Charge-Transfer Complex of a New Acceptor Cyananilate with Tetramethyltetrathiafulvalene, (TMTTF)2HCNAL

• Md Badruz Zaman

  Department of Functional Molecular Science, The Graduate University for Advanced StudiesMyodaiji, Okazaki

• Yasushi Morita

  Department of Chemistry, Graduate School of Science, Osaka UniversityToyonaka, Osaka

• Jiro Toyoda

  Department of Chemistry, Graduate School of Science, Osaka UniversityToyonaka, Osaka

• Hideki Yamochi

  Department of Chemistry, Faculty of Science, Kyoto UniversityKyoto

• Gunzi Saito

  Department of Chemistry, Faculty of Science, Kyoto UniversityKyoto

• Naoki Yoneyama

  Department of Chemistry, Faculty of Science, Tokyo Institute of TechnologyO-okayama, Meguroku, Tokyo

• Toshiaki Enoki

  Department of Chemistry, Faculty of Science, Tokyo Institute of TechnologyO-okayama, Meguroku, Tokyo

• Kazuhiro Nakasuji

  Department of Chemistry, Graduate School of Science, Osaka UniversityToyonaka, Osaka

Abstract

Cyananilic acid (H2CNAL) gave a charge-transfer complex with tetramethyltetrathiafulvalene, (TMTTF)2HCNAL, in which the acceptor forms a hydrogen-bonded ribbon arrangement and the donor forms a columnar stacking. The ionicity of the donor is estimated as +0.5. The electrical conductivity is 0.03 Scm−1 with the activation energy of 0.05 eV. The magnetic spin susceptibility is described in terms of a one-dimensional antiferromagnet.

Journal

• Chemistry Letters

  Chemistry Letters 26 (8), 729-730, 1997-08-01

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360846644039522944
• NII Article ID: 10002613596
• NII Book ID: AA00603318
• DOI: 10.1246/cl.1997.729
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/26/8/729/56075362/cl.1997.729.pdf
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  • CiNii Articles