An Efficient Method for the Preparation of <i>N</i>-Alkylamides from Alkyl Diphenylphosphinites and Amides by Using Methyl Acrylate
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- Hidenori Aoki
- Center for Basic Research, The Kitasato Institute
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- Teruaki Mukaiyama
- Center for Basic Research, The Kitasato Institute
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Abstract
<jats:title>Abstract</jats:title> <jats:p>N,N-Dibenzyltrifluoroacetamide was formed in good yield by treating benzyl diphenylphosphinite with N-benzyltrifluoroacetamide in the presence of easily available methyl acrylate under mild conditions. Yields obtained for the corresponding inverted sulfonamides were good to high in the cases when alkyl diphenylphosphinites derived from chiral secondary alcohols were used.</jats:p>
Journal
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- Chemistry Letters
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Chemistry Letters 35 (4), 456-457, 2006-03-25
Oxford University Press (OUP)
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Keywords
Details 詳細情報について
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- CRID
- 1360283694087540224
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- NII Article ID
- 10018126008
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- NII Book ID
- AA00603318
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- ISSN
- 13480715
- 03667022
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- Data Source
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- Crossref
- CiNii Articles