017

<p>This account describes a current summary of our computational studies intended to elucidate the mechanism underlying water oxidation by the tetranuclear Mn cluster in the oxygen-evolving complex …

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Yam Vivian Wing-Wah Bulletin of Japan Society of Coordination Chemistry 69 (0), 21-28, 2017

<p>Platinum(II) complexes have been extensively explored in previous years due to their intriguing chromphoric and aggregation properties. The introduction of supramolecular assembly components …

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Jonathan Nitschke, 三原のぞみ Bulletin of Japan Society of Coordination Chemistry 69 (0), 29-34, 2017

<p>This article describes the recent research on molecular cages achieved in Nitschkeʼs group. Subcomponent self-assembly allows the construction of molecular cages from simple building blocks via …

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松本 崇弘 Bulletin of Japan Society of Coordination Chemistry 69 (0), 50-55, 2017

<p>In this review, dihydrogen and dioxygen activation by an oxygen-tolerant hydrogenase and its models is described. While a standard hydrogenase can only oxidize dihydrogen, the oxygen-tolerant …

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小笠原 正道 Bulletin of Japan Society of Coordination Chemistry 70 (0), 14-21, 2017

<p>Planar-chiral transition-metal complexes are important chiral scaffolds in organic and organometallic chemistry and have been utilized as chiral ligands, chiral catalysts, or chiral building …

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山田 裕介 Bulletin of Japan Society of Coordination Chemistry 68 (0), 16-28, 2016

<p>Recent reports on utilization of polymeric cyano-bridged metal complexes, which have reticular structures utilizing M^C–CN–M^N coordination networks, as heterogeneous …

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三方 裕司 Bulletin of Japan Society of Coordination Chemistry 68 (0), 3-15, 2016

<p>Fluorescent detection of specific metal ions with organic ligands is an attractive subject in coordination chemistry. This account summarizes the evolution history of fluorescent metal sensor …

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西原 寛 Bulletin of Japan Society of Coordination Chemistry 67 (0), 2-9, 2016

<p>In this review, a new research area on highly integrated metal-containing p-conjugated and/or redox-active systems constructed by <i>coordination programming</i>, which is to utilize the …

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有賀 克彦 Bulletin of Japan Society of Coordination Chemistry 67 (0), 30-40, 2016

<p>Fabrication of functional materials through self-assembly and coordination chemistry at interface becomes hot topics in recent research activities. However, supramolecular chemistry at interface …

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Que, Jr. Lawrence, Puri Mayank Bulletin of Japan Society of Coordination Chemistry 67 (0), 10-18, 2016

<p>The investigation of synthetic nonheme oxoiron(IV) complexes has been stimulated by the trapping of such intermediate species in the catalytic cycles of several dioxygen activating nonheme iron …

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Chirik Paul J., Schaefer Brian A., Margulieux Grant W. Bulletin of Japan Society of Coordination Chemistry 67 (0), 19-29, 2016

<p>Cationic bis(imino)pyridine iron alkene complexes, key intermediates in the polymerization and oligomerization of ethylene, have been targeted to understand important physical properties such as …

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作田 絵里 Bulletin of Japan Society of Coordination Chemistry 67 (0), 62-74, 2016

<p>In this review, we overview the recent research trends on the photophysical properties and its application of metal complexes having arylborane charge transfer unit(s). The vacant p-orbital on …

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坂本 良太 Bulletin of Japan Society of Coordination Chemistry 67 (0), 41-46, 2016

<p>The author has investigated on one-dimensional wires and two-dimensional nanosheets based on coordination compounds. At the same time, molecular chemistry on the metal complex motifs used therein …

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砂田 祐輔 Bulletin of Japan Society of Coordination Chemistry 67 (0), 47-61, 2016

<p>In this review, synthesis and applications of a series of novel transition metal complexes bearing the disilametallacycle skeleton have been reported. The first topic is the synthesis of an …

