Chiral Scandium-catalyzed Highly Stereoselective Ring-opening of meso-Epoxides with Thiols

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著者

    • OGAWA Chikako
    • Graduate School of Pharmaceutical Sciences, The University of Tokyo, The HFRE Division, ERATO, Japan Science and Technology Agency (JST)
    • WANG Naiwei
    • Graduate School of Pharmaceutical Sciences, The University of Tokyo, The HFRE Division, ERATO, Japan Science and Technology Agency (JST)
    • KOBAYASHI Shu
    • Graduate School of Pharmaceutical Sciences, The University of Tokyo, The HFRE Division, ERATO, Japan Science and Technology Agency (JST)

抄録

The desymmetrization of <I>meso</I>-epoxides with thiols proceeded smoothly in dichloromethane or dichloroethane in the presence of a catalytic amount of a chiral scandium complex consisting of Sc(OTf)<SUB>3</SUB> and chiral bipyridine <B>1</B>, to afford the corresponding sulfides in high yields with high enantioselectivities.

収録刊行物

  • Chemistry letters  

    Chemistry letters 36(1), 34-35, 2007-01-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018662606
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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