Cyclohexylenedithio Annelated Bis-Fused TTF Donors and Their Conducting Salts

  • Minoru Ashizawa
    Department of Organic and Polymeric Materials, Tokyo Institute of TechnologyO-okayama, Tokyo
  • Masanobu Aragaki
    Department of Organic and Polymeric Materials, Tokyo Institute of TechnologyO-okayama, Tokyo
  • Takehiko Mori
    Department of Organic and Polymeric Materials, Tokyo Institute of TechnologyO-okayama, Tokyo
  • Yohji Misaki
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto UniversityYoshida, Kyoto
  • Tokio Yamabe
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto UniversityYoshida, Kyoto

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Bis-fused TTF(tetrathiafulvalene) derivatives with a cyclohexane ring 1a-c have been synthesized. One of their radical-cation salts (1b)2Au(CN)2 exhibits high conductivity σrt=160 Scm−1 and is metallic down to 120 K. Its structure consists of weakly dimerized columns with relatively small intercolumnar interactions.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 26 (7), 649-650, 1997-07-01

    Oxford University Press (OUP)

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