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川本 圭祐, 橋本 秀樹 Bulletin of Japan Society of Coordination Chemistry 67 (0), 75-79, 2016

<p>In this topic, we introduce some previous researches on metal complexes using electroabsorption (Stark) spectroscopy. It measures the effect of an applied electric field on an absorption spectrum …

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浦 康之 Bulletin of Japan Society of Coordination Chemistry 65 (0), 49-52, 2015

Synthesis of methanol from methane and terminal alcohols from linear alkanes using molecular oxygen as an oxidant under mild conditions is an attractive and environmentally-friendly transformation …

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佐藤 宗太 Bulletin of Japan Society of Coordination Chemistry 65 (0), 30-37, 2015

The clusters of biomolecules have an important role as recognition interface in living systems, where the weak molecular recognition of each biomolecular unit is efficiently enhanced by the dense …

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榧木 啓人 Bulletin of Japan Society of Coordination Chemistry 66 (0), 3-11, 2015

Homogeneous gold catalysis has attracted intensive interest from synthetic chemists because of its significant advances in the field of carbon-carbon and carbon-heteroatom bond formations. The gold …

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山下　 正廣 Bulletin of Japan Society of Coordination Chemistry 65 (0), 2-8, 2015

Spintronics is a key technology in 21^st century based on the freedoms of the charge, spin, as well as orbital of the electron. Usually in these systems, the bulk or classical magnets …

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Suh Myunghyun Paik Bulletin of Japan Society of Coordination Chemistry 65 (0), 9-22, 2015

In this review, properties and applications of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) are described. Many MOFs and PCPs are highly flexible and responsive to …

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劒 隼人 Bulletin of Japan Society of Coordination Chemistry 65 (0), 38-48, 2015

In this review, we report a new reduction protocol for early transition metal complexes – a salt-free reduction. In this salt-free reduction process, electron-rich organosilicon compounds, such as …

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杉本 直己 Bulletin of Japan Society of Coordination Chemistry 65 (0), 23-29, 2015

Nucleic acids can adopt many types of noncanonical structures such as a triple helix and a quadruplex depending on the sequence and solution conditions. Recently, we developed a molecular crowding …

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林 宜仁 Bulletin of Japan Society of Coordination Chemistry 66 (0), 12-25, 2015

Inorganic ligands, such as polyoxovanadates, may offer a new way to further expand the boundary of coordination chemistry for inorganic complexes featuring a part of metal oxide structures. Many …

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大木 靖弘 Bulletin of Japan Society of Coordination Chemistry 66 (0), 26-30, 2015

Nirtogenases are a class of enzymes that catalyze the reduction of N₂ to NH₃ under ambient conditions in the presence of protons and electrons. The active site of the most …

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堀内 新之介 Bulletin of Japan Society of Coordination Chemistry 66 (0), 31-33, 2015

Inspired by the efficiency displayed by enzymes, self-assembled cages with nanometer-sized cavities have been demonstrated as molecular flasks which can alter reaction pathways to show unusual …

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森本 祐麻 Bulletin of Japan Society of Coordination Chemistry 63 (0), 49-51, 2014

Molecular oxygen is a highly atom-economical, environmentally benign, and abundant oxidant. However, the large activation energies in the reactions of oxygen and formation of undesirable …

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伊藤 亮孝 Bulletin of Japan Society of Coordination Chemistry 63 (0), 46-48, 2014

Recent research trends on the photophysical properties of transition metal complexes under rigid environments are overviewed. Since the transition metal complexes are often introduced into rigid …

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堀毛 悟史 Bulletin of Japan Society of Coordination Chemistry 63 (0), 38-45, 2014

Crystalline coordination frameworks often have intrinsic molecular dynamics such as rotation, libration in wide temperature range. The cooperative motions in the frameworks are controllable by …

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猪熊 泰英 Bulletin of Japan Society of Coordination Chemistry 63 (0), 29-37, 2014

