Photoinduced Intra- and Inter-Molecular Hydrogen-Atom Abstraction of 1-Methylanthraquinone

• Tetsuya Hamana

  Department of Chemistry, Kyoto Institute of Technology

• Sadao Miki

  Department of Chemistry, Kyoto Institute of Technology

• Kumao Hamanoue

  Department of Chemistry, Kyoto Institute of Technology

Abstract

The intramolecular hydrogen-atom abstraction in the lowest excited singlet and triplet states of 1-methylanthraquinone yields 9-hydroxy-1,10-anthraquinone-1-methide. The lowest excited triplet state at room temperature also abstracts a hydrogen atom from ethanol yielding 1-methyl-9,10-dihydroxyanthracene.

Journal

• Chemistry Letters

  Chemistry Letters 25 (1), 87-88, 1996-01-01

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360565169062676224
• NII Article ID: 10003738379
• NII Book ID: AA00603318
• DOI: 10.1246/cl.1996.87
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/25/1/87/56070185/cl.1996.87.pdf
• Data Source:
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  • CiNii Articles