Molecular design of macrotricyclic ammonium cage hosts and novel halide ion inclusion complexes : complexibility, selectivity and structure 大環状アンモニウムキャビタンドの分子設計と新規なハライドイオン包接錯体 : 錯形成能、選択能および構造
この論文にアクセスする
この論文をさがす
著者
書誌事項
- タイトル
-
Molecular design of macrotricyclic ammonium cage hosts and novel halide ion inclusion complexes : complexibility, selectivity and structure
- タイトル別名
-
大環状アンモニウムキャビタンドの分子設計と新規なハライドイオン包接錯体 : 錯形成能、選択能および構造
- 著者名
-
Mohammed Alamgir Hossain
- 著者別名
-
モハメド アラムギール ホサイン
- 学位授与大学
-
北海道大学
- 取得学位
-
博士 (地球環境科学)
- 学位授与番号
-
甲第3946号
- 学位授与年月日
-
1996-03-25
注記・抄録
博士論文
目次
- Table of Contents / (0004.jp2)
- Chapter1.Introduction / (0006.jp2)
- 1.1.Molecular recognition-origins and perspectives / p2 (0007.jp2)
- 1.2 Molecular recognition of inorganic anions by artificial receptors:a historical review / p3 (0008.jp2)
- 1.3.Purpose and constitution of the present study / p10 (0015.jp2)
- 1.4.Reference / p12 (0017.jp2)
- Chapter2.Design of Molecular Receptors and Syntheses of the Parent Macrotricyclic Amines / (0019.jp2)
- 2.1.Molecular conception and design of hosts / p15 (0020.jp2)
- 2.2.Synthesis of Macrotricyclic Amine MA 555 / p16 (0021.jp2)
- 2.3.Synthesis of MA 556 / p27 (0032.jp2)
- 2.4.Synthesis of MA 566 / p29 (0034.jp2)
- 2.5.Synthesis of MA 666 / p38 (0043.jp2)
- 2.6.References / p39 (0044.jp2)
- Chapter3.X-ray Crystal Structures of Macrotricyclic Amines / (0045.jp2)
- 3.1.Crystal structure of MA 555 / p41 (0046.jp2)
- 3.2.Crystal structure of MA 566 / p48 (0053.jp2)
- 3.3.Discussion / p56 (0061.jp2)
- 3.4.References / p57 (0062.jp2)
- Chapter4.Syntheses of Macrotricyclic Cage Hosts / (0063.jp2)
- 4.1.Synthesis of methylated macrotricyclic quaternary ammonium salt MMQAS 555 / p59 (0064.jp2)
- 4.2.Synthesis of methylated macrotricyclic quaternary ammonium salt MMQAS 556 / p60 (0065.jp2)
- 4.3.Syntheses of functionalized macrotricyclic quaternary ammonium salts RMQAS 566 / p61 (0066.jp2)
- 4.4.Syntheses of functionalized maerotricyclie quaternary ammonium salts RMQAS 666 / p62 (0067.jp2)
- 4.5.References / p65 (0070.jp2)
- Chapter5.Encapsulation and Selectivity of Halide Ions by RMQAS in Solutions / (0071.jp2)
- 5.1.Introduction / p67 (0072.jp2)
- 5.2.Encapsulation of fluoride ion by MMQAS 555 / p68 (0073.jp2)
- 5.3.Encapsulation of halide ions by RMQAS 566 / p77 (0082.jp2)
- 5.4.Encapsulation and selectivity of halide ions by RMQAS 666 / p93 (0098.jp2)
- 5.5.References / p108 (0113.jp2)
- Chapter6.Novel Ionic Crystal of Chloride Ion Encapsulated in the Macrotricyclic Cage Host / (0114.jp2)
- 6.1.Introduction / p110 (0115.jp2)
- 6.2.Synthesis of single crystal of chloride complex〔Cl⁻⊂PMQA⁴⁺566〕 / p110 (0115.jp2)
- 6.3.Single crystal X-ray analysis of〔Cl⁻⊂PMQA⁴⁺566〕 / p111 (0116.jp2)
- 6.4.Discussion / p123 (0128.jp2)
- 6.5.References / p124 (0129.jp2)
- Chapter7.Summary and Conclusions / (0130.jp2)