This review describes a newborn method for the single crystal X-ray analysis of non-crystalline or trace amount of compounds in which single crystal samples are prepared without recrystallization of …

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黒田 一幸 Bulletin of Japan Society of Coordination Chemistry 64 (0), 2-13, 2014

Our recent results on the preparation of silica-based nanoporous materials with unique structures and porosities, derived from various starting materials, have been reviewed. The interactions …

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増田 秀樹 Bulletin of Japan Society of Coordination Chemistry 63 (0), 2-18, 2014

Biological functions in metallo-enzymes are induced by the unique first and secondary coordination spheres around the metal ions of active centers. We designed and prepared some structural and …

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Braunstein Pierre Bulletin of Japan Society of Coordination Chemistry 63 (0), 19-28, 2014

This Account will focus on some recent aspects of the research performed in the author’s laboratory. Selected examples of complexes in which the ligands play an essential role in determining the …

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錦織 広昌, 轟 健太 Bulletin of Japan Society of Coordination Chemistry 64 (0), 28-31, 2014

Ruthenium complexes are used as effective sensitizers for the dye-sensitized solar cells. The electrons are excited from the HOMO (metal) to LUMO (ligand), and then injected into the titania …

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石田 斉 Bulletin of Japan Society of Coordination Chemistry 64 (0), 14-24, 2014

In a luminescent metal complex, the singlet excited state readily converts the excitation energy to the triplet state by increasing the spin-orbit coupling due to the presence of a heavy atom such a …

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越山 友美 Bulletin of Japan Society of Coordination Chemistry 64 (0), 25-28, 2014

Coordination polymers (CPs) or metal-organic frameworks (MOFs) are attractive porous materials because of their potential applications such as molecular storage, separation, heterogeneous catalysis, …

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野呂 真一郎 Bulletin of Japan Society of Coordination Chemistry 61 (0), 38-45, 2013

Host materials based on metal complexes are of great interest because of their high structural and functional diversities. To obtain unique and applicative metal complex hosts, we attempted new …

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徂徠 道夫 Bulletin of Japan Society of Coordination Chemistry 61 (0), 17-37, 2013

Better understanding of materials should be achieved by complementarily employing experimental techniques which lead to either microscopic or macroscopic aspect. The specific characteristic of …

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山内 幸正 Bulletin of Japan Society of Coordination Chemistry 62 (0), 26-28, 2013

In nature, hydrogenase enzymes catalyze H<SUB>2</SUB> production from water with the turnover frequency (TOF) of 9000 s<SUP>-1</SUP>. In this context, studies on the water-splitting reactions with …

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伊藤 肇, 関 朋宏 Bulletin of Japan Society of Coordination Chemistry 62 (0), 3-11, 2013

Aryl gold isocyanide complexes are found to have interesting photoluminescence properties in the solid state, being referred to as luminescence mechanochromism and molecular domino. A gold complex …

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山田 鉄兵 Bulletin of Japan Society of Coordination Chemistry 61 (0), 46-54, 2013

Proton conductors are applied as electrolytes in fuel cells and act as key material in it. We introduced acidic functional groups into the porous coordination polymer (PCP), or metal-organic …

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鈴木 正樹 Bulletin of Japan Society of Coordination Chemistry 61 (0), 2-16, 2013

Dioxygen binding and activation by non-heme type transition metal complexes are of current interest due to its importance in biological system and industrial processes. Since active-oxygen species …

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山田 泰之, 田中 健太郎 Bulletin of Japan Society of Coordination Chemistry 62 (0), 12-22, 2013

In this review, we focus on the integrated assemblies of metal complexes and their functional emergence generated by the synergy effects of π-π stacking interaction and metal complexation. …

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板崎 真澄, 神谷 昌宏 Bulletin of Japan Society of Coordination Chemistry 62 (0), 23-26, 2013

Hydrogen is a promising potential source of environmentally-clean energy. However, the transport, storage, and handling of hydrogen gas have some problems because of its physical properties. …

