Electrochemical Syntheses and Electrochromic Properties of Chromium Cyanide Magnetic Thin Films

  • Osamu Sato
    Kanagawa Academy of Science and Technology1583 Iiyama, Atsugi, Kanagawa
  • Zhongze Gu
    Kanagawa Academy of Science and Technology1583 Iiyama, Atsugi, Kanagawa
  • Hiroyuki Etoh
    Kanagawa Academy of Science and Technology1583 Iiyama, Atsugi, Kanagawa
  • Jun-ichi Ichiyanagi
    Kanagawa Academy of Science and Technology1583 Iiyama, Atsugi, Kanagawa
  • Tomokazu Iyoda
    Kanagawa Academy of Science and Technology1583 Iiyama, Atsugi, Kanagawa
  • Akira Fujishima
    Kanagawa Academy of Science and Technology1583 Iiyama, Atsugi, Kanagawa
  • Kazuhito Hashimoto
    Kanagawa Academy of Science and Technology1583 Iiyama, Atsugi, Kanagawa

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Electrochemical preparation method and electromic properties of the mixed valence chromium cyanide thin film, which is one of the ferrimagnet with highest critical temparature (Tc) among molecule-based magnets, were described. The difference in the ability of the ligand substitution reaction between CrII and CrIII was utilized to synthesize the prussian blue analogs. The obtained magnetic material exhibited an excellent electrochromic properties. This indicates the compound has a potential for future display devices, as well as tunable molecule-based magnetic devices.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 26 (1), 37-38, 1997-01-01

    Oxford University Press (OUP)

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