Cyclohexylenedithio Annelated Bis-Fused TTF Donors and Their Conducting Salts

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著者

    • ASHIZAWA Minoru
    • Department of Organic and Polymeric Materials, Tokyo Institute of Technology
    • ARAGAKI Masanobu
    • Department of Organic and Polymeric Materials, Tokyo Institute of Technology
    • MORI Takehiko
    • Department of Organic and Polymeric Materials, Tokyo Institute of Technology
    • MISAKI Yohji
    • Department of Molecular Engineering, Graduate School of Engineering, Kyoto University
    • YAMABE Tokio
    • Department of Molecular Engineering, Graduate School of Engineering, Kyoto University

抄録

Bis-fused TTF(tetrathiafulvalene) derivatives with a cyclohexane ring <B>1a-c</B> have been synthesized. One of their radical-cation salts (<B>1b</B>)<SUB>2</SUB>Au(CN)<SUB>2</SUB> exhibits high conductivity σ<SUB>rt</SUB>=160 Scm<SUP>−1</SUP> and is metallic down to 120 K. Its structure consists of weakly dimerized columns with relatively small intercolumnar interactions.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1997(7), 649-650, 1997-07 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002613099
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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