Microporous Structure of a Chain Compound of Copper(II) Benzoate Bridged by Pyrazine

  • Ryoji Nukada
    Department of Chemistry, School of Science, Kwansei Gakuin UniversityUegahara, Nishinomiya
  • Wasuke Mori
    Department of Chemistry, Faculty of Science, Kanagawa UniversityHiratsuka
  • Satoshi Takamizawa
    Department of Chemistry, Graduate School of Science, Osaka UniversityToyonaka, Osaka
  • Masahiro Mikuriya
    Department of Chemistry, School of Science, Kwansei Gakuin UniversityUegahara, Nishinomiya
  • Makoto Handa
    Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane UniversityNishikawatsu, Matsue
  • Hiromitsu Naono
    Department of Chemistry, School of Science, Kwansei Gakuin UniversityUegahara, Nishinomiya

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Reaction of copper(II) benzoate with pyrazine (pyz) gave a compound, [Cu2(bz)4(pyz)]n (1) which has a gas-occlusion property. The X-ray structure analysis of 1·2nCH3CN shows a microporous structure formed by chains where the carboxylate dimer units are linked by pyrazine molecules.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 28 (5), 367-368, 1999-05-01

    Oxford University Press (OUP)

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