Photochemistry of <i>π</i>-Complexes of Chlorine Atom with Methyl- and Ethyl-Substituted Benzenes

• Wu Feng

  Department of Atomic Science and Nuclear Engineering, Faculty of Engineering, Hokkaido University

• Takashi Sumiyoshi

  Department of Atomic Science and Nuclear Engineering, Faculty of Engineering, Hokkaido University

• Yuichiro Yamashita

  Department of Atomic Science and Nuclear Engineering, Faculty of Engineering, Hokkaido University

• Toshihiko Shindo

  Department of Atomic Science and Nuclear Engineering, Faculty of Engineering, Hokkaido University

• Sadashi Sawamura

  Department of Atomic Science and Nuclear Engineering, Faculty of Engineering, Hokkaido University

Abstract

The photochemistry of π-complexes of the chlorine atom with a series of methyl- and ethyl-substituted benzenes has been investigated using combined pulse radiolysis-laser flash photolysis techniques. Direct photolysis of π-complexes in carbon tetrachloride causes photobleaching by intramolecular hydrogen abstraction with quantum yields of 0.05–0.15 depending on the substituents but not on the positions of them.

Journal

• Chemistry Letters

  Chemistry Letters 25 (8), 643-644, 1996-08-01

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360002219109224832
• NII Article ID: 10002605123
• NII Book ID: AA00603318
• DOI: 10.1246/cl.1996.643
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/25/8/643/56071416/cl.1996.643.pdf
• Data Source:
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  • CiNii Articles