Synthesis, Structure, and Electrochemical Properties of New “Unsymmetrical” Metal Dithiolate Complexes

• Reizo Kato

  The Institute for Solid State Physics, The University of TokyoRoppongi, Minato-ku, Tokyo

• Yoshiaki Kashimura

  The Institute for Solid State Physics, The University of TokyoRoppongi, Minato-ku, Tokyo

• Hiroshi Sawa

  Department of Physics, Faculty of Science, Chiba UniversityYayoi-cho, Inage-ku, Chiba

• Yoshinori Okano

  The Institute for Solid State Physics, The University of TokyoRoppongi, Minato-ku, Tokyo

Abstract

New “unsymmetrical” (mixed ligand) metal dithiolate complexes, expected as components of molecular conductors, have been obtained by a ligand-exchange reaction in refluxing acetone, followed by isolation with a preparative HPLC (ODP; acetonitrile-H2O). Their electrochemical data suggest that the acceptor (donor) ability and the on-site Coulomb energy for the “unsymmetrical” complexes can be tuned by a combination of ligands.

Journal

• Chemistry Letters

  Chemistry Letters 26 (9), 921-922, 1997-09-01

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360002219109416320
• NII Article ID: 10002615018
• NII Book ID: AA00603318
• DOI: 10.1246/cl.1997.921
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/26/9/921/56074168/cl.1997.921.pdf
• Data Source:
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  • CiNii Articles