Synthesis and Reactivity of Tris(7-azaindolyl)boratoruthenium Complex. Comparison with Poly(methimazolyl)borate Analogue
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- Tomoyuki Saito
- Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology
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- Shigeki Kuwata
- Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology
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- Takao Ikariya
- Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology
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Abstract
<jats:title>Abstract</jats:title> <jats:p>A reaction of [Cp*RuCl]4 (Cp* = η5-C5(CH3)5) with K[HB(aza)3] (aza = 7-azaindolyl) afforded the first organometallic HB(aza)3− complex [Cp*Ru{HB(aza)3-κ3H,N,N′}], which lost one of the aza-units coordination upon treatment with carbon monoxide to give the mono(carbonyl) complex [Cp*Ru{HB(aza)3-κ2H,N}(CO)]. The crystal structures of these complexes have been determined by X-ray crystallography.</jats:p>
Journal
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- Chemistry Letters
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Chemistry Letters 35 (11), 1224-1225, 2006-09-30
Oxford University Press (OUP)
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Keywords
Details 詳細情報について
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- CRID
- 1360565169064185728
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- NII Article ID
- 10018404648
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- NII Book ID
- AA00603318
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- ISSN
- 13480715
- 03667022
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- Data Source
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- Crossref
- CiNii Articles