Molecular design of macrotricyclic ammonium cage hosts and novel halide ion inclusion complexes : complexibility, selectivity and structure 大環状アンモニウムキャビタンドの分子設計と新規なハライドイオン包接錯体 : 錯形成能、選択能および構造
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Bibliographic Information
- Title
-
Molecular design of macrotricyclic ammonium cage hosts and novel halide ion inclusion complexes : complexibility, selectivity and structure
- Other Title
-
大環状アンモニウムキャビタンドの分子設計と新規なハライドイオン包接錯体 : 錯形成能、選択能および構造
- Author
-
Mohammed Alamgir Hossain
- Author(Another name)
-
モハメド アラムギール ホサイン
- University
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北海道大学
- Types of degree
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博士 (地球環境科学)
- Grant ID
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甲第3946号
- Degree year
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1996-03-25
Note and Description
博士論文
Table of Contents
- Table of Contents / (0004.jp2)
- Chapter1.Introduction / (0006.jp2)
- 1.1.Molecular recognition-origins and perspectives / p2 (0007.jp2)
- 1.2 Molecular recognition of inorganic anions by artificial receptors:a historical review / p3 (0008.jp2)
- 1.3.Purpose and constitution of the present study / p10 (0015.jp2)
- 1.4.Reference / p12 (0017.jp2)
- Chapter2.Design of Molecular Receptors and Syntheses of the Parent Macrotricyclic Amines / (0019.jp2)
- 2.1.Molecular conception and design of hosts / p15 (0020.jp2)
- 2.2.Synthesis of Macrotricyclic Amine MA 555 / p16 (0021.jp2)
- 2.3.Synthesis of MA 556 / p27 (0032.jp2)
- 2.4.Synthesis of MA 566 / p29 (0034.jp2)
- 2.5.Synthesis of MA 666 / p38 (0043.jp2)
- 2.6.References / p39 (0044.jp2)
- Chapter3.X-ray Crystal Structures of Macrotricyclic Amines / (0045.jp2)
- 3.1.Crystal structure of MA 555 / p41 (0046.jp2)
- 3.2.Crystal structure of MA 566 / p48 (0053.jp2)
- 3.3.Discussion / p56 (0061.jp2)
- 3.4.References / p57 (0062.jp2)
- Chapter4.Syntheses of Macrotricyclic Cage Hosts / (0063.jp2)
- 4.1.Synthesis of methylated macrotricyclic quaternary ammonium salt MMQAS 555 / p59 (0064.jp2)
- 4.2.Synthesis of methylated macrotricyclic quaternary ammonium salt MMQAS 556 / p60 (0065.jp2)
- 4.3.Syntheses of functionalized macrotricyclic quaternary ammonium salts RMQAS 566 / p61 (0066.jp2)
- 4.4.Syntheses of functionalized maerotricyclie quaternary ammonium salts RMQAS 666 / p62 (0067.jp2)
- 4.5.References / p65 (0070.jp2)
- Chapter5.Encapsulation and Selectivity of Halide Ions by RMQAS in Solutions / (0071.jp2)
- 5.1.Introduction / p67 (0072.jp2)
- 5.2.Encapsulation of fluoride ion by MMQAS 555 / p68 (0073.jp2)
- 5.3.Encapsulation of halide ions by RMQAS 566 / p77 (0082.jp2)
- 5.4.Encapsulation and selectivity of halide ions by RMQAS 666 / p93 (0098.jp2)
- 5.5.References / p108 (0113.jp2)
- Chapter6.Novel Ionic Crystal of Chloride Ion Encapsulated in the Macrotricyclic Cage Host / (0114.jp2)
- 6.1.Introduction / p110 (0115.jp2)
- 6.2.Synthesis of single crystal of chloride complex〔Cl⁻⊂PMQA⁴⁺566〕 / p110 (0115.jp2)
- 6.3.Single crystal X-ray analysis of〔Cl⁻⊂PMQA⁴⁺566〕 / p111 (0116.jp2)
- 6.4.Discussion / p123 (0128.jp2)
- 6.5.References / p124 (0129.jp2)
- Chapter7.Summary and Conclusions / (0130.jp2)