High Surface Area Smectite Supported Cobalt Oxides as Active Catalysts for Thiophene Hydrodesulfurization

  • Eiji Hayashi
    Advanced Catalysts Research Laboratory, Petroleum Energy Center, KSPTakatsu, Kawasaki
  • Eiji Iwamatsu
    Advanced Catalysts Research Laboratory, Petroleum Energy Center, KSPTakatsu, Kawasaki
  • Mohammad Elias Biswas
    The Research Institute, King Fahd University of Petroleum and MineralsDhahran 31261, Saudi Arabia
  • Syed Ahmed Ali
    The Research Institute, King Fahd University of Petroleum and MineralsDhahran 31261, Saudi Arabia
  • Yosuke Yamamoto
    Advanced Catalysts Research Laboratory, Petroleum Energy Center, KSPTakatsu, Kawasaki
  • Yuzo Sanada
    Advanced Catalysts Research Laboratory, Petroleum Energy Center, KSPTakatsu, Kawasaki
  • Augustin K K Lee
    The Research Institute, King Fahd University of Petroleum and MineralsDhahran 31261, Saudi Arabia
  • Halim Hamid
    The Research Institute, King Fahd University of Petroleum and MineralsDhahran 31261, Saudi Arabia
  • Toshikazu Yoneda
    Advanced Catalysts Research Laboratory, Petroleum Energy Center, KSPTakatsu, Kawasaki

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Cobalt oxide loaded on high surface area smectites are prepared and tested in a pulse flow reactor for thiophene hydrodesulfurization (HDS). Smectites used were montmorillonite, saponite, porous saponite, hectorite and stevensite. Co-porous saponite showed the highest activity among Co-smectites, Co/Al2O3, and CoMo/Al2O3 so far studied. It suggests that the property of smectite has an influence on the catalyst activity.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 26 (5), 433-434, 1997-05-01

    Oxford University Press (OUP)

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