Distortion of the Unit Cell of Platinum(II) Complexes under Light Irradiation

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  • Takashi Ikagawa
    CREST, Japan Science and Technology Corporation(JST)
  • Toshihiko Okumura
    Department of Chemistry, Tokyo Institute of TechnologyO-okayama, Megro-ku, Tokyo
  • Takuhiro Otsuka
    Department of Chemistry, Tokyo Institute of TechnologyO-okayama, Megro-ku, Tokyo
  • Youkoh Kaizu
    Department of Chemistry, Tokyo Institute of TechnologyO-okayama, Megro-ku, Tokyo

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Abstract

<jats:title>Abstract</jats:title> <jats:p>The shift of X-ray powder pattern of Platinum(II) complexes was observed under light irradiation by using X-ray powder diffractometer. The peaks were returned to the original one when the irradiation of light was cut off. The observed X-ray powder patterns show that the unit cell of [Pt(acac)2] is expanded under light irradiation, however, that of [Bu4N]4[Pt2(pop)4] (pop2−=P2O5H22−) is contracted.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 26 (8), 829-830, 1997-08-01

    Oxford University Press (OUP)

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