Rhodium-catalyzed Addition of Organo[2-(hydroxymethyl)phenyl]dimethylsilanes to Arenesulfonylimines

  • Yoshiaki Nakao
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University
  • Masahide Takeda
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University
  • Jinshui Chen
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University
  • Tamejiro Hiyama
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University
  • Yoshitaka Ichikawa
    Department of Chemistry, Graduate School of Science, Kyoto University
  • Ryo Shintani
    Department of Chemistry, Graduate School of Science, Kyoto University
  • Tamio Hayashi
    Department of Chemistry, Graduate School of Science, Kyoto University

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Abstract

<jats:title>Abstract</jats:title> <jats:p>The title reaction is found to proceed in the presence of a rhodium/diene catalyst. Variously substituted diarylmethylamines and allylamines having an N-arenesulfonyl protection are obtained in good yields, which are important building blocks in organic synthesis.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 37 (3), 290-291, 2008-02-09

    Oxford University Press (OUP)

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