A new mechanism of the generation of electron spin polarization through interactions between radical and excited molecule ラジカルと励起分子の相互作用による新しい電子スピン分極発生機構
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著者
書誌事項
- タイトル
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A new mechanism of the generation of electron spin polarization through interactions between radical and excited molecule
- タイトル別名
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ラジカルと励起分子の相互作用による新しい電子スピン分極発生機構
- 著者名
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河合, 明雄
- 著者別名
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カワイ, アキオ
- 学位授与大学
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東京工業大学
- 取得学位
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理学博士
- 学位授与番号
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甲第2396号
- 学位授与年月日
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1992-03-26
注記・抄録
博士論文
目次
- 論文目録 / (0002.jp2)
- CONTENTS / p1 (0004.jp2)
- Contents / p1 (0004.jp2)
- List of Figures / p4 (0007.jp2)
- Chapter I Overview of the "SPIN CHEMISTRY" / p1 (0012.jp2)
- 1-1 Contribution of Magnetic Resonance Technique to Photochemistry / p1 (0012.jp2)
- 1-2 Conventional Sources of Electron Spin Polarization / p3 (0014.jp2)
- 1-3 Recent Trends in Spin Chemistry / p11 (0022.jp2)
- 1-4 New Mechanism of the CIDEP Generation / p14 (0025.jp2)
- References / p17 (0028.jp2)
- Chapter II Experimental / p19 (0030.jp2)
- 2-1 Apparatus / p19 (0030.jp2)
- 2-2 Analysis of Time Resolved ESR Signals / p20 (0031.jp2)
- References / p27 (0038.jp2)
- Chapter III Electron Spin Polarization in Radical-Triplet Molecule Systems / p28 (0039.jp2)
- 3-1 Introduction / p28 (0039.jp2)
- 3-2 Experimental / p30 (0041.jp2)
- 3-3 Discovery of New CIDEP Generations / p31 (0042.jp2)
- 3-4 Theory of Radical Triplet Pair Mechanism (RTPM) / p39 (0050.jp2)
- 3-5 Solvent Effects on Net and Multiplet Polarization / p63 (0074.jp2)
- References / p72 (0083.jp2)
- Chapter IV Electron Spin Polarization in Radical-Excited Singlet Molecule Systems / p74 (0085.jp2)
- 4-1 Introduction / p74 (0085.jp2)
- 4-2 Experimental / p76 (0087.jp2)
- 4-3 Net Absorptive and Absorption/Emission (A/E) Multiplet Polarization / p77 (0088.jp2)
- 4-4 RTPM with Doublet Precursor / p81 (0092.jp2)
- 4-5 Switching of Doublet Precursor RTPM to Quartet Precursor RTPM / p85 (0096.jp2)
- References / p97 (0108.jp2)
- Chapter V Relation of RTPM and Radical-Excited Molecule Interactions / p99 (0110.jp2)
- References / p103 (0114.jp2)
- Chapter VI Application of RTPM / p104 (0115.jp2)
- 6-1 RTPM in Conventional Photochemical System / p104 (0115.jp2)
- 6-2 Trial Application of RTPM for the Excited States Quenching Processes / p110 (0121.jp2)
- References / p121 (0132.jp2)
- Acknowledgements / p122 (0133.jp2)