Visible Light-induced Cationic Polymerization of Epoxides Sensitized by Benzoquinonylsulfanyl Derivatives

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  • Kanji Suyama
    Department of Applied Chemistry, Osaka Prefecture University1-1 Gakuen-cho, Sakai, Osaka
  • Weihong Qu
    Department of Applied Chemistry, Osaka Prefecture University1-1 Gakuen-cho, Sakai, Osaka
  • Masamitsu Shirai
    Department of Applied Chemistry, Osaka Prefecture University1-1 Gakuen-cho, Sakai, Osaka
  • Masahiro Tsunooka
    Department of Applied Chemistry, Osaka Prefecture University1-1 Gakuen-cho, Sakai, Osaka

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Abstract

<jats:title>Abstract</jats:title> <jats:p>On irradiation with visible light, cationic polymerization of epoxides by a photoacid generator (PAG) was sensitized by benzoquinonylsulfanyl derivatives. Spectral analyses suggest that the reduction of the quinone derivatives on irradiation was the initial and essential step of the polymerization.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 32 (1), 92-93, 2002-12-20

    Oxford University Press (OUP)

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