Chromatography for sustainable polymeric materials : renewable, degradable and recyclable
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書誌事項
Chromatography for sustainable polymeric materials : renewable, degradable and recyclable
（Advances in polymer science, 211）
Springer, c2008
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注記
Includes bibliographical references and index
"e-ISBN:9783540787631"---t. p. verso
内容説明・目次
内容説明
Polymericmaterials, both"inert"anddegradable,constantlyinteractwiththe surroundings. Because of this interaction changes take place in the polymer matrix and small molecules are released to the environment. Reliable me- ods for testing biodegradability and environmental interaction of renewable resources and biodegradable polymers are required to answer the rema- ing questions concerning the environmental impact of these future materials. Inthecaseofdegradablepolymersmultiplefactorsaffectthedegradation process and small changes in the chemical structure or product formulation may change the susceptibility to degradation or cause different degradation product patterns, rendering the product less environmentally adaptable. - velopment of sustainable polymeric materials also demands the development of more migration-resistant polymer additives. Chromatographic techniques especially gaschromatographyandliquidchromatographypreferentially c- pled to mass spectrometric detection are ideal tools for studying these low molecular weight compounds and polymer-environment interactions. In the ?rst chapter of this volume chromatographic ?ngerprinting and - dicator product concepts are presented as tools for evaluating polymeric - terials.
These concepts have great potential in evaluation of degradation state andlife-time/service-life ofpolymericmaterials, evaluation ofanti-oxidant or pro-oxidant systems, degradation mechanism and processing parameters as wellasrapidcomparisonandqualitycontrolofmaterials.Thesolid-phase- croextractiontechniquehasrapidlyfoundapplicationsinnumerous?elds.The second chapter reviews the extraction of polymer degradation products and additives, monomer-rests, odour compounds, migrants from packaging and medicalproductsaswellasextractionofpolymeradditivesfromenvironm- talsamplesandbiological?uidsbysolid-phasemicroextractiondemonstrating the high versatility and potential of this technique also in polymer analysis.
目次
L. Burman, A.-C. Albertsson, M. Hakkarainen: Indicator Products and Chromatographic Fingerprinting: New Tools for Degradation State and Lifetime Estimation.- M. Hakkarainen: Solid-Phase Microextraction for Analysis of Polymer Degradation Products and Additives.- M. Groening, M. Hakkarainen, A.-C. Albertsson: Quantitative Determination of Volatiles in Polymers and Quality Control of Recycled Materials by Static Headspace Techniques.- M. Hakkarainen, A.-C. Albertsson: Degradation Products of Aliphatic and Aliphatic-Aromatic Polyesters.- C. Strandberg, A.C. Albertsson: Chromatographic Analysis of Antioxidants in Polymeric Materials and Their Migration from Plastics into Solution.- M. Hakkarainen: Migration of Monomeric and Polymeric PVC Plasticizers.-
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