Chelate-Ring Formation in Cr(CO)5(phen) Studied by Laser Flash Photolysis with Visible and Infrared Detection
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- Shigero Oishi
- Department of Chemistry, School of Science, Kitasato UniversityKitasato, Sagamihara, Kanagawa
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- Hiroshi Inui
- Department of Chemistry, School of Science, Kitasato UniversityKitasato, Sagamihara, Kanagawa
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- Yasunao Kuriyama
- Department of Chemistry, School of Science, Kitasato UniversityKitasato, Sagamihara, Kanagawa
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Abstract
<jats:title>Abstract</jats:title> <jats:p>Kinetic parameters were obtained for the formation of chelate ring in transient Cr(CO)5(phen) and 0.17 s−1 (20 °C), ΔH‡ = 85.0 kJ·mol−1, and ΔS‡ =29.8 J·mol−1·K−1, indicating the concerted extrusion of CO by an uncoordinated nitrogen rather than the simple dissociation of CO. In comparison with other bidentate ligands, it was revealed that the structural advantage of phen, which gave significant enhancement in the rate of chelation, was due to entropy term.</jats:p>
Journal
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- Chemistry Letters
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Chemistry Letters 26 (2), 115-116, 1997-02-01
Oxford University Press (OUP)
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Keywords
Details 詳細情報について
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- CRID
- 1360283694086002816
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- NII Article ID
- 10002609515
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- NII Book ID
- AA00603318
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- ISSN
- 13480715
- 03667022
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- Data Source
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- Crossref
- CiNii Articles