Radical Copolymerizations of Vinyl Monomers in a Porous Coordination Polymer

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  • Takashi Uemura
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
  • Yukari Ono
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University
  • Susumu Kitagawa
    Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Radical copolymerizations of vinyl monomers, such as styrene, methyl methacrylate, and vinyl acetate, in the nanochannels of a porous coordination polymer have been studied. The results are compared with those obtained for the corresponding free radical copolymerizations, which shows a spatial confinement effect on the monomer reactivity ratios in this system.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 37 (6), 616-617, 2008-05-03

    Oxford University Press (OUP)

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