Insertion of Phenylacetylene into <i>cis</i>-Silyl(stannyl)platinum Complexes

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  • Fumiyuki Ozawa
    Department of Applied Chemistry, Faculty of Engineering, Osaka City UniversitySumiyoshi-ku, Osaka
  • Yasunobu Sakamoto
    Department of Applied Chemistry, Faculty of Engineering, Osaka City UniversitySumiyoshi-ku, Osaka
  • Takashi Sagawa
    Department of Applied Chemistry, Faculty of Engineering, Osaka City UniversitySumiyoshi-ku, Osaka
  • Rika Tanaka
    Department of Applied Chemistry, Faculty of Engineering, Osaka City UniversitySumiyoshi-ku, Osaka
  • Hiroyuki Katayama
    Department of Applied Chemistry, Faculty of Engineering, Osaka City UniversitySumiyoshi-ku, Osaka

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Silyl(stannyl)platinum(II) complexes cis-Pt(SiR3)(SnMe3)(PMe2Ph)2 (SiR3 = SiMe3, SiMe2Ph, SiMePh2, SiPh3) undergo insertion of phenylacetylene into the Pt–Si or Pt–Sn bond. The site selectivity dramatically varies with silyl ligands under kinetic conditions, while under thermodynamic conditions the insertion into the Pt–Si bond exclusively takes place irrespective of silyl ligands.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 28 (12), 1307-1308, 1999-12-01

    Oxford University Press (OUP)

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