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Kimura Eiichi Bulletin of Japan Society of Coordination Chemistry 59 (0), 26-47, 2012-05-31

Our chemical exploitation of saturated macrocyclic polyamines has led to discoveries of numerous new functions, and synthesis of new functional molecules and supramolecular complexes. In this …

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Po-Chun Liu Isiah, Chen Chun-hsien, Peng Shie-Ming Bulletin of Japan Society of Coordination Chemistry 59 (0), 3-10, 2012-05-31

The revisit of Ni<SUB>3</SUB>(dpa)<SUB>4</SUB>Cl<SUB>2</SUB> (dpa<SUP>-</SUP> = dipyridylamido anion) by the groups of Hathaway, Cotton, and ours in the early 1990s extended the knowledge of …

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小澤 寛晃, 芳賀 正明 Bulletin of Japan Society of Coordination Chemistry 60 (0), 2-23, 2012

Assembling functional coordination compounds into nano-scaled architectures on solid surfaces is a fundamental topic of nanomaterial science because of tremendous applications in electronics and …

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田邊 真 Bulletin of Japan Society of Coordination Chemistry 60 (0), 34-37, 2012

The catalytic dehydrocoupling reactions of amine-boranes have attracted considerable interest from the perspectives of chemical hydrogen storage and the production of new inorganic polymers. In …

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久米 晶子 Bulletin of Japan Society of Coordination Chemistry 59 (0), 48-55, 2012

In this review, a family of new bistable copper complexes has been rationally assembled from the basic components, which undergoes the coordination isomerization by rotation of coordinated …

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米田 宏, 大場 正昭 Bulletin of Japan Society of Coordination Chemistry 59 (0), 66-81, 2012

Since the discovery of the fascinating structures and properties of porous coordination polymers (PCPs), also known as metal—organic frameworks (MOFs), the designing skills and synthetic methods for …

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呉 威毅, 神川 憲 Bulletin of Japan Society of Coordination Chemistry 60 (0), 24-31, 2012

In this review, haptotropic isomerizations and arene ligand exchange reactions of the tircarbonyl chromium complexes have been reported. Haptotropic metal migration reactions are well known …

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田代 省平 Bulletin of Japan Society of Coordination Chemistry 60 (0), 32-34, 2012

Porous metal complexes such as metal-organic framework (MOF) and porous coordination polymer (PCP) are one of the current attractive structural motifs because of their utility for several practical …

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大洞 光司 Bulletin of Japan Society of Coordination Chemistry 59 (0), 82-83, 2012

In biological systems, many protein assemblies are ubiquitous and play various, complicated and important roles. Most of such assemblies are achieved with electrostatic, hydrophobic and hydrogen …

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二瓶 雅之 Bulletin of Japan Society of Coordination Chemistry 59 (0), 56-65, 2012

This review article describes multi-stabilities and multi-responses in multicomponent metal complexes as well as cyanide-bridged multinuclear clusters. Spin-crossover complexes are bistable …

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渡辺 芳人 Bulletin of Japan Society of Coordination Chemistry 59 (0), 11-25, 2012

Heme enzymes responsible for a variety of oxidation are believed to afford an O=Fe(IV) porphyrin cation radical intermediate as the common reactive species. We have studied detailed mechanisms of …

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亀尾 肇 Bulletin of Japan Society of Coordination Chemistry 58 33-35, 2011

In this contribution, the chemistry of borane ligands acting as sigma electron acceptors has been reviewed briefly. Borane works as a Lewis acid by its empty p orbital, and can withdraw the electron …

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藤田 誠 Bulletin of Japan Society of Coordination Chemistry 57 (0), 13-29, 2011

Molecular self-assembly has recently undergone on explosive development, making possible the synthesis of many fascinating and complex structures using only relatively simple procedures. Over the …

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松田 亮太郎 Bulletin of Japan Society of Coordination Chemistry 57 45-56, 2011

Nanoporous materials are ubiquitous and indispensable in daily life as adsorbents. The discovery of a new porous compound having unique properties based on intrinsic nano-sized space and surface …

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錦織 広昌 Bulletin of Japan Society of Coordination Chemistry 57 77-80, 2011

Spirooxazines (SOs) exhibit the well-known photochromic reaction of photoinduced interconversion between the original colorless form and the colored merocyanine (MC) form. The MC easily coordinates …

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作田 絵里, 喜多村 昇 Bulletin of Japan Society of Coordination Chemistry 57 75-77, 2011

In this topics, we overview the recent research trends on the photophysical properties of ruthenium(II) and rhenium(I) complexes having arylborane charge transfer unit(s). The vacant p-orbital on …

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中野 元裕 Bulletin of Japan Society of Coordination Chemistry 58 6-19, 2011

The octahedral manganese(III) complex, [Mn<SUP>III</SUP>(taa)] (H<SUB>3</SUB>taa = tris(1-(2-azolyl)-2-azabuten-4-yl)amine), has long been known as a rare example of (3d)<SUP>4</SUP> spin-crossover …

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阿部 正明 Bulletin of Japan Society of Coordination Chemistry 58 20-32, 2011

Recent progress in the redox chemistry of multimetallic transition-metal complexes and clusters is reviewed. Special attention is paid to high-nuclearity complexes wherein redox-active sites (e.g., …

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Udit Andrew K, Hill Michael G, Winkler Jay R, Gray Harry B Bulletin of Japan Society of Coordination Chemistry 57 2-12, 2011

Employing laser flash-quench triggering methods, we have shown that 20-angstrom, coupling-limited Cu(I) to Ru(III) electron tunneling in Ru-modified blue copper proteins can occur on the microsecond …

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橋本 和仁 Bulletin of Japan Society of Coordination Chemistry 57 30-35, 2011

Genus Shewanella is a gram-negative microorganism which has a unique property of utilizing solid state metal-oxide as a terminal electron acceptor. The extracellular electron transfer (ET) occurs …

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高石 慎也 Bulletin of Japan Society of Coordination Chemistry 57 (0), 36-44, 2011

Metal complexes have originally many kinds of bistability owing to charge, spin, lattice etc. Recently, there has been much effort for controlling the macroscopic properties by the molecular …

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倉橋 拓也, 藤井 浩 Bulletin of Japan Society of Coordination Chemistry 57 57-66, 2011

In order to garner in-depth understanding of oxidation catalysis by salen complexes, we investigated the conformation, electronic structure and reactivity of high-valent salen complexes. We herein …

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八木 政行 Bulletin of Japan Society of Coordination Chemistry 57 67-74, 2011

Artificial photosynthesis is expected as one of promising clean energy-providing systems in future. Development of an efficient catalyst for water oxidation to evolve O<SUB>2</SUB> is a key task to …

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真島, 豊, MAJIMA, YUTAKA 第60回記念錯体化学OSAKA国際会議 講演要旨集 2010-09

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柘植 清志 Bulletin of Japan Society of Coordination Chemistry 56 (0), 24-40, 2010

Recent development of emissive transition metal complexes involves synthesis of various copper(I) and gold(I) complexes that reveals attracting emissive nature of monovalent group 11 metal …

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水田 勉 Bulletin of Japan Society of Coordination Chemistry 56 (0), 2-13, 2010

Ferrocenophosphines have a long history. The first phosphorus compound having a ferrocenyl group had appeared only 10 years after the discovery of ferrocene. Since then, a vast number of …

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小泉 武昭, 神原 貴樹 Bulletin of Japan Society of Coordination Chemistry 56 (0), 14-23, 2010

Oxidative dehydrogenation of alcohols and amines is one of the most fundamental and important reactions in organic chemistry and industrial processes. To avoid the environmental pollution, the …

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秋津 貴城, 山崎 敦央 Bulletin of Japan Society of Coordination Chemistry 55 78-79, 2010

Time-dependent density functional theory has been successfully applied to analyze circular dichroism spectra of Δ- or Λ- octahedral metal complexes with bidentate ligands containing both s- and …

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棚瀬 知明 Bulletin of Japan Society of Coordination Chemistry 55 52-70, 2010

This account reports recent development of linearly ordered multinuclear transition-metal complexes, or molecular metal atom chains, supported by multidentate phosphines, which could be important …

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有川 康弘 Bulletin of Japan Society of Coordination Chemistry 55 31-38, 2010

In this article, our study of dynamic NO ligands on ruthenium complexes has been reported. Transformation of NO ligand, linear NO<SUP>+</SUP> and bent NO<SUP>-</SUP> form, is characteristic of NO …

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小野田 晃 Bulletin of Japan Society of Coordination Chemistry 56 41-42, 2010

One useful synthetic reaction missing from nature's toolbox is the direct hydrogenation of substrates using hydrogen. To create an enzyme that can directly reduce organic substrates with hydrogen, …

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金井塚 勝彦 Bulletin of Japan Society of Coordination Chemistry 55 79-80, 2010

Metal-organic frameworks on electrode surfaces have been developed via bottom-up syntheses to fabricate a promising catalytic device with specific shape and sized nanospaces. A metal-organic …

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山村 剛士, 有安 真也 Bulletin of Japan Society of Coordination Chemistry 55 (0), 71-77, 2010

In this review, we focus on the recent development of conjugates between nanoparticles (NPs) and biomolecules such as DNAs, as well as a brief history for inorganic bioconjugate chemistry. …

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松尾 豊 Bulletin of Japan Society of Coordination Chemistry 55 39-51, 2010

This review article describes synthetic chemistry and materials science of metal-fullerene complexes. The contents include six topics: 1) Development of synthetic methodology for metal-fullerene …

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谷口 功 Bulletin of Japan Society of Coordination Chemistry 55 19-30, 2010

In this account, typical achievements for these 30 years related to metalloprotein electrochemistry using various functional electrodes and related fields are reviewed, for which JSCC award of 2009 …

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Sauvage Jean-Pierre Bulletin of Japan Society of Coordination Chemistry 55 3-18, 2010

The chemistry of molecules displaying novel topologies has experienced an explosive development in the course of the last 25 years. The fast growth of this field originates to a large extend from …

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久枝 良雄 Bulletin of Japan Society of Coordination Chemistry 54 10-21, 2009

This account describes a current summary of our research on the development of bio-inspired catalysts with vitamin B₁₂ enzyme functions for degradation of environmental pollutants. We …

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松本 剛 Bulletin of Japan Society of Coordination Chemistry 54 (0), 38-51, 2009

This review summarizes the recent progress of the studies on acetyl CoA synthase (ACS), a metalloenzyme that plays an important role of fixing CO and CO₂ in the global carbon cycle. ACS …

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杉本 学 Bulletin of Japan Society of Coordination Chemistry 54 (0), 52-67, 2009

Theoretical and computational studies on metal-complex photosensitizers, photo-induced electron transfer, and electric characteristics of dye-sensitized solar cells (DSSC) are reviewed as a typical …

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久保 和幸 Bulletin of Japan Society of Coordination Chemistry 54 68-70, 2009

This contribution describes a brief overview of the chemistry of divalent carbon(0) compounds, carbodiphosphoranes (CDPs) and carbodicarbenes (CDCs), which have currently emerged as an important new …

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Collman James P., Decréau Richard A. Bulletin of Japan Society of Coordination Chemistry 54 3-9, 2009

A new functional biomimetic model of cytochrome c oxidase is reported. It is synthesized in 32 steps. Single turnover reaction with oxygen leads to the same intermediates as the ones reported in the …

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鈴木 教之 Bulletin of Japan Society of Coordination Chemistry 53 (0), 43-57, 2009

This review describes a series of five-membered metallacyclic compounds of unsaturated carbon-carbon bonds, especially, 1-metallacyclopenta-2,3,4-trienes, 1-metallacyclopent-3-ynes and …

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田中 晃二 Bulletin of Japan Society of Coordination Chemistry 53 3-16, 2009

Proton dissociation of an aqua-Ru-quinone complex, [Ru(trpy)(3,5-t-Bu₂q)(OH₂)]²⁺ (trpy = 2,2’:6’,2”-terpyridine, 3,5-t-Bu₂q = …

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相田 卓三 Bulletin of Japan Society of Coordination Chemistry 53 17-23, 2009

This review article gives an overview of our recent discovery that a Gemini-shaped hexa-<i>peri</i>-hexabenzocoronene (HBC) amphiphile (<b>1</b>) and its derivatives undergo highly controlled …

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井頭 麻子 Bulletin of Japan Society of Coordination Chemistry 54 70-72, 2009

Transition metal complexes containing a metal–metal bond have received considerable attention not only due to fundamental understanding of their bonding nature but also their potential applications. …

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長尾 宏隆 Bulletin of Japan Society of Coordination Chemistry 54 (0), 22-37, 2009

In this accounts, syntheses and reactions of ruthenium complexes bearing pyridyl-containing ligands have been described. The properties and reactivity of complexes are related to their geometrical …

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岩村 宗高 Bulletin of Japan Society of Coordination Chemistry 53 58-59, 2009

Real-time observations of ultrafast relaxation dynamics of metal complexes are very important for fundamental understanding of photo-excited states of this class of molecules. In these topics, some …

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張 浩徹 Bulletin of Japan Society of Coordination Chemistry 53 24-32, 2009

The present contribution reviews the synthesis and properties of complexes including redox-active dioxolene ligands as well as its analogues, diiminosemiquinonato, and dithiolene ligands. This …

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高見澤 聡 Bulletin of Japan Society of Coordination Chemistry 53 33-42, 2009

In this article, gas inclusion phenomena for a flexible single-crystal host have been described. The synthesized single crystal hosts exhibit high flexibility and adjustability for the properties of …

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Graetzel Michael Bulletin of Japan Society of Coordination Chemistry 51 3-12, 2008

In this review, I will describe our research in the field of molecular engineering of transition metal complexes for use as sensitizers in dye sensitized solar cells (DSC), light emitting agents in …

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秋津 貴城 Bulletin of Japan Society of Coordination Chemistry 51 55-64, 2008

In this review, current development of studies on electronic structures of the copper active sites of multicopper oxidase (MCO) by various spectroscopic methods and related electronic functions have …

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村橋 哲郎 Bulletin of Japan Society of Coordination Chemistry 51 31-40, 2008

Recent development in the chemistry of multinuclear sandwich compounds is summarized in this article. Existence of stable multinuclear sandwich complexes was proven through isolation and structural …

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北川 進 Bulletin of Japan Society of Coordination Chemistry 51 13-19, 2008

The chemistry of the coordination polymers has in recent years advanced extensively, affording various architectures, which are constructed from a variety of molecular building blocks with different …

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坪村 太郎, 佃 俊明, 松本 健司 Bulletin of Japan Society of Coordination Chemistry 52 (0), 29-42, 2008

The study in the area of luminescent d¹⁰ complexes has been developing rapidly. The metals with d¹⁰ electronic configuration have a closed d-shell, therefore the nature of the …

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小島 隆彦 Bulletin of Japan Society of Coordination Chemistry 52 (0), 3-16, 2008

This account describes a current summary of our research on ruthenium complexes having tris(2-pyridylmethyl)amine (TPA) and its derivatives as ligands. Topics include their characteristics, …

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山口 佳隆 Bulletin of Japan Society of Coordination Chemistry 52 43-54, 2008

Since the successful isolation of <I>N</I>-heterocyclic carbenes (NHCs), NHCs are now fully established as an important class of ligands for the homogeneous catalysis. The most common method for the …

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藤田 恵津子, Muckerman James T. Bulletin of Japan Society of Coordination Chemistry 51 (0), 41-54, 2008

Solar energy is a more abundant source of energy than any other source. Many researchers consider solar generation of fuels (stored in the form of chemical bonds such as hydrogen from water and …

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小林 厚志 Bulletin of Japan Society of Coordination Chemistry 51 65-66, 2008

Porous metal-organic framework (MOFs) and porous coordination polymers have attracted much attention and extensively studied for past decades because of their interesting properties applicable to …

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正岡 重行 Bulletin of Japan Society of Coordination Chemistry 51 66-67, 2008

Visible-light-induced water splitting into hydrogen gas (H<SUB>2</SUB>) and oxygen gas (O<SUB>2</SUB>) attracts much attention for the development of fossil-fuel-independent energy systems. The …

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上野 隆史 Bulletin of Japan Society of Coordination Chemistry 51 20-30, 2008

In recent years, efforts to design protein monomers and assemblies conjugated with metal complexes have attracted much attention in the field of coordination chemistry because protein scaffolds …

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有川 康弘 Bulletin of Japan Society of Coordination Chemistry 52 55-56, 2008

Activation of atmospheric dinitrogen under mild conditions has remained a challenge to chemists for more than a century. In addition to the fixation of dinitrogen to ammonia, direct elaboration of …

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御厨 正博 Bulletin of Japan Society of Coordination Chemistry 52 17-28, 2008

In this review, a new method for the preparation of metal-assembled complexes based on copper(II) acetate type dinuclear systems has been reported. A variety of coordination modes of carboxylato …

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北河 康隆 Bulletin of Japan Society of Coordination Chemistry 52 56-58, 2008

In this paper, a topic about recent theoretical calculations for di-chromium(I) complex and its related complexes is introduced. In 2005, a synthesis of a novel complex which has a short Cr(I)-Cr(I) …

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杉本 秀樹 Bulletin of Japan Society of Coordination Chemistry 50 (0), 26-39, 2007

Recent advance of bioinspired coordination chemistry of molybdenum and tungsten ions has been reviewed. New synthetic methods to modeling uncommon core structures, sulfido and oxo-sulfido metal …

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西藪 隆平 Bulletin of Japan Society of Coordination Chemistry 50 41-42, 2007

Spontaneous formation of submicron sized coordination polymer particles through self-assembly of metal ions and ligands has been reported by several research groups in the last few years. In this …

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須崎 裕司 Bulletin of Japan Society of Coordination Chemistry 50 40-41, 2007

A “molecular Borromean rings” was obtained by 2:2 condensation of difunctionalized bipyridine and diformylpyridine in the presence of M(OAc)₂ (M = Zn, Cu) in high yield. A similar …

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磯辺 清, 中井 英隆, 小島 創太 Bulletin of Japan Society of Coordination Chemistry 50 2-17, 2007

In this article, we report unique reactivities of hydrogensulfide (SH), disulfide (S₂), and oxydisulfide ligands (S₂O_n: n = 1-4) bridging between the Rh—Rh/Ir—Ir …

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上野 圭司, 村岡 貴子 Bulletin of Japan Society of Coordination Chemistry 50 18-25, 2007

Synthesis, bonding, and reactivity of terminal gallylene and gallium-bridged complexes with two-coordinate gallium centers are discussed in this review. The M-Ga bonds in these complexes are …

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山崎 一雄 化学教育 31 (1), 29-31, 1983

...1982年8月23-27日ハンガリイのブダペストで第22回国際錯体化学会議(International Conference on Coordination Chemistry, 略称ICCC)が開かれたとき, 第1日, 23日の午後"大学教育カリキュラムにおける錯体化学"という小さなシンポジウムが行われた。...

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