Intercalation of α,ω-Diaminoalkanes in the Interlayer Space of the Protonated Form of the Layered Perovskite H1.8Bi0.2Sr0.8Ta2O7

• Seiichi Tahara

  Department of Applied Chemistry, School of Science and Engineering, Waseda University

• Takashi Yamashita

  Department of Applied Chemistry, School of Science and Engineering, Waseda University

• Go Kajiwara

  Department of Applied Chemistry, School of Science and Engineering, Waseda University

• Yoshiyuki Sugahara

  Department of Applied Chemistry, School of Science and Engineering, Waseda University

Abstract

α,ω-Diaminoalkanes (NH2(CH2)nNH2; n = 2, 4, 8, and 12) are intercalated in the interlayer space of the protonated form of a layered perovskite, H1.8Bi0.2Sr0.8Ta2O7 (HSrTa). The amounts of α,ω-diaminoalkanes, which possess a monolayer arrangement in the interlayer space, are calculated as ca. 0.5 per [Bi0.2Sr0.8Ta2O7]. A model for α,ω-diaminoalkane–HSrTa intercalation compounds is proposed, and the model is consistent with that proposed for n-alkylamine–HSrTa intercalation compounds.

Journal

• Chemistry Letters

  Chemistry Letters 35 (11), 1292-1293, 2006-10-21

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360846644040904832
• NII Article ID: 10018405232
• NII Book ID: AA00603318
• DOI: 10.1246/cl.2006.1292
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/35/11/1292/55590854/cl.2006.1292.pdf
• Data Source:
  • Crossref
  • CiNii Articles