Easy Access to [60]Fulleroalkaloids <i>via</i> Photoinduced Reactions of Tertiary Amines with [60]Fullerene

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  • Li-Wei Guo
    Department of Chemistry, Fudan UniversityShanghai 200433, P.R . China
  • Xiang Gao
    Department of Chemistry, Fudan UniversityShanghai 200433, P.R . China
  • Dan-Wei Zhang
    Department of Chemistry, Fudan UniversityShanghai 200433, P.R . China
  • Shi-Hui Wu
    Department of Chemistry, Fudan UniversityShanghai 200433, P.R . China
  • Hou-Ming Wu
    State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic ChemistryShanghai 200032, P.R . China
  • Yong-Jiang Li
    State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic ChemistryShanghai 200032, P.R . China

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Photoinduced reactions of tertiary amines with [60]fullerene (C60) were successfully applied to the synthesis of [60]fulleroalkaloids. This method is easy and effective for constructing C60 derivatives containing natural alkaloids for the purpose of checking the influence of the carbon cage on the biological activities of the alkaloids. In this letter, the preparation and characterization of [60]fulleroscandine is reported.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 28 (5), 411-412, 1999-05-01

    Oxford University Press (OUP